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High aromatic hydrocarbon oil as well as preparation method and application thereof

A technology of high aromatics and oil materials, which is applied in the treatment of hydrocarbon oils, only multi-stage series refining and cracking process treatment, petroleum industry, etc., can solve the problems of high equipment investment and operating costs, reduce production rate, increase aromatics content, The effect of increasing economic benefits

Pending Publication Date: 2022-01-07
SHANGHAI NAKE AUXILIARIES +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] CN112725031A discloses a kind of "oil suitable for the production of needle coke and its preparation method and system", in which catalytic cracking oil slurry or catalytic cracking clarified oil or other raw materials are fractionated through a distillation tower to obtain crude wax oil and tower bottom oil, and then Four times of steam stripping, hydrogenation, polycondensation and other processes to obtain needle coke raw materials, equipment investment and operating costs are very high
Even if the scheme is feasible, it is only suitable for deep single-pass cracking without producing oil slurry macromolecular components, not to mention that there is no public report on the method of increasing the reaction depth that can achieve such a purpose

Method used

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  • High aromatic hydrocarbon oil as well as preparation method and application thereof
  • High aromatic hydrocarbon oil as well as preparation method and application thereof
  • High aromatic hydrocarbon oil as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0076] Such as figure 1 As shown, FCC feed oil and catalytic cracking / cracking catalyst are subjected to catalytic cracking / cracking reaction in riser reactor 7 to form reaction oil gas. The operating conditions of the catalytic cracking / cracking reaction are shown in Table 2 below.

[0077] Such as figure 1 As shown, the reaction oil gas from the reaction unit is fed below the washing and desuperheating section of the catalytic cracking / cracking fractionator 2, and the reaction oil gas and the FCC feed oil are fully contacted in the washing and desuperheating section 13 to elute the reaction oil gas Catalyst powder contained in. The operating conditions of the fractionation tower are shown in Table 2 below.

[0078] In the fractionation tower, high-aromatic oil, heavy diesel oil (as required) and light diesel oil are extracted sequentially from bottom to top, and gasoline, liquefied gas and dry gas are separated after passing through a subsequent gas-liquid separator and...

Embodiment 2-4

[0080] According to the conditions described in Table 2, the steps similar to those described in Example 1 were used to prepare high aromatics oil. The product distribution of Examples 2-4 can be seen in Table 2 below. Moreover, the properties of the high aromatics oil produced in Examples 2-4 are shown in Table 2 below.

[0081] Table 2

[0082]

[0083]

Embodiment 5

[0094] According to the conditions described in Table 4, the steps similar to those described in Example 1 were used to prepare high aromatics oil. The product distribution of Example 5 can be seen in Table 4 below. Moreover, the properties of the high aromatics oil produced in Example 5 are shown in Table 4 below.

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PUM

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Abstract

The invention relates to high aromatic hydrocarbon oil as well as a preparation method and application thereof. The method comprises the following steps: (1) carrying out catalytic cracking / cracking reaction on less than or equal to 99 wt% of FCC raw oil to generate oil gas; (2) introducing the oil gas below a washing and desuperheating section of a fractionating tower, and carrying out countercurrent contact with more than or equal to 1 wt% of residual FCC raw oil so as to elute catalyst powder; (3) the eluted oil gas rising along the fractionating tower, entering a plate section of the fractionating tower and is in countercurrent contact with reflux liquid; (4) extracting a high aromatic hydrocarbon oil from the side stream, wherein the high aromatic hydrocarbon oil contains ash less than 20 mu g / g; (5) carrying out catalytic cracking / cracking reaction on washing raw oil containing catalyst powder and the FCC raw oil in the step (1) to generate oil gas; and (6) repeating the steps (2)-(5) to form a cycle, wherein the catalytic cracking / cracking catalyst comprises a macroporous in-situ crystallization catalytic cracking catalyst, and more than or equal to 97 wt% of the oil gas enters the high aromatic hydrocarbon oil extraction plate. The method is simple in process and low in equipment investment, and the operation cost can be greatly reduced.

Description

technical field [0001] The invention relates to the field of petroleum refining, in particular to a high-aromatic oil material prepared by catalytic cracking / cracking, a preparation method and application thereof. [0002] technical background [0003] Catalytic cracking / cracking is one of the most important lightening processes and the main source of profit in the oil refining industry. Its main products are divided into gasoline, diesel, liquefied gas, dry gas, oil slurry and other products through fractionation towers and absorption stabilization systems. In the early years of catalytic cracking of wax oil, due to the light raw material and low yield of oil slurry, the oil slurry was basically used for refining, and no oil slurry product was produced. The current catalytic cracking / cracking unit basically adopts heavy raw materials, in which the oil slurry yield is high, and full or most of the back refining will lead to a high coke yield in the system, which reduces the ...

Claims

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Application Information

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IPC IPC(8): C10G55/06
CPCC10G55/06C10G2300/70
Inventor 陆明全陆善祥李明晖
Owner SHANGHAI NAKE AUXILIARIES