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39results about How to "Solve easy coking" patented technology

Nickel-based oxygen vacancy carrier catalyst as well as preparation method and application thereof

The invention provides a nickel-based oxygen vacancy carrier catalyst as well as a preparation method and application thereof, and belongs to the field of catalytic reforming and diesel hydrogen production. With the catalyst provided by the invention adopted, the problems of low activity, easy coking and poor sulfur resistance of a diesel reforming catalyst can be solved. Cerium dioxide is used asan oxygen carrier; heterovalent metal La is doped in the CeO2 to reduce oxygen vacancy generation energy; the enhancement of the oxygen storage and release capacity of the carrier can inhibit side reactions so as to improve the activity of a main reaction. Diesel oil H/C is low, a large amount of carbon deposits are likely to occur during reforming; when coking occurs, the oxygen vacancy carriercan release more oxygen to oxidize the carbon deposits, so that coking inactivation of the catalyst is avoided. Ni particles are smaller in size and more uniform in distribution, so that the catalyticactivity of the catalyst is improved, and the catalyst can still keep excellent reforming performance after part of active metal sulfur is poisoned; the oxide of lanthanum is mainly distributed on asurface phase, so that high-temperature stability of the catalyst can be improved, and high-temperature sintering of the catalyst carrier is avoided.
Owner:TSINGHUA UNIV

Laser detection type combustion chamber temperature detection device

PendingCN108225574AAccurately obtain combustion parametersReal-time monitoring of temperature field distribution parametersSensing radiation from gases/flamesCombustion chamberEngineering
The invention discloses a laser detection type combustion chamber temperature detection device, which comprises a supporting frame, a decoking device, a soot blowing and cooling device and a laser detection device. The supporting frame comprises a seamless steel pipe; one end of the decoking device is arranged in the seamless steel pipe and capable of axially and freely sliding; the decoking device is provided with a forked head portion which extends out of the front end of the supporting frame during decoking; the soot blowing and cooling device and the laser detection device are sequentiallyfixed to the rear end of the supporting frame; one end of the soot blowing and cooling device is communicated with the seamless steel pipe while the other end is sealed through a windproof filter, and the soot blowing and cooling device is provided with an air inlet. During laser detection, laser emitted by the laser detection device sequentially penetrates the soot blowing and cooling device andthe supporting frame to enter a to-be-detected combustion chamber or sequentially penetrates the supporting frame and the soot blowing and cooling device to be received by the laser detection device.By arrangement of the supporting frame, the decoking device and the soot blowing and cooling device, problems of high temperature, high dust and proneness to coking of a viewport in implementation ofa TDLAS (tunable diode laser absorption spectroscopy) system is effectively solved.
Owner:NANJING SCIYON AUTOMATION GRP

Low-rank pulverized coal gas generating process used for blast furnace injection

The invention discloses a low-order pulverized coal gas-making process for blast furnace injection. Oxygen and water vapor are mixed at high temperature to form a gasification agent, and the gasification agent is passed into pulverized coal to react to form high-temperature coal-made gas. The dust in the high-temperature coal-to-gas is purified and cooled, and then desulfurized. The gas is compressed and stored in the gas storage tank. The gas in the gas storage tank is led to each blast furnace tuyere through the pipeline for injection. The low-order pulverized coal gas production process used in blast furnace injection in the present invention first generates coal gas through the reaction of clean coal powder, and then utilizes it for blast furnace injection. The process of producing coal gas burns clean, effectively alleviating energy pollution, and the preparation process Simple and efficient, strong operability, high purity of the gas produced and low pollution; the injection of clean gas not only improves the efficiency of the blast furnace, but also solves the problem of energy imbalance, reduces the cost of blast furnace ironmaking, and solves the problem of blast furnace injection Coal powder is easy to coke and the combustion efficiency is low, which solves the problem of high cost of natural gas, solves the problem of poor atomization caused by heavy oil injection, and prevents the formation of a large amount of soot at high temperatures.
Owner:JIANGSU PROVINCE METALLURGICAL DESIGN INST

Vacuum tower for waste lubricating oil pretreatment

The invention provides a vacuum tower for waste lubricating oil pretreatment. The vacuum tower is of a cylinder vertical structure; a tower tray is not arranged in the vacuum tower; a tower skirt, a feeding port, a baffle, an over-vaporized oil production section, a distillate oil production section, a diesel production section and a gas outlet are formed in the vacuum tower; two packing sectionscan be arranged among the diesel production section, the distillate oil production section and the over-vaporized oil production section according to the difficulty of separation of distillate oil ineach of the production sections; further, backflow spray distributors are respectively arranged on the three oil production sections and the packing sections. According to the vacuum tower in the scheme of the invention, the tower tray and fillers are directly replaced by utilizing a sprayer, the pressure drop is reduced in a manner of spray fractionation, the separation effect is good, and the process is simple, convenient and practical; moreover, according to the fraction separation difficulty, whether the fillers are provided or not can be freely selected, the heat and mass transfer efficiency is enhanced, and flexible and variable effects are realized, Importantly, the technical scheme of the invention solves the problem of influence on continuous production due to coking in all positions in the vacuum tower.
Owner:深圳至诚环境科技有限公司

