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Method for treating hematite deironing tail gas

A hematite and tail gas technology, applied in the metallurgical field, can solve the problems of reducing the start-up rate, high solid content of the washing liquid, and large amount of fresh water, etc., and achieves the effect of improving the recycling rate, improving the washing efficiency and reducing the cleaning frequency.

Pending Publication Date: 2022-04-15
云锡文山锌铟冶炼有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the traditional tail gas scrubbing method, the direction of liquid and solid is reaction kettle, flash tank exhaust → exhaust scrubber → washing liquid storage tank → 1# cooling water storage tank → cooling fan → 2# cooling water storage tank → exhaust steam scrubber , with this cycle, the disadvantage of this traditional washing method is that the solid particles in the washing liquid cannot be discharged from the washing system, resulting in higher and higher solids in the washing liquid, poor cleaning effect of the tail gas, large amount of new water, and serious slag accumulation in the tail gas washing system. Reduce the start-up rate, which is not conducive to the control of the volume balance of the wet system and affects the production operation
[0003] Therefore, the washing method of the existing hematite iron removal tail gas needs to be improved

Method used

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  • Method for treating hematite deironing tail gas
  • Method for treating hematite deironing tail gas
  • Method for treating hematite deironing tail gas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Step 1: Send the hematite iron removal tail gas to the exhaust scrubber and use the produced water as the washing liquid for spraying to obtain the first washed gas and the washed liquid containing solid particles, wherein the hematite iron removal tail gas O 2 with Fe 2+ A mixture of residual gases and vapors after a reaction. The hematite iron removal tail gas includes O 2 , Fe 2 o 3 、H 2 SO 4 , ZnSO 4 Wait. The solid content of the hematite iron removal tail gas is 5g / L. The flow ratio of hematite iron removal tail gas to washing liquid is 1000:1;

[0046] Step 2: supplying the above-mentioned first scrubbed gas to the Venturi tube for intensive scrubbing to obtain the second scrubbed gas;

[0047] Step 3: supply the above-mentioned second washed gas to a gas-liquid separator for gas-liquid separation, obtain separated gas and separated liquid, and empty the separated gas;

[0048] Step 4: supply the washed liquid obtained in step 1 to a settling tank for ...

Embodiment 2

[0052] Step 1: Send the hematite iron removal tail gas to the exhaust scrubber and use the produced water as the washing liquid for spraying to obtain the first washed gas and the washed liquid containing solid particles, wherein the hematite iron removal tail gas O 2 with Fe 2+ A mixture of residual gases and vapors after a reaction. The hematite iron removal tail gas includes O 2 , Fe 2 o 3 、H 2 SO 4 , ZnSO 4 Wait. The solid content of the hematite iron removal tail gas is 3g / L. The flow ratio of hematite iron removal tail gas to washing liquid is 1200:1;

[0053] Step 2: supplying the above-mentioned first scrubbed gas to the Venturi tube for intensive scrubbing to obtain the second scrubbed gas;

[0054] Step 3: supply the above-mentioned second washed gas to a gas-liquid separator for gas-liquid separation, obtain separated gas and separated liquid, and empty the separated gas;

[0055] Step 4: supply the washed liquid obtained in step 1 to a settling tank for ...

Embodiment 3

[0059] Step 1: Send the hematite iron removal tail gas to the exhaust scrubber and use the produced water as the washing liquid for spraying to obtain the first washed gas and the washed liquid containing solid particles, wherein the hematite iron removal tail gas O 2 with Fe 2+ A mixture of residual gases and vapors after a reaction. The hematite iron removal tail gas includes O 2 , Fe 2 o 3 、H 2 SO 4 , ZnSO 4 Wait. The solid content of the hematite iron removal tail gas is 7g / L. The flow ratio of hematite iron removal tail gas to washing liquid is 900:1;

[0060] Step 2: supplying the above-mentioned first scrubbed gas to the Venturi tube for intensive scrubbing to obtain the second scrubbed gas;

[0061] Step 3: supply the above-mentioned second washed gas to a gas-liquid separator for gas-liquid separation, obtain separated gas and separated liquid, and empty the separated gas;

[0062] Step 4: supply the washed liquid obtained in step 1 to a settling tank for s...

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PUM

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Abstract

The invention discloses a method for treating hematite deironing tail gas, which comprises the following steps: contacting the hematite deironing tail gas with washing liquid to obtain first washed gas and washed liquid containing solid particles, and washing the first washed gas to obtain second washed gas, and performing gas-liquid separation on the second washed gas to obtain separated gas and separated liquid, settling the washed liquid containing the solid particles to obtain supernatant and underflow, cooling the supernatant to obtain cooled liquid, and circulating the cooled liquid as a washing liquid. The hematite deironing tail gas is treated by adopting the method, solid particles in tail gas washing liquid can be discharged out of a washing system, and the solid content of the hematite deironing tail gas washing system is reduced, so that the tail gas washing effect is improved, the washing efficiency is improved, and stable operation of the system is facilitated.

Description

technical field [0001] The invention belongs to the field of metallurgy, and in particular relates to a method for treating hematite iron removal tail gas. Background technique [0002] In the zinc hydrometallurgy process, iron removal methods mainly include jarosite method, goethite method and hematite method. Using hematite method to remove iron has the advantages of high leaching rate of zinc and associated metals, good comprehensive recovery, and high yield. Less amount of slag, good filterability of slag, high iron content in slag (Fe≥56%) and other advantages; while iron removal by hematite method will produce a large amount of exhaust gas entrained with solid particles, which needs to be purified. In the traditional tail gas scrubbing method, the direction of liquid and solid is reaction kettle, flash tank exhaust → exhaust scrubber → washing liquid storage tank → 1# cooling water storage tank → cooling fan → 2# cooling water storage tank → exhaust steam scrubber , w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/78B01D53/46B01D47/02
Inventor 李鹏宋永平朱北平陶家荣成世雄陈玉朴俞凌飞王私富李云张朋胡坤孙如波
Owner 云锡文山锌铟冶炼有限公司
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