Polarizing plate equipped with phase difference layer and image display apparatus employing same
A retardation layer and polarizing plate technology, which is applied in identification devices, lighting devices, optics, etc., can solve the problems of reduced optical properties, low optical properties, insufficient optical properties of polarizing plates, etc., and achieve excellent optical properties and excellent handling.
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Embodiment 1
[0194] 1. Fabrication of Polarizing Film
[0195] As the thermoplastic resin substrate, a long amorphous isophthalic acid-copolyethylene terephthalate film (thickness: 100 μm) having a water absorption rate of 0.75% and a Tg of about 75° C. was used. Corona treatment is performed on one side of the resin substrate.
[0196] 100 wt. After adding 13 parts by weight of potassium iodide to each part, it was dissolved in water to prepare an aqueous PVA solution (coating solution).
[0197] The above-mentioned PVA aqueous solution was applied on the corona-treated surface of the resin base material and dried at 60° C. to form a PVA-based resin layer with a thickness of 13 μm to produce a laminate.
[0198] The free end of the obtained laminate was uniaxially stretched 2.4 times in the longitudinal direction (longitudinal direction) between rolls having different circumferential speeds in an oven at 130° C. (assisted in-air stretching treatment).
[0199] Next, the laminated body ...
Embodiment 2
[0216] 1. Fabrication of Polarizing Film
[0217] A polarizing film having a thickness of 5.0 μm was formed on a resin substrate in the same manner as in Example 1 except that the single transmittance (Ts) of the polarizing film was 43.0%.
[0218] 2. Fabrication of polarizing plate
[0219] Except having used the polarizing film obtained in said 1., it carried out similarly to Example 1, and produced the polarizing plate which has the structure of a protective layer / adhesive layer / polarizing film. The single transmittance of the polarizing plate (substantially a polarizing film) was 43.0%, and the degree of polarization was 99.995%.
[0220] 3. Fabrication of the retardation film constituting the retardation layer
[0221] Except having set Re(550) of the retardation film to 144 nm, it carried out similarly to Example 1, and obtained the retardation film.
[0222] 4. Fabrication of polarizing plate with retardation layer
[0223] On the surface of the polarizing film of t...
Embodiment 3-1
[0225] 1. Fabrication of Polarizing Film
[0226] In the same manner as in Example 2, a polarizing film with a thickness of 5.0 μm was formed on the resin substrate.
[0227] 2. Fabrication of polarizing plate
[0228] Use the triacetate cellulose (TAC) film (hard coat thickness 7 μ m, TAC thickness 25 μ m, modulus of elasticity: 3600MPa) with hard coat as protective layer, except that, operate in the same way as in Example 1, make protective Layer / adhesive layer / polarizing film composition of the polarizing plate. The single transmittance of the polarizing plate (substantially a polarizing film) was 43.0%, and the degree of polarization was 99.995%.
[0229] 3. Fabrication of the retardation film constituting the retardation layer
[0230] Operate in the same manner as in Example 1 except that the PMMA of 0.7 parts by mass is melt-kneaded, and the obtained polyester carbonate resin (pellet) is vacuum-dried for 5 hours at 80° C., then, using a single-screw extruder ( Manuf...
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