Film for forming protective film, composite sheet for forming protective film, and method for manufacturing semiconductor chip with protective film
A protective film, semiconductor technology, applied in semiconductor/solid-state device manufacturing, chemical instruments and methods, film/sheet release liners, etc., can solve problems such as increased production efficiency, excessive curing temperature, obstacles, etc.
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Embodiment 1
[0199] The following components were mixed in the compounding ratio (mass ratio; converted to solid content) shown in Table 1, diluted with methyl ethyl ketone so that the solid content concentration was 54% by mass, and a coating agent for forming a protective film was prepared.
[0200] (a) UV curable component: an acrylic polymer (weight average molecular weight: 400,000, glass transition temperature: -10°C) with a UV curable group introduced into the side chain, which is relative to 2-hydroxyhexyl acrylate 80 parts by mass and 20 parts by mass of 2-hydroxyethyl acrylate are copolymerized with 100 moles of hydroxyl groups derived from 2-hydroxyethyl acrylate, and 80 moles of methacryloyloxyethyl obtained by the reaction of isocyanates.
[0201] (b1) Red coloring agent: diketopyrrolopyrrole red pigment (manufactured by Sanyo Color Co., Ltd., PigmentRed 264)
[0202] (b2) Black coloring agent: carbon black (manufactured by Mitsubishi Chemical Corporation, #MA600B, average pa...
Embodiment 2~3
[0208] [Examples 2-3, Comparative Examples 1-2]
[0209] Except having changed the kind and compounding quantity of each component which comprises a protective film forming film to what is shown in Table 1, it carried out similarly to Example 1, and manufactured the sheet|seat for protective film formation.
[0210] In addition, the value W / T which divided the content W (mass %) of the coloring agent by the thickness T (micrometer) of a protective film forming film in each example was calculated, and it shows in Table 1.
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