Method and system for preparing low-carbon olefin from crude oil

A low-carbon olefin and crude oil technology, applied in the field of low-carbon olefin preparation, can solve the problems of insufficient vaporization of crude oil, easy coking, low yield of low-carbon olefins, etc., to achieve insufficient gasification, high yield, and extended operation cycle effect

Active Publication Date: 2021-04-27
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0012] The purpose of the present invention is to provide a method and system for preparing low-carbon olefins from crude oil in order to overcome the problems of insufficient crude oil vaporization, easy coking in the cracking process, and low yield of low-carbon olefins in the prior art. It can improve the cracking efficiency of crude oil raw materials, prolong the operation period, reduce the coking phenomenon during cracking, and increase the yield of low-carbon olefins in the product at the same time

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  • Method and system for preparing low-carbon olefin from crude oil

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Comparison scheme
Effect test

Embodiment 1

[0077] Embodiment 1 adopts the method for preparing light olefins from crude oil

[0078] use figure 1 The system shown is performed, wherein the vaporization treatment unit employs a cyclone separator.

[0079] (1) The dehydrated and desalted crude oil is mixed with superheated steam in the first tube group of the convection section of the cracking furnace, and then preheated to obtain preheated crude oil. The weight ratio of superheated steam to crude oil is 0.75:1. Crude oil continues to be heated to 280°C to become preheated crude oil.

[0080] (2) The temperature of the preheated crude oil is 280°C, and it is sent to a cyclone separator with internals (the guide vane type cyclone separator is selected in this embodiment) for vaporization treatment to obtain the first vapor phase and the first liquid phase. Mutually. The separation efficiency of the cyclone separator is 98%, and the liquid phase in the first vapor phase after separation is 265mg / m 3 .

[0081] (3) Sen...

Embodiment 2

[0087] use figure 1 The system shown is carried out, wherein the vaporization separation unit adopts a cyclone separator.

[0088] (1) After the dehydrated and desalted crude oil is mixed with superheated steam in the first pipe group 1 of the convection section of the cracking furnace 4, the preheated crude oil is obtained. Crude oil continues to be heated to 315°C to become preheated crude oil.

[0089] (2) the temperature of the crude oil after preheating is 315 ℃, it is sent into the first cyclone separator 5 (the guide vane type cyclone separator is selected in the present embodiment) that has internal member to carry out vaporization separation and obtain the first vapor phase and first liquid phase. The separation efficiency of the first cyclone separator 5 is 98%, and the liquid phase in the first vapor phase after separation is 150mg / m 3 .

[0090] (3) Send the first liquid phase into the first tube group of the convection section of the cracking furnace for prehe...

Embodiment 3

[0096] use figure 1 The system shown is carried out, wherein the vaporization separation unit adopts a cyclone separator.

[0097] (1) After the dehydrated and desalted crude oil is mixed with superheated steam in the first pipe group 1 of the convection section of the cracking furnace 4, the preheated crude oil is obtained. Crude oil continues to be heated to 220°C to become preheated crude oil.

[0098] (2) The temperature of the preheated crude oil is 220°C, and it is sent into the first cyclone separator 5 with internals (the guide vane type cyclone separator is selected in this embodiment) for vaporization and separation to obtain the first gas phase and the second gas phase. a liquid phase. The separation efficiency of the first cyclone separator 5 is 98%, and the liquid phase in the first gas phase after separation is 100mg / m 3 .

[0099] (3) The first liquid phase is sent to the first tube group of the convection section of the cracking furnace for preheating to 26...

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Abstract

The invention relates to a method and system for preparing low-carbon olefin from crude oil, and the method comprises the following steps: feeding crude oil into a first pipe group of a convection section of a cracking furnace for preheating, and then carrying out vaporization treatment to form a first vapor phase and a first liquid phase; feeding the first liquid phase into the first pipe group of the convection section of the cracking furnace, conducting preheating, and then conducting distilling to form a tower top fraction, a middle fraction and a tower bottom fraction; mixing the tower top fraction, the middle fraction and the first steam phase, feeding a formed mixture into a second pipe group of the convection section of the cracking furnace, conducting heating to a crossing temperature, and feeding the mixture into a radiation section for cracking to obtain cracking gas; and carrying out deep catalytic cracking on the tower bottom fraction to obtain deep catalytic cracking gas, and separating the deep catalytic cracking gas from the cracking gas to obtain the low-carbon olefin. The cracking furnace is matched with a vaporization treatment unit, a distillation unit and a deep catalytic cracking unit, so that the problems that a heavy cracking raw material cannot be fully gasified in a convection section and is easy to coke in a radiation section and a quenching part can be effectively solved.

Description

technical field [0001] The invention relates to the field of preparation of light olefins, in particular to a method and system for preparing light olefins from crude oil. Background technique [0002] Low-carbon olefins usually refer to the general term of unsaturated hydrocarbons with carbon four or less, mainly including ethylene, propylene, isobutylene, butadiene and other organic chemical raw materials with high economic value. With the development of my country's economy, the demand for these organic chemical raw materials is increasing year by year. Although the production scale of low-carbon olefins is also increasing year by year, it cannot meet the growing demand. [0003] For a long time, my country has been preparing low-carbon olefin products from naphtha. However, in recent years, with the massive exploitation of associated gas in oilfields in the Middle East and shale gas in the United States, these cheap oil and gas resources have been widely used as ethylen...

Claims

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Application Information

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IPC IPC(8): C10G55/06C07C4/06C07C11/04C07C11/06C07C11/08C07C11/21
CPCC10G55/06C07C4/06C07C11/04C07C11/06C07C11/08C07C11/21Y02P30/40
Inventor 石莹王国清张利军刘同举张兆斌周丛蒋冰
Owner CHINA PETROLEUM & CHEM CORP
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