Polyacrylonitrile precursor and polymerization reaction kettle serving as production equipment thereof

The invention relates to a polyacrylonitrile precursor and a polymerization reaction kettle serving as production equipment thereof. The formula of the polyacrylonitrile precursor mainly comprises monomers AN, MA and IA, dimethylsulfoxide (DMSO) serving as a solvent, and azodiisobutyronitrile (AIBN) serving as an initiator; and if the total content of the mixed liquid of AN, MA and IA is 1, the content of the DMSO is 30-50% by weight, and the content of the AIBN is 6.5-9.5% by weight. The reaction kettle serving as the production equipment of polyacrylonitrile precursor provided by the invention comprises a kettle body and a kettle cover, wherein the kettle body and the kettle cover are connected through a flange; stirrers are arranged in the kettle body; a liquid inlet and a liquid outlet are arranged on the kettle cover; each stirrer is a ribbon stirrer; and two or more ribbon stirrers are arranged. The invention has the advantages that the conversion rate is obviously improved, the monomer recovery is easy, and fiber with a dense structure is easily obtained in spinning, thereby being beneficial to the improvement of the soft scientific performance of the finally obtained fiber; and moreover, the problems of non-uniform stirring, easy coking, low conversion rate, unstable reaction and the like in the production of the polyacrylonitrile precursor can be effectively solved.
Owner:HENGSHEN

A method and system for preparing low-carbon olefins

The invention relates to a method and system for preparing low-carbon olefins. The method is carried out as follows: the crude oil is sent to the first tube group of the convection section of the cracking furnace for preheating, and then vapor-liquid separation is performed to form a first vapor phase and a first liquid phase. phase; the first liquid phase is sent to the first tube group of the convection section for preheating, and the preheated first liquid phase is distilled to form a tower top fraction, a middle distillate and a tower bottom fraction; the tower bottom fraction is subjected to hydroprocessing , to obtain circulating hydrogen, light components after hydrogenation and heavy components after hydrogenation; mix the top distillate with the middle distillate, mix with the first vapor phase, and light components after hydrogenation, and send them to the cracking furnace for cracking to obtain a low carbon olefins. The present invention adopts the combination of cracking furnace, vapor-liquid separation unit, distillation unit and hydroprocessing unit, which can effectively solve the problems that the heavy cracking raw material cannot be fully gasified in the convection section and is easy to coke in the radiation section and the quenching section.
Owner:CHINA PETROLEUM & CHEM CORP +1

Method and system for preparing low-carbon olefin from crude oil

ActiveCN112708455ASolve the problem of insufficient gasificationHigh yieldTreatment with plural serial stages onlyEthylene productionChemistryVapor phase
The invention relates to a method and system for preparing low-carbon olefin from crude oil, and the method comprises the following steps: feeding crude oil into a first pipe group of a convection section of a cracking furnace for preheating, and then carrying out vaporization treatment to form a first vapor phase and a first liquid phase; feeding the first liquid phase into the first pipe group of the convection section of the cracking furnace, conducting preheating, and then conducting distilling to form a tower top fraction, a middle fraction and a tower bottom fraction; mixing the tower top fraction, the middle fraction and the first steam phase, feeding a formed mixture into a second pipe group of the convection section of the cracking furnace, conducting heating to a crossing temperature, and feeding the mixture into a radiation section for cracking to obtain cracking gas; and carrying out deep catalytic cracking on the tower bottom fraction to obtain deep catalytic cracking gas, and separating the deep catalytic cracking gas from the cracking gas to obtain the low-carbon olefin. The cracking furnace is matched with a vaporization treatment unit, a distillation unit and a deep catalytic cracking unit, so that the problems that a heavy cracking raw material cannot be fully gasified in a convection section and is easy to coke in a radiation section and a quenching part can be effectively solved.
Owner:CHINA PETROLEUM & CHEM CORP +1

High Efficiency Cokeless Briquette Boiler

A high-efficiency coke-free briquette boiler, including a furnace body, a furnace, a smoke chamber, a high-level water tank, a preheater and a dust collector. Including the outer furnace body, outer water jacket and inner smoke chamber; the furnace includes the combustion zone and the air chamber; the high-level water tank is respectively connected with the outer water jacket and the preheater; the preheater is connected with the water inlet pipe, and the preheater is connected with the inner and lower water jacket Connected; the inner and lower large water jackets are connected with the outer water jacket; the outer water jacket is connected with the outlet pipe; a water level gauge and a water level controller are installed in the high water tank, which are respectively connected with the outer water jacket and the preheater. The present invention utilizes the design features of the water-cooled wall tube and the air chamber, so that there is sufficient air circulation in the furnace, the briquettes are fully burned, and a large amount of nitrogen oxides cannot be formed, which reduces the discharge of nitrogen oxides, reduces urban pollution, and The flame in the combustion area is scattered, and it also solves the problem of easy coking in traditional small hand-burning furnaces. It is an environmentally friendly, high-efficiency and energy-saving new boiler.
Owner:杨飞

