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Method for regenerating SCR (Selective Catalytic Reduction) denitration catalyst by on-line semi-dry method

A denitration catalyst, semi-dry technology, applied in chemical instruments and methods, separation methods, gas treatment and other directions, can solve the problems of long construction period, high consumption of raw materials, high regeneration cost, and achieve extended life, obvious environmental benefits, The effect of suppressing conversion rates

Pending Publication Date: 2022-04-19
SUZHOU XIRE ENERGY SAVING ENVIRONMENTAL PROTECTION TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The regeneration method of the catalyst workshop is mature and the regeneration effect is good, but there are also the following problems: (1) The regeneration process involves catalyst disassembly, hoisting, round-trip transportation, workshop regeneration, etc., and the construction period lasts for a long time
Taking the regeneration of a single 300MW unit with two layers of catalyst as an example, the regeneration period is about 35 days; (2) There are many links involved in the regeneration process, the consumption of raw materials is large, the energy consumption is large, and the regeneration cost is high; (3) The catalyst is in the workshop During the regeneration process, a large amount of waste water, dust, waste gas and other pollutants will be generated, which will easily cause secondary pollution and bring new environmental problems

Method used

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  • Method for regenerating SCR (Selective Catalytic Reduction) denitration catalyst by on-line semi-dry method
  • Method for regenerating SCR (Selective Catalytic Reduction) denitration catalyst by on-line semi-dry method

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Embodiment 1

[0052] The catalyst in the SCR denitrification device of a 300MW coal-fired unit adopts a "2+1" layer arrangement, and two layers of 18-hole catalyst are initially installed. The length of the catalyst is 800mm, and the volume of the catalyst in the initial layer is 280m 3 . The soot blower is a combination of rake steam soot blower and sonic soot blower. After 32,000 hours of operation, the catalyst activity of the initial layer dropped from the initial 39.1m / h to 26.3m / h. After a comprehensive evaluation, the on-line semi-dry method is used to regenerate the catalyst, including the following steps:

[0053] Before shutting down, use the existing rake steam soot blower to carry out continuous blowing for 90 minutes, and the blowing pressure is 1.8 MPa; after stopping, use the sonic soot blower to blow soot for 12 hours. Fly ash away. After the sootblower is out of service, open the manhole door and the hoisting door, remove the steam sootblower and its auxiliary pipelines, ...

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Abstract

The invention discloses a method for regenerating an SCR (Selective Catalytic Reduction) denitration catalyst by an online semi-dry method. The method comprises the following steps: cleaning accumulated dust in an SCR denitration reactor; evaluating whether the ash removal effect reaches the standard or not; replacing and repairing the damaged catalyst unit body; drying and dehumidifying the catalyst; the active substance loading liquid is atomized, sprayed and loaded on the surface of the catalyst; active substances loaded on the catalyst are heated and cured by clean hot air; hardening the end face of the catalyst, and resetting a soot blower and accessory equipment; and performing high-temperature operation activation. Active substances of the SCR denitration catalyst can be supplemented online, the activity of the catalyst can be improved in a short time, the catalyst does not need to be disassembled, assembled, hoisted, transported, calcined and the like, the regeneration period can be greatly shortened, the construction period is only 1 / 4-1 / 2 of that of a traditional method, the method has the advantages of being time-saving, efficient, energy-saving, environment-friendly and the like, no waste water is generated in the regeneration process, and the method is suitable for industrial production. The problem of secondary pollution is not worried about, and obvious environmental benefits are achieved.

Description

technical field [0001] The invention belongs to the technical field of air pollutant treatment, and in particular relates to an online semi-dry method for regenerating an SCR denitrification catalyst. Background technique [0002] As the country restricts the concentration of NOx emissions in flue gas more and more strictly, SCR denitrification, as a denitrification technology with high efficiency, good selectivity and mature technology, is currently being used in thermal power plants, industrial boilers, steel sintering machines, glass kilns Widely used in many thermal equipment. The denitrification catalyst is the core of the SCR denitrification device, and its performance directly affects the denitrification efficiency. [0003] During the use of SCR denitrification catalyst, the activity will be reduced due to factors such as wear, flow channel blockage, active material loss, micropore blockage, low temperature