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Method and system for preparing low-carbon olefin from crude oil

A low-carbon olefin and crude oil technology, applied in the field of low-carbon olefin preparation, can solve the problems of short equipment operation period, extended operation period, and easy coking, and achieve the effect of simplifying crude oil utilization route, extending operation period and high yield

Active Publication Date: 2022-05-13
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The purpose of the present invention is to provide a method and system for preparing low-carbon olefins from crude oil in order to overcome the technical problems of low utilization rate of crude oil, easy coking in the process, and short operation period of equipment in the prior art, and the process flow of the method is simple , can improve the cracking efficiency of crude oil raw materials, prolong the operation cycle, reduce the coking phenomenon during cracking, and also increase the yield of low-carbon olefins in the product

Method used

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  • Method and system for preparing low-carbon olefin from crude oil

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Experimental program
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Effect test

Embodiment 1

[0091] (1) Send the crude oil to the first tube group of the convection section of the cracking furnace for preheating, and send it to the high-pressure extraction tower together with light hydrocarbons (propane), wherein, the crude oil is sent to the middle and upper part of the high-pressure extraction tower, and the light hydrocarbons are sent to the upper part of the high-pressure extraction tower. into the lower part of the high-pressure extraction tower for extraction, wherein the weight ratio of light hydrocarbons to crude oil is 6:1, the pressure of the extraction tower is 6MPa, the temperature of the extraction tower is 90°C, and light components are obtained at the top of the tower. Heavy components are obtained at the bottom of the tower;

[0092] (2A) Light components are mixed with water vapor and sent to the second tube group of the convection section of the cracking furnace, and then sent to the radiation section of the cracking furnace after being heated to the ...

Embodiment 2

[0097] (1) Crude oil is sent into the convection section first pipe group of cracking furnace and preheated, and light hydrocarbons (by weight, isobutane 5%, n-butane 95%) are sent into high-pressure extraction tower together, wherein , the crude oil is sent to the middle and upper part of the high-pressure extraction tower, and the light hydrocarbons are sent to the middle and lower part of the high-pressure extraction tower for extraction, wherein the weight ratio of light hydrocarbons and crude oil is 4:1, and the pressure of the extraction tower is 4.5MPa, The temperature of the extraction tower is 155°C, light components are obtained at the top of the tower, and heavy components are obtained at the bottom of the tower;

[0098] (2B) Reduce the pressure of the light components to 1MPa, and separate the gas phase components and liquid phase components; mix the liquid phase components with water vapor and send them to the convection section of the cracking furnace, and heat t...

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Abstract

The invention relates to the field of preparation of low-carbon olefins, and discloses a method and a system for preparing low-carbon olefins from crude oil. The method comprises the following steps: (1) mixing crude oil with light hydrocarbon, and extracting under the condition of high pressure greater than 1MPa to obtain light components and heavy components; (2) mixing the light component with water vapor, feeding into a convection section of a cracking furnace, heating to a crossing temperature, feeding into a radiation section of the cracking furnace, and cracking to obtain a cracking product; (3) performing catalytic thermal cracking on the heavy component to obtain catalytic thermal cracking gas; and (4) mixing the cracking product in the step (2) with the catalytic pyrolysis gas, and separating to obtain a product containing low-carbon olefin. The method provided by the invention is simple in process flow, the cracking efficiency of the crude oil raw material can be improved, the operation cycle can be prolonged, the coking phenomenon during cracking of the crude oil raw material can be reduced, meanwhile, the yield of low-carbon olefins in the product can be improved, and the method has a wide application prospect.

Description

technical field [0001] The invention relates to the field of preparation of low-carbon olefins, in particular to a method and system for preparing low-carbon olefins from crude oil. Background technique [0002] Low-carbon olefins usually refer to the general term of unsaturated hydrocarbons with carbon four or less, mainly including ethylene, propylene, butadiene and other organic chemical raw materials with high economic value. With the development of my country's economy, the demand for these organic chemical raw materials is increasing year by year. Although the production scale of low-carbon olefins is also increasing year by year, it cannot meet the growing demand. [0003] For a long time, naphtha has been mostly used as the main raw material for the preparation of light olefins in my country. However, in recent years, with the massive exploitation of associated gas in oilfields in the Middle East and shale gas in the United States, these cheap oil and gas resources ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G55/06C07C11/04C07C11/06C07C11/167C07C4/10C07C4/18
CPCC10G55/06C07C4/10C07C4/18C07C2529/40C07C11/04C07C11/06C07C11/167
Inventor 石莹王国清刘同举张利军彭晖张兆斌周丛蒋冰
Owner CHINA PETROLEUM & CHEM CORP
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