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Two-way stretching degradable film and preparation method thereof

A biaxially stretched and degradable film technology, which is applied to chemical instruments and methods, flat products, and other household appliances, can solve problems such as heat-sealing strength and surface smoothness, difficulty in degradation, and negative environmental impacts.

Inactive Publication Date: 2021-07-27
HAINAN SHINER IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the traditional polyolefin packaging cigarette film has excellent mechanical properties, thermal properties and interface smoothness, it has a relatively large negative impact on the environment due to its difficulty in degradation
The new degradable cigarette film in response to the new national policy, such as polylactic acid degradable cigarette film, although it meets the degradation requirements, the elongation at break, heat seal strength and surface smoothness of the cigarette film itself are difficult to meet the relevant requirements of the existing cigarette packaging film

Method used

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  • Two-way stretching degradable film and preparation method thereof
  • Two-way stretching degradable film and preparation method thereof
  • Two-way stretching degradable film and preparation method thereof

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preparation example Construction

[0041] The present invention also provides a method for preparing the biaxially oriented degradable film described above, comprising the following steps:

[0042] A) extruding and blending the raw materials of layer A, layer B and layer C respectively according to the ratio of raw materials to obtain the blended material of layer A, the blended material of layer B and the blended material of layer C;

[0043] B) Three-layer co-extrusion of the A-layer blend material, B-layer blend material and C-layer blend material, followed by casting, longitudinal stretching and transverse stretching, to obtain a biaxially stretched degradable film.

[0044] In the present invention, the raw material formulations of the A layer, the B layer and the C layer are consistent with the raw material formulations of the A layer, the B layer and the C layer described above, and will not be repeated here.

[0045]In the present invention, the above-mentioned components are blended and extruded in a t...

Embodiment 1

[0056] The composition of each layer is shown in Table 1:

[0057] Table 1

[0058] A layer composition Mass fraction / % Heat seal masterbatch FS5612 85 Slip agent SAB06554PPR 2 Antisticking agent ABVT22SC 3 Antistatic agent FASPS2955 5 polylactic acid 5 B layer composition Mass fraction / % polylactic acid 80 Initiator (tert-butyl peroxybenzoate) 5 maleic anhydride 15 C layer composition Mass fraction / % Heat seal masterbatch FS5612 88 Anti-sticking agent ABS04S 5 Antistatic agent DS126T 5 polylactic acid 2

[0059] Layer A: Blend the blend of anti-sticking agent ABVT22SC, slip agent SAB06554PPR, antistatic agent FASPS2955 and polylactic acid with heat-sealing masterbatch FS5612 in a twin-screw extruder at 190°C;

[0060] Layer B: under the action of an initiator, polylactic acid and maleic anhydride are blended in a twin-screw extruder at 190°C;

[0061] Layer C: Blend the blen...

Embodiment 2

[0064] Table 2

[0065] A layer composition Mass fraction / % Heat seal masterbatch FS5612 84 Slip agent SAB06554PPR 3 Antisticking agent ABVT22SC 3 Antistatic agent FASPS2955 3 polylactic acid 6 B layer composition Mass fraction / % polylactic acid 85 Initiator (tert-butyl peroxybenzoate) 3 maleic anhydride 12 C layer composition Mass fraction / % Heat seal masterbatch FS5612 87 Anti-sticking agent ABS04S 4 Antistatic agent DS126T 4 polylactic acid 5

[0066] Layer A: Blend the blend of anti-sticking agent ABVT22SC, slip agent SAB06554PPR, antistatic agent FASPS2955 and polylactic acid with heat-sealing masterbatch FS5612 in a twin-screw extruder at 190°C;

[0067] Layer B: under the action of an initiator, polylactic acid and maleic anhydride are blended in a twin-screw extruder at 190°C;

[0068] Layer C: Blend the blend of anti-sticking agent ABS04S, antistatic agent DS126T and ...

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Abstract

The invention provides a two-way stretching degradable film, which comprises a layer A, a layer B and a layer C; wherein the layer A is prepared from, by mass, 83%-85% of heat sealing master batch A, 2%-3% of slipping agent, 2%-3% of anti-sticking agent A, 3%-5% of antistatic agent A and 4%-10% of polylactic acid; the layer B comprises the following raw materials in percentage by mass: 80-90% of polylactic acid, 1-5% of an initiator and 5-15% of maleic anhydride; and the layer C is prepared from the following raw materials in percentage by mass: 85 to 88 percent of heat-sealing master batch C, 2 to 5 percent of anti-sticking agent C and 3 to 5 percent of an antistatic agent C; and 2-10% of polylactic acid. The modified polylactic acid and the modified polypropylene are compounded, so that other properties of the film greatly meet the requirements of the existing cigarette packaging film while the degradable requirement is met. The invention also provides a preparation method of the two-way stretching degradable film.

Description

technical field [0001] The invention belongs to the technical field of polymer films, and in particular relates to a biaxially stretched degradable film and a preparation method thereof. Background technique [0002] BOPP cigarette film is also known as biaxially oriented polypropylene cigarette film, referred to as cigarette film, which is co-extruded and stretched from a variety of polypropylene functional materials. Cigarette film has high transparency and gloss, non-toxic material, stable molecular structure, and has a certain barrier function to odor and moisture, so it is an ideal material for cigarette packaging. [0003] The main components of traditional cigarette films are polyolefins extracted from petroleum, and their degradation will take at least a hundred years, which brings a great burden to the environment. On January 19, 2020, the National Development and Reform Commission and the Ministry of Ecology and Environment issued a new version of the plastic rest...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/32B32B27/36B32B27/18B32B27/30B32B27/08B32B27/06B32B33/00C08J5/18C08L67/04C08L23/14C08K7/20C08K5/55B29D7/01
CPCB32B27/32B32B27/36B32B27/18B32B27/30B32B27/08B32B33/00C08J5/18B29D7/01B32B2250/24B32B2307/31B32B2307/716C08J2367/04C08J2323/14C08K7/20C08K5/55Y02W90/10
Inventor 赵洁邢青涛黎坛王俊峰沈智全
Owner HAINAN SHINER IND
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