Ultrahigh-isotropy heat-conducting material of epoxy two-dimensional flaky metal nanofiller and preparation method of heat-conducting material

A flake metal and nanofiller technology, applied in the field of thermal conductive materials, can solve the problems of inapplicability of high-efficiency thermal interface materials, poor thermal conductivity, complex preparation methods, etc., achieve good commercial application prospects, improve thermal conductivity, and preparation methods. simple effect

Active Publication Date: 2021-09-21
SICHUAN UNIV
View PDF10 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] It can be seen from the above that most of the current polymer composite thermal conductive materials filled with metal composite fillers utilize the synergistic effect of different thermal conductive fillers to a certain extent, but their thermal conductivity is still low, usually difficult to exceed 5W / m·K , and the heat conduction is usually anisotropic, and only one direction has good heat conduction performance, while the heat conduction performance in other directions is very poor, and it is difficult to meet higher heat conduction standards and requirements, thus limiting the use of materials Product shape specification and scope of application
In addition, in order to achieve better thermal conductivity, high-cost raw materials are usually selected, and the preparation method is relatively complicated, which is not suitable for the preparation of high-efficiency thermal interface materials that can be used commercially.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Ultrahigh-isotropy heat-conducting material of epoxy two-dimensional flaky metal nanofiller and preparation method of heat-conducting material
  • Ultrahigh-isotropy heat-conducting material of epoxy two-dimensional flaky metal nanofiller and preparation method of heat-conducting material
  • Ultrahigh-isotropy heat-conducting material of epoxy two-dimensional flaky metal nanofiller and preparation method of heat-conducting material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0059] The ultra-high isotropic thermally conductive material of an epoxy-based two-dimensional sheet metal nanofiller in the present embodiment mainly includes the following components in parts by weight:

[0060]

[0061] Wherein, the epoxy resin is selected from bisphenol A type epoxy resin,

[0062] The two-dimensional flake metal nano-fillers are selected from two-dimensional flake metal iron nano-flakes with an average sheet thickness of 100-300 nm and an average outer diameter of 10-15 μm.

[0063] The two-dimensional sheet-like carbon-based thermally conductive filler is selected from two-dimensional sheet-like graphene with an average sheet thickness of 10-50 nm and an average outer diameter of 1-10 μm.

[0064] The diluent is petroleum ether.

[0065] The preparation method of the above-mentioned epoxy-based two-dimensional sheet metal nanofiller ultra-high isotropic thermally conductive material mainly includes the following steps:

[0066] (1) The epoxy resin,...

Embodiment 2

[0071] The ultra-high isotropic thermally conductive material of an epoxy-based two-dimensional sheet metal nanofiller in the present embodiment mainly includes the following components in parts by weight:

[0072]

[0073] Wherein, the epoxy resin is selected from aromatic heterocyclic epoxy resin,

[0074] The two-dimensional flake metal nano-fillers are selected from two-dimensional flake metal silver nano-flakes with an average sheet thickness of 100-200 nm and an average outer diameter of 10-15 μm.

[0075] The two-dimensional flake carbon-based thermally conductive filler is selected from two-dimensional flake micrographite flakes with an average sheet thickness of 50-500 nm and an average outer diameter of 1-10 μm.

[0076] The diluent is ethanol.

[0077] The preparation method of the above-mentioned epoxy-based two-dimensional sheet metal nanofiller ultra-high isotropic thermally conductive material mainly includes the following steps:

[0078] (1) The epoxy resi...

Embodiment 3

[0083] The ultra-high isotropic thermally conductive material of an epoxy-based two-dimensional sheet metal nanofiller in the present embodiment mainly includes the following components in parts by weight:

[0084]

[0085] Wherein, the epoxy resin is selected from bisphenol F type epoxy resin,

[0086] The two-dimensional flake metal nano-fillers are selected from two-dimensional flake metal aluminum nano-flakes with an average sheet thickness of 100-200 nm and an average outer diameter of 10-20 μm.

[0087] The two-dimensional sheet-like carbon-based thermally conductive filler is selected from two-dimensional sheet-like expanded graphite with an average sheet thickness of 50-500 nm and an average outer diameter of 1-10 μm.

[0088] The diluent is n-hexane.

[0089] The preparation method of the above-mentioned epoxy-based two-dimensional sheet metal nanofiller ultra-high isotropic thermally conductive material mainly includes the following steps:

[0090] (1) The epoxy...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Thicknessaaaaaaaaaa
Average outer diameteraaaaaaaaaa
Average outer diameteraaaaaaaaaa
Login to view more

Abstract

The invention provides an ultrahigh-isotropy heat-conducting material of an epoxy two-dimensional flaky metal nanofiller and a preparation method of the heat-conducting material. The material mainly comprises the following components: epoxy resin, a two-dimensional sheet metal nanofiller, a two-dimensional sheet carbon series heat conduction filler and a diluent. The method comprises the following steps: uniformly mixing the components, removing the diluent, and preparing the heat-conducting material or a workpiece through a hot press molding process. The two kinds of two-dimensional sheet-shaped heat-conducting fillers are in lap joint in an epoxy resin matrix to form a three-dimensional heat-conducting network, efficient lap joint and efficient synergistic effect of the two-dimensional sheet-shaped metal nanofiller are achieved, the heat-conducting property of the obtained heat-conducting material or the workpiece is greatly improved, and the isotropic heat-conducting characteristic is achieved.

Description

technical field [0001] The invention belongs to the technical field of thermal conductive materials, and in particular relates to an ultra-high isotropic thermal conductive material of epoxy-based two-dimensional sheet metal nanofillers and a preparation method thereof. Background technique [0002] With the vigorous development of power density in the fields of microelectronics, optoelectronics, and energy harvesting, thermal management problems have become increasingly prominent. Insufficient heat dissipation will cause heat to accumulate in electronic devices, and overheating of electronic devices will shorten the service life of the device, cause damage to the device, or even cause a fire. Therefore, in such fields, thermal management problems need to be optimized and solved urgently. Therefore, the development of high-efficiency thermally conductive materials and the commercial application of this type of thermal interface materials are the keys to solving thermal mana...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L63/02C08K3/08C08K3/04C08K7/24C09K5/14
CPCC08K3/08C08K3/042C08K3/04C08K7/24C09K5/14C08K2003/0856C08K2201/011C08K2201/005C08K2003/0806C08K2003/0812C08K2003/085C08K2003/0862C08L63/00
Inventor 杨双桥王晓彤王琪白时兵
Owner SICHUAN UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products