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Piezoelectric film

A piezoelectric thin film, piezoelectric body technology, applied in the direction of circuits, piezoelectric/electrostrictive transducers, piezoelectric devices/electrostrictive devices, etc., can solve the trouble of carrying, damage lightness and flexibility, and cannot Sufficiently achieve thinning and other issues, and achieve the effects of preventing defects, good acoustic characteristics, and good durability

Pending Publication Date: 2022-02-08
FUJIFILM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if such a speaker is intended to be built into the above-mentioned thin display, it cannot be sufficiently thinned, and lightness and flexibility may be impaired.
Also, when the speaker is installed externally, it is troublesome to carry, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0280] pass Figure 2 to Figure 5 The shown method to fabricate the piezoelectric film.

[0281] First, cyanoethylated PVA (CR-V manufactured by Shin-Etsu Chemical Co., Ltd.) was dissolved in dimethylformamide (DMF) at the following composition ratio. Then, PZT particles were added as piezoelectric particles in the following composition ratio to this solution, and stirred using a propeller mixer (rotational speed: 2000 rpm) to prepare a coating material for forming a piezoelectric layer.

[0282] ・PZT particles 300 parts by mass

[0283] ·Cyanoethylated PVA...30 parts by mass

[0284] ·DMF················· 70 parts by mass

[0285] In addition, as the PZT particles, a mixture obtained by wet-mixing powders of Pb oxide, Zr oxide, and Ti oxide as main components with a ball mill so that Zr = 0.52 mol and Ti = 0.48 mol with respect to Pb = 1 mol was used. PZT particles were crushed after the powder was fired at 800°C for 5 hours.

[0286] On the other hand, a sheet in which ...

Embodiment 2~ Embodiment 9

[0311] [Example 2 to Example 9, Example 11 to Example 16, Example 18 to Example 20, and Comparative Example 1 to Comparative Example 4]

[0312] In the formation of the upper laminated body and the lower laminated body, the upper laminated body and the lower laminated body were formed in the same manner as in Example 1, except that the coating thickness of the coating material for forming the piezoelectric layer and the conditions of the rolling treatment were variously changed. laminated body, thereby producing a piezoelectric film.

[0313] For the produced piezoelectric film, the porosity of the upper region and the porosity of the lower region were measured in the same manner as in Example 1, and the porosity ratio and average porosity were calculated.

Embodiment 10

[0315] In the same manner as the formation of the upper laminate in Example 1, except for changing the coating thickness of the coating material for forming the piezoelectric layer and the conditions of the rolling treatment, a laminate having a lower protective layer, a lower electrode, and rolling treatment was produced. and a laminate of polarized piezoelectric layers.

[0316] In addition, the temperature of the heating roll was set at 60° C., the pressing force of the heating roll was set at 0.05 MPa, and the moving speed of the heating roll was set at 3 m / min to perform calendering 30 times.

[0317] A sheet having the same upper electrode and upper protective layer as in Example 1 was stacked on the manufactured laminate so that the upper electrode and the piezoelectric layer faced each other (refer to Figure 6 ).

[0318] Next, using a laminator, the laminated body and the laminated body of the sheet were subjected to thermocompression bonding at a temperature of 120...

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Abstract

The present invention addresses the problem of providing a piezoelectric film capable of materializing an electroacoustic transduction film or the like that is highly durable and capable of producing an adequate level of sound pressure in response to an input operating voltage. This problem is solved by a piezoelectric film that has a polymeric composite piezoelectric material in which piezoelectric particles are included in a matrix containing a polymeric material; and electrode layers provided to both surfaces of the polymeric composite piezoelectric material, wherein when the polymeric composite piezoelectric material is divided in the thickness direction into two equal regions while a thickness-direction cross-sectional surface thereof is being observed under an electron scanning microscope, and when a measurement is made of porosity in the two regions, the ratio obtained by dividing the porosity in the region having a higher porosity by the porosity in the region having a lower porosity is 1.2 or higher.

Description

technical field [0001] The present invention relates to a piezoelectric film used for an electroacoustic transducing film and the like. Background technique [0002] In response to thinner and lighter displays such as liquid crystal displays and organic EL (Electro Luminescence) displays, thinner and lighter speakers are also required for these thin displays. In addition, in response to the development of flexible displays using flexible substrates such as plastics, flexibility is also required for speakers used in flexible displays. [0003] Conventional loudspeakers generally have a funnel-like so-called cone shape, a spherical dome shape, or the like. However, if such a speaker is to be incorporated in the above-mentioned thin display, the thickness reduction cannot be achieved sufficiently, and light weight and flexibility may be impaired. Also, when the speaker is mounted externally, it is troublesome to carry it around. [0004] Therefore, as a thin speaker that can...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H04R7/20H01L41/43H04R17/00H01L41/047H01L41/09H01L41/18
CPCH04R17/005H10N30/883H10N30/852H04R7/20H04R17/00H10N30/87H10N30/85H10N30/2047H10N30/874H10N30/857
Inventor 玉田芳纪
Owner FUJIFILM CORP