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CO2 adsorbent based on multi-source solid waste modification and preparation method and application thereof

An adsorbent and modification technology, which is applied in the direction of separation methods, chemical instruments and methods, and other chemical processes, can solve the problems of capture cost and cycle adsorption performance, weak cycle adsorption capacity, safety and environmental protection hazards, etc. Achieve harmless treatment, improve adsorption performance, and low cost

Pending Publication Date: 2022-03-04
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the raw material cost of the above two adsorbents is high, the preparation process is complicated, and the cycle adsorption capacity is weak.
[0004] With the rapid development of industry, the disposal of solid waste generated in the industrial production process has always been a difficult problem. At present, industrial solid waste is mainly stored for disposal, but the accumulation of a large amount of solid waste not only occupies land resources, but also poses safety hazards during the storage process. and environmental protection hazards, the harmless treatment of industrial solid waste is the main problem of current research
[0005] In summary, CO 2 The low-cost capture and high capture performance are still the focus of researchers, although the current research has achieved some remarkable results, but the CO 2 The capture cost and cycle adsorption performance of CO2 still need to be improved. Therefore, it is urgent to develop a CO 2 Adsorbent for efficient capture and harmless treatment of industrial solid waste

Method used

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  • CO2 adsorbent based on multi-source solid waste modification and preparation method and application thereof
  • CO2 adsorbent based on multi-source solid waste modification and preparation method and application thereof
  • CO2 adsorbent based on multi-source solid waste modification and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] This example provides a CO based on multi-source solid waste modification 2 The preparation method of adsorbent, described preparation method comprises the following steps:

[0050] (1) Limestone was immersed in 1mol / L NaCl solution for 2 hours, calcined at 1000°C at a heating rate of 5°C / min for 2h, and then ball milled at a speed of 300r / min for 25min to obtain an adsorbent;

[0051] (2) Al 2 o 3 Dry at 130°C for 2 hours, ball mill at 300r / min for 25 minutes, and 1g of Al after ball milling 2 o 3 Mixed with 9g of the adsorbent described in step (1), the obtained mixture was ball milled at 300r / min for 25min, and then calcined at 800°C for 2h at a heating rate of 5°C / min to obtain the CO 2 Adsorbent.

Embodiment 2

[0053] This example provides a CO based on multi-source solid waste modification 2 The preparation method of adsorbent, described preparation method comprises the following steps:

[0054] (1) Limestone was immersed in 1mol / L NaCl solution for 2 hours, calcined at 1000°C at a heating rate of 5°C / min for 2h, and then ball milled at a speed of 300r / min for 25min to obtain an adsorbent;

[0055] (2) MgO was dried at 130° C. for 2 h, ball milled at 300 r / min for 25 min, 1 g of MgO after ball milling was mixed with 9 g of the adsorbent described in step (1), and the obtained mixture was ball milled at 300 r / min for 25 min, Then calcined at 800°C for 2h at a heating rate of 5°C / min to obtain the CO 2 Adsorbent.

Embodiment 3

[0057] This example provides a CO based on multi-source solid waste modification 2 The preparation method of adsorbent, described preparation method comprises the following steps:

[0058] (1) Limestone was immersed in 1mol / L KCl solution for 3 hours, calcined at 900° C. for 2 hours at a heating rate of 3° C. / min, and then ball milled at 400 r / min for 20 minutes to obtain an adsorbent;

[0059] (2) Al 2 o 3 Dry at 125°C for 2 hours, ball mill at 400r / min for 20 minutes, and 1g of Al after ball milling 2 o 3 Mixed with 9g of the adsorbent described in step (1), the obtained mixture was ball milled at 400r / min for 20min, and then calcined at 850°C for 2h at a heating rate of 3°C / min to obtain the CO 2 Adsorbent.

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Abstract

The invention relates to a CO2 adsorbent based on multi-source solid waste modification as well as a preparation method and application thereof, the preparation method comprises the following steps: (1) sequentially performing dipping treatment and calcining treatment on multi-source solid waste to obtain an adsorbent; and (2) drying an oxide, mixing the dried oxide with the adsorbent in the step (1), and calcining the obtained mixture to obtain the CO2 adsorbent. The preparation method is low in cost, simple in process, environmentally friendly, free of secondary pollution and suitable for CO2 capture of high-temperature industrial flue gas; according to the present invention, the adsorption performance can be improved after the multi-source solid waste is subjected to the salt solution immersion treatment, the multi-source solid waste adsorbent is modified by using the oxide so as to improve the adsorption performance, the high temperature sintering resistance and the cyclic adsorption performance of the adsorbent, and the efficient CO2 capture and the harmless treatment of the industrial solid waste are achieved.

Description

technical field [0001] The invention belongs to the technical field of adsorbents and relates to CO 2 Capture adsorbent, specifically related to a CO based on multi-source solid waste modification 2 Adsorbent and its preparation method and application. Background technique [0002] With the rapid development of economy and society, particulate matter in the atmosphere, SO 2 , NO x and CO 2 Pollutants such as pollutants continue to increase and have a serious impact on environmental quality. Current particulate matter, SO 2 and NO x The control technology has become increasingly mature, reducing CO 2 Emissions are key to improving air quality. Adsorption is a commonly used CO 2 The capture method is widely used because of its advantages of simple process, low energy consumption, and no corrosion. [0003] CN109201007A discloses a carbon dioxide adsorbent and its preparation method and application. The adsorbent is composed of organic amine, ionic liquid and biomass ...

Claims

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Application Information

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IPC IPC(8): B01J20/04B01J20/06B01J20/08B01J20/30B01J20/32B01D53/02
CPCB01J20/06B01J20/08B01J20/041B01J20/3078B01J20/3202B01D53/02B01D2257/504B01D2258/0283B01J2220/4875B01J2220/4887Y02C20/40
Inventor 朱廷钰郭旸旸罗雷
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI
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