Lithium battery pole piece and preparation method and application thereof
A lithium battery and pole piece technology, applied in the field of lithium battery pole pieces and their preparation, can solve the problems of easy deposition of lithium, piercing of lithium battery separator, large volume expansion, etc.
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[0048] An embodiment of the present invention also provides a method for preparing the above-mentioned lithium battery pole piece, including the following steps S110-S150.
[0049] Step S110: Mix the active material, the binder, the conductive agent and the electrode solvent to obtain the active material slurry.
[0050] Step S120: the active substance slurry is uniformly coated on the surface of the current collector, dried, and rolled to obtain a slurry membrane.
[0051] Step S130: uniformly coating the adhesive on the slurry film and drying to obtain an adhesive film with an adhesive layer.
[0052] Step S140: Mix the ceramic powder, dispersant, binder and ceramic solvent, and sieve to obtain a ceramic slurry.
[0053] Step S150: coating the ceramic slurry on the surface of the adhesive membrane, and drying to obtain a lithium battery pole piece.
[0054] The preparation method of the above-mentioned lithium battery pole piece has simple process, low manufacturing cost, ...
Embodiment 1
[0061] The positive pole piece is prepared according to the following steps:
[0062] (1) Add 96.5 parts of NCM622, 0.5 part of conductive carbon black, 1 part of carbon nanotube (hereinafter referred to as CNT), and 2 parts of polyvinylidene fluoride (hereinafter referred to as PVDF) to 33.8 parts of N-methyl Stir evenly in pyrrolidone (hereinafter referred to as NMP) to prepare a uniform positive electrode slurry, and then coat the uniform positive electrode slurry on both sides of a 12 μm aluminum foil, and press 3.5g / cm2 after drying. 3 The compacted density is rolled to obtain the positive electrode sheet.
[0063] (2) Add 10 parts of PVDF into 90 parts of NMP and stir evenly according to parts by mass to prepare a uniform binder slurry. The binder slurry is sprayed on the surface of the positive electrode sheet by means of spin spraying, and then dried to obtain a positive electrode sheet with a binder cluster layer. The binder clusters are distributed in an island sha...
Embodiment 2
[0066] This embodiment is a change made on the basis of Embodiment 1. The difference with Embodiment 1 is that the percentage of the positive electrode sheet binder cluster layer in Embodiment 2 to the surface area of the positive active coating film is 15%, and the viscosity per unit area is 15%. The mass of the cluster layer is 0.5g / m 2 .
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