Silicon-free rubber outsole and preparation method thereof

A silicone rubber and outsole technology, applied in the field of shoe soles and outsoles, can solve problems such as shoe material damage and affect the normal movement of staff, and achieve the effects of low production cost, convenient control and high production efficiency

Pending Publication Date: 2021-10-01
DONGGUAN ZUNRONG SHOES
View PDF6 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the existing painting environment, the air will be mixed with more organic solvents, and there will be a small amount of liquid organic solvents on the ground. If the staff wear shoes with rubber outsoles in the painting workshop, they will

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Silicon-free rubber outsole and preparation method thereof
  • Silicon-free rubber outsole and preparation method thereof
  • Silicon-free rubber outsole and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A kind of non-silicone rubber outsole, comprises the raw material of following parts by weight:

[0036]

[0037] The preparation method of described nitrile rubber comprises the steps:

[0038] (R1), 70 parts by weight of butadiene, 30 parts of acrylonitrile, 8 parts of fluorine-containing acrylate monomer, 0.8 part of coupling agent, 4 parts of emulsifier, 0.5 part of dodecyl mercaptan, 0.15 part Ferrous sulfate, 0.15 part of 1,3-diketone, 0.15 part of initiator, 0.15 part of polymerization inhibitor sodium nitrite and 250 parts of water, set aside;

[0039] (R2), add fluorine-containing acrylate monomer and coupling agent to acrylonitrile and mix, then add butadiene, water, emulsifier, dodecyl mercaptan, ferrous sulfate and 1,3-diketone in sequence , pre-emulsified for 40min to obtain a pre-emulsion;

[0040] (R3) Add hydrogen peroxide to the pre-emulsion, copolymerize at 10° C. for 2 hours, then add 0.5 part of polymerization inhibitor sodium nitrite and mix to...

Embodiment 2

[0051] A kind of non-silicone rubber outsole, comprises the raw material of following parts by weight:

[0052]

[0053] The preparation method of described nitrile rubber comprises the steps:

[0054] (R1), 60 parts by weight of butadiene, 20 parts of acrylonitrile, 5 parts of fluorine-containing acrylate monomer, 0.5 part of coupling agent, 2 parts of emulsifier, 0.1 part of dodecyl mercaptan, 0.1 part Ferrous sulfate, 0.1 part of 1,3-diketone, 0.1 part of initiator, 0.1 part of polymerization inhibitor sodium nitrite and 200 parts of water, set aside;

[0055] (R2), add fluorine-containing acrylate monomer and coupling agent to acrylonitrile and mix, then add butadiene, water, emulsifier, dodecyl mercaptan, ferrous sulfate and 1,3-diketone in sequence , pre-emulsified for 30 minutes to obtain a pre-emulsion;

[0056] (R3) Add hydrogen peroxide to the pre-emulsion, copolymerize at 1° C. for 1 hour, then add 0.1 part of polymerization inhibitor sodium nitrite and mix to ob...

Embodiment 3

[0067] A kind of non-silicone rubber outsole, comprises the raw material of following parts by weight:

[0068]

[0069] The preparation method of described nitrile rubber comprises the steps:

[0070] (R1), 80 parts by weight of butadiene, 40 parts of acrylonitrile, 10 parts of fluorine-containing acrylate monomer, 1 part of coupling agent, 5 parts of emulsifier, 0.8 part of dodecyl mercaptan, 0.2 part Ferrous sulfate, 0.2 part of 1,3-diketone, 0.2 part of initiator, 0.2 part of polymerization inhibitor sodium nitrite and 300 parts of water, set aside;

[0071] (R2), add fluorine-containing acrylate monomer and coupling agent to acrylonitrile and mix, then add butadiene, water, emulsifier, dodecyl mercaptan, ferrous sulfate and 1,3-diketone in sequence , pre-emulsified for 60 minutes to obtain a pre-emulsion;

[0072] (R3) Add hydrogen peroxide to the pre-emulsion, copolymerize at 15° C. for 3 hours, then add 1 part of polymerization inhibitor sodium nitrite and mix to o...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to the technical field of soles and outsole, in particular to a silicon-free rubber outsole and a preparation method thereof. The silicon-free rubber outsole comprises the following raw materials in parts by weight: 75-100 parts of nitrile rubber, 10-20 parts of butadiene rubber, 5-15 parts of an active agent, 1-2 parts of an anti-aging agent, 5-8 parts of conductive carbon black, 25-45 parts of reinforcing carbon black, 1-3 parts of a dispersing agent, 1-3 parts of PEG-400, 5-10 parts of a plasticizer and 2-6 parts of an adhesive. The silicon-free rubber outsole can ensure the tensile strength, elongation at break, tear strength, wear resistance and aging resistance of a material, and does not contain silicon, so that the situation that the outsole is dissolved by an organic solvent and adhered to the ground in a paint spraying operation environment is avoided.

Description

technical field [0001] The invention relates to the technical field of soles and outsoles, in particular to a silicone-free outsole and a preparation method thereof. Background technique [0002] In the existing painting environment, the air will be mixed with more organic solvents, and there will be a small amount of liquid organic solvents on the ground. If the staff wear shoes with rubber outsoles in the painting workshop, they will be easily contaminated by organic solvents ( Such as acetone, methyl ethyl ketone, cyclohexanone, benzene, n-butanol, styrene, etc.) dissolve and adhere to the ground, causing damage to the shoe material and affecting the normal movement of the staff. Contents of the invention [0003] In order to overcome the shortcomings and deficiencies in the prior art, the object of the present invention is to provide a non-silicone rubber outsole. It is found through research that the use of a silicon-free rubber outsole can avoid being dissolved by or...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L9/02C08L9/00C08L71/02C08K3/04C08K5/12C08K5/3437C08K5/18C08K3/22C08K5/09A43B13/04
CPCC08L9/02A43B13/04C08K2201/001C08K2201/014C08L2201/08C08K2003/2296C08L9/00C08L71/02C08K3/04C08K5/12C08K5/3437C08K5/18C08K3/22C08K5/09Y02T10/86
Inventor 刘伟东
Owner DONGGUAN ZUNRONG SHOES
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products