Polyolefin resin composition and production method thereof
A technology of polyolefin resin and composition, applied in the direction of organic chemistry, which can solve the problems of reduced impact resistance and achieve the effects of reducing color tone, impact resistance and excellent fluidity
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[0211] Hereinafter, the present invention will be described in further detail using examples. Unless otherwise indicated, "%" and "part" in an example mean % by mass and parts by mass, respectively. First, the measurement method of the physical property value will be described.
[0212] Determination of Intrinsic Viscosity
[0213] The intrinsic viscosity (unit: dl / g) is a value measured at a temperature of 135°C by the following method using tetralin as a solvent.
[0214] The reduced viscosity was measured at three points of concentrations of 0.1 g / dl, 0.2 g / dl and 0.5 g / dl using an Ubbelohde viscometer. Using the calculation method described on page 491 of "Polymer Solution, Polymer Experiment Science 11" (published by Kyoritsu Publishing Co., Ltd. in 1982), that is, using the method of plotting the reduced viscosity against the concentration and extrapolating the concentration to zero Extrapolation method to find the intrinsic viscosity.
[0215] Determination of melt ...
manufacture example 1
[0221] Production Example 1: Production of Polyolefin Resin (A-1)
[0222] According to the method described in Example 1 of Japanese Patent Laid-Open No. 2004-182981, a polymerization catalyst was produced, and using the polymerization catalyst, a propylene homopolymer component containing 79 wt. parts, and 21 parts by mass of the polyolefin resin (A-1) of the ethylene-propylene random copolymer component which is an ethylene-type copolymer. The melt flow rate (230° C., 2.16 kg load) of the obtained polyolefin resin was 25 g / 10 minutes. The intrinsic viscosity of the propylene homopolymer component (P portion, propylene-based resin pp1) contained in the polyolefin resin (A-1) was 1.1 dl / g. In addition, the intrinsic viscosity of the ethylene-propylene random copolymer component (EP part, ethylene-based copolymer ep1) is 2.8 dl / g, and the content of the monomer unit derived from ethylene contained in the ethylene-based copolymer ep1 is relative to the ethylene-based copolymer...
manufacture example 2
[0223] Production Example 2: Production of Polyolefin Resin (A-2)
[0224] According to the method described in Example 1 of Japanese Patent Application Laid-Open No. 2004-182981, a polymerization catalyst was produced, and using the polymerization catalyst, a propylene homopolymer component containing 89 wt. parts, and polyolefin resin (A-2) of 11 parts by mass of the ethylene-propylene random copolymer component which is an ethylene-based copolymer. The melt flow rate (230° C., 2.16 kg load) of the obtained polyolefin resin was 98 g / 10 minutes. The intrinsic viscosity of the propylene homopolymer component (P portion, propylene-based resin pp2) contained in the polyolefin resin (A-2) was 0.79 dl / g. In addition, the intrinsic viscosity of the ethylene-propylene random copolymer component (EP part, ethylene-based copolymer ep2) is 7.0 dl / g, and the content of the monomer unit derived from ethylene contained in the ethylene-based copolymer ep2 is relative to the ethylene-based...
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