A method and system for preparing low-carbon olefins

A low-carbon olefin and cracking furnace technology, which is applied in the fields of hydrocarbon cracking to produce hydrocarbons, processing hydrocarbon oil, and hydrocarbon oil processing products, etc., can solve the problems of easy coking, low low-carbon olefin yield, insufficient crude oil vaporization, etc. Yield, the effect of extending the operating cycle

Active Publication Date: 2022-05-24
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The purpose of the present invention is to provide a method and system for preparing low-carbon olefins in order to overcome the problems of insufficient crude oil vaporization, easy coking in the cracking process, and low yield of low-carbon olefins in the prior art. Improve the cracking efficiency of crude oil raw materials, prolong the operation cycle, reduce the coking phenomenon during cracking, and increase the yield of low-carbon olefins in the product at the same time

Method used

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  • A method and system for preparing low-carbon olefins
  • A method and system for preparing low-carbon olefins

Examples

Experimental program
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Effect test

Embodiment 1

[0097] use figure 1 The shown system is carried out, wherein the vaporization treatment unit adopts a cyclone separator, and the cracking furnace is a single furnace cracking furnace, which only contains the first radiant section 3 .

[0098] (1) The crude oil after dehydration and desalting is mixed with superheated steam in the first tube group of the convection section of the cracking furnace, and then preheated to obtain preheated crude oil. The weight ratio of superheated steam to crude oil is 0.70:1. The crude oil continues to be heated to 280°C to become the preheated crude oil.

[0099] (2) The temperature of the preheated crude oil is 280°C, and it is sent to a cyclone separator with internal components (the guide vane type cyclone separator is selected in this embodiment) for vaporization treatment to obtain the first vapor phase and the first liquid phase. Mutually. The separation efficiency of the cyclone is 98%, and the liquid phase in the first vapor phase afte...

Embodiment 2

[0109] use figure 1 The system shown is carried out, wherein the vaporization separation unit adopts a cyclone, and the cracking furnace is a single furnace cracking furnace, which only contains the first radiant section 3 .

[0110] (1) The dehydrated and desalted crude oil is mixed with superheated steam in the first tube group 1 of the convection section of the cracking furnace 4, and then preheated to obtain preheated crude oil. The crude oil continues to be heated to 315°C to become the preheated crude oil.

[0111] (2) The temperature of the preheated crude oil is 315°C, and it is sent to the first cyclone separator 5 with internal components (the guide vane type cyclone separator is selected in this embodiment) for vaporization and separation to obtain the first gas phase and the second cyclone separator. a liquid phase. The separation efficiency of the first cyclone separator 5 is 98%, and the liquid phase in the first gas phase after separation is 150 mg / m 3 .

[...

Embodiment 3

[0120] use figure 1 The system shown is carried out, wherein the vaporization separation unit adopts a cyclone, and the cracking furnace is a single furnace cracking furnace, which only contains the first radiant section 3 .

[0121] (1) The dehydrated and desalted crude oil is mixed with superheated steam in the first tube group 1 of the convection section of the cracking furnace 4, and then preheated to obtain preheated crude oil. The crude oil continues to be heated to 120°C to become the preheated crude oil.

[0122] (2) The temperature of the preheated crude oil is 220°C and the pressure is 0.15MPa, and it is sent to the first cyclone separator 5 with internal components (the guide vane type cyclone separator is selected in this embodiment) for vaporization and separation. a first gas phase and a first liquid phase. The separation efficiency of the first cyclone separator 5 is 98%, and the liquid phase in the first gas phase after separation is 100 mg / m 3 .

[0123] (...

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Abstract

The invention relates to a method and system for preparing low-carbon olefins. The method is carried out as follows: the crude oil is sent to the first tube group of the convection section of the cracking furnace for preheating, and then vapor-liquid separation is performed to form a first vapor phase and a first liquid phase. phase; the first liquid phase is sent to the first tube group of the convection section for preheating, and the preheated first liquid phase is distilled to form a tower top fraction, a middle distillate and a tower bottom fraction; the tower bottom fraction is subjected to hydroprocessing , to obtain circulating hydrogen, light components after hydrogenation and heavy components after hydrogenation; mix the top distillate with the middle distillate, mix with the first vapor phase, and light components after hydrogenation, and send them to the cracking furnace for cracking to obtain a low carbon olefins. The present invention adopts the combination of cracking furnace, vapor-liquid separation unit, distillation unit and hydroprocessing unit, which can effectively solve the problems that the heavy cracking raw material cannot be fully gasified in the convection section and is easy to coke in the radiation section and the quenching section.

Description

technical field [0001] The invention relates to the field of preparation of low-carbon olefins, in particular to a preparation method and system of low-carbon olefins. Background technique [0002] Low-carbon olefins generally refer to the general term for unsaturated hydrocarbons with carbon 4 and below, mainly including ethylene, propylene, isobutylene, butadiene and other organic chemical raw materials with high economic value. With the development of my country's economy, the demand for these organic chemical raw materials is increasing year by year. Although the production scale of low-carbon olefins is also increasing year by year, it cannot meet the increasing demand. [0003] For a long time, my country has been preparing low-carbon olefin products from naphtha. However, in recent years, with the massive exploitation of associated gas in Middle East oilfields and shale gas in the United States, these cheap oil and gas resources have been widely used as ethylene raw ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G69/00C07C4/04C07C11/04C07C11/06C07C11/08C07C11/09
CPCC10G69/00C07C4/04C10G2400/20C07C11/04C07C11/06C07C11/08C07C11/09
Inventor 王国清石莹张利军彭晖张兆斌周丛刘同举蒋冰
Owner CHINA PETROLEUM & CHEM CORP
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