Preparation method of natural biofilm carrier for surfactant wastewater treatment

A biofilm carrier and surfactant technology, which is applied in the field of preparation of natural biofilm carriers, can solve problems such as microplastic pollution, achieve fast film-hanging speed, high environmental friendliness, and improve the effect of film-hanging efficiency

Active Publication Date: 2021-08-06
SICHUAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method of the present invention has the advantages of simple operation, high economy and environmental friendliness, and the natural biofilm carr

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  • Preparation method of natural biofilm carrier for surfactant wastewater treatment
  • Preparation method of natural biofilm carrier for surfactant wastewater treatment
  • Preparation method of natural biofilm carrier for surfactant wastewater treatment

Examples

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[0026] Example 1

[0027] The gelatin was extracted from the leather abandoned edge angle with alkali-free hydrazine, and 5 G gelatin was added to 50 ml of phosphate buffer (pH = 7.5), stirred at 50 ° C for 30 min, resulting in a homogeneous gelatin aqueous solution. 0.2 g of methacrylic anhydride was then added thereto, and the reaction time was added at 50 ° C for 3 h, and 100 ml of phosphate buffer was added to the end of the reaction to terminate the reaction, and the resulting product was used in a constant temperature incubator in 40 ° C. Deionized water dialysis 3d, freeze dry, and prepared a carbon-carbon double bond (C = C) methacryl-acryloyed modified gelatin.

[0028] A 20 mL of a concentration of 2.5% w / v, a metaphylpropylene-modified gelatin solution was added thereto, and 0.03 G photoinitiator was added thereto, and then the mixed solution was placed under -18 ° C under low temperature conditions to freeze 16 h; then the refrigeration system Placed in ultraviolet l...

Example Embodiment

[0029] Example 2

[0030] The gelatin was extracted from the leather abandoned edge angle with alkali-free hydrazine, and 5 G gelatin was added to 50 ml of phosphate buffer (pH = 7.5), stirred at 50 ° C for 30 min, resulting in a homogeneous gelatin aqueous solution. 0.2 g of methacrylic anhydride was then added thereto, and the reaction time was added at 50 ° C for 3 h, and 100 ml of phosphate buffer was added to the end of the reaction to terminate the reaction, and the resulting product was used in a constant temperature incubator in 40 ° C. Deionized water dialysis 3d, freeze dry, and prepared a methacrylated modified gel containing carbon-carbon double bonds (C = C).

[0031] A 20 mL of a concentration of 2.5% w / v, a metaphylpropylene-modified gelatin solution was added thereto, and 0.03 G photoinitiator was added thereto, and then the mixed solution was placed under -18 ° C under low temperature conditions to freeze 16 h; then the refrigeration system Placed under ultravio...

Example Embodiment

[0032] Example 3

[0033] The gelatin was extracted from the leather abandoned edge angle with alkali-free hydrazine, and 5 G gelatin was added to 50 ml of phosphate buffer (pH = 7.5), stirred at 50 ° C for 30 min, resulting in a homogeneous gelatin aqueous solution. 0.4 g of methacrylic anhydride was added thereto, and the reaction time was 3 h under a 50 ° C water bath, and 100 ml of phosphate buffer was added to the end of the reaction, and the resulting product was used in a constant temperature incubator at 40 ° C. Deionized water dialysis 3d, freeze dry, and prepared a methacrylated modified gel containing carbon-carbon double bonds (C = c).

[0034]A 20 mL of a concentration of 2.5% w / v, a metaphylpropylene-modified gelatin solution was added thereto, and 0.03 G photoinitiator was added thereto, and then the mixed solution was placed under -18 ° C under low temperature conditions to freeze 16 h; then the refrigeration system Placed in ultraviolet light, the light intensit...

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Abstract

The invention provides a preparation method of a natural biofilm carrier for surfactant wastewater treatment. The method mainly comprises the following steps: (1) firstly, extracting gelatin from waste leather leftover materials through alkaline hydrolysis, and then modifying the gelatin by utilizing methacrylic anhydride to prepare modified gelatin with carbon-carbon double bonds on a molecular chain; and (2) preparing the natural biofilm carrier by using the modified gelatin in the step (1) as a raw material through a freezing-ultraviolet radiation polymerization method. The method provided by the invention has the advantages of simple process, high economy and environmental friendliness. The biofilm carrier prepared by the method is a porous material prepared by taking natural biomass as a raw material, so that the problem of micro-plastic pollution caused by synthesizing a polymer biofilm carrier can be avoided; and the structure of the biofilm carrier contains an-glyci argininene-aspartic acid (RGD) sequence capable of promoting microbial adhesion, so that the biofilm carrier has unique advantages as a biofilm carrier and has a good market application prospect.

Description

technical field [0001] The invention relates to the technical field of surfactant wastewater treatment and preparation of natural biofilm carriers, in particular to a preparation method of natural biofilm carriers used for surfactant wastewater treatment. Background technique [0002] As an industrial additive, surfactant is widely used in various industries of the national economy, but the surfactant wastewater produced at the same time also brings ecological and environmental problems. Surfactants are listed as the second type of pollutants in my country, and according to the discharge standards of urban sewage treatment plants in my country, the highest discharge standard is 5 mg / L. Therefore, surfactant wastewater must be effectively treated before it is discharged into the natural environment. The biofilm method is one of the main methods of surfactant wastewater treatment, and its core is to provide a carrier for microorganisms to adhere to, grow and reproduce. [00...

Claims

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Application Information

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IPC IPC(8): C02F3/00B01J13/00C02F103/34
CPCC02F3/00B01J13/0052B01J13/0065B01J13/0069C02F2103/34Y02W10/10
Inventor 林炜何雨静王春华王帅
Owner SICHUAN UNIV
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