Method for preparing polyester spinning melt by removing polyurethane contained in waste polyester textile through alcoholysis of ethylene glycol

The invention relates to a waste polyester high-value circulation reutilization technique, in particular to a method for preparing a polyester spinning melt by removing polyurethane contained in a waste polyester textile through alcoholysis of ethylene glycol. According to the method for preparing the polyester spinning melt by removing the polyurethane contained in the waste polyester textile through the alcoholysis of the ethylene glycol, a waste polyester textile raw material contains the polyurethane, a raw material, in which ethylene glycol with 1% to 8% of the raw material mass is added, is fed to a screw extruder to be blended, melt and extruded, and the melt viscosity of melt from the screw extruder is 0.40 to 0.50 d1 / g; and then the material enters a hardening, tempering and viscosity regulation device, and the melt viscosity of the melt body discharged from the hardening, tempering and viscosity regulation device is 0.635 to 0.685 d1 / g. Due to an alcoholysis manner, the influences on the viscosity, flowing property, fiber saturation property and drafting property of a polyester melt body, and series problems that vacuum pipes and tubular heat exchangers are easy to block due to the existence of spandex (polyurethane) are reduced.
Owner:NINGBO DAFA CHEM FIBER

A method and system for preparing light olefins from crude oil

The invention relates to a method and system for preparing low-carbon olefins from crude oil. The method is carried out as follows: the crude oil is sent to the first tube group in the convection section of the cracking furnace for preheating, and then vaporized to form the first vapor phase and the second steam phase. One liquid phase; the first liquid phase is sent to the first tube group of the convection section of the cracking furnace to be preheated and then distilled to form an overhead fraction, a middle fraction and a bottom fraction; the overhead fraction, the middle fraction and the first After the steam phase is mixed, it is sent to the second tube group of the convection section of the cracking furnace, and after being heated to the crossing temperature, it is sent to the radiation section for cracking to obtain cracked gas; the bottom fraction is subjected to deep catalytic cracking to obtain deep catalytic cracking gas, which is then combined with the The cracked gas is separated to obtain light olefins. The invention adopts cracking furnace to cooperate with vaporization treatment unit, distillation unit and deep catalytic cracking unit, which can effectively solve the problems that heavy cracking raw materials cannot be fully gasified in the convection section and are easy to coke in the radiation section and the quenching section.
Owner:CHINA PETROLEUM & CHEM CORP +1

Oil-gas composite cooling type flame stabilizer and combustion chamber

ActiveCN113898973AShorten the lengthEliminates the problem of easy coking and the need for thermal protectionContinuous combustion chamberCold airCombustion chamber
The invention discloses an oil-gas composite cooling type flame stabilizer and a combustion chamber. The flame stabilizer comprises a flame stabilizer main body, wherein the flame stabilizer main body is divided into a V-shaped section and a straight section by a partition plate; an inner cavity of the V-shaped section is divided into a plurality of layers of oil cooling cavities which are in communication with one another from inside to outside; an inner cavity of the straight section is in communication with a cooling gas guide pipe, and a plurality of through holes used for sending out gas sent by the cooling gas guide pipe are formed in the outer wall of the straight section; and fuel oil passes through the oil cooling cavity and then is vertically injected into the high-temperature main flow through fuel oil injection holes. Cold air enters an air cooling cavity through the cooling gas guide pipe, then part of the cold air forms an air film on the side wall face through air film holes, the rest of the cold air enters the near-wall area of the rear end face of the stabilizer through cold air jet holes to form cold air vortexes, the wall temperature of the straight section of the stabilizer can be reduced, and the oxygen content and combustion efficiency in the wake area of the stabilizer can be improved.
Owner:NANJING UNIV OF AERONAUTICS & ASTRONAUTICS

Process and device for producing tetrachloro-2-cyanopyridine with liquid chromatography

The invention relates to a process for producing tetrachloro-2-cyanopyridine. The process comprises steps as follows: liquid 2-cyanopyridine is preheated, flows into a gas-liquid reinforcement pre-reactor and pre-reacts with chlorine under the action of a pre-reaction catalyst; after the reaction, a gas-phase material is washed and flows into an absorption device to be absorbed; a liquid-phase material after pre-reaction enters a gas-liquid reinforcement main reactor and has a chlorination reaction with the chlorine under the action of a main reaction catalyst; the liquid-phase material discharged from the main reactor is introduced into an evaporator for separation, and finally a tetrachloro-2-cyanopyridine solid is obtained. The process has the advantages that the production flow of tetrachloro-2-cyanopyridine is shortened, and safety and operability of the production process are improved; the utilization rate of the chlorine is increased, and the exhaust gas treatment load is reduced; the chlorination reaction temperature is reduced, the problem that the catalyst is prone to coking is solved, and the service life of the catalyst is prolonged; the yield and content of the product are increased, the difficulty of product purification is reduced, the reaction temperature is low, energy consumption is small; the process is green and environment-friendly.
Owner:NANJING UNIV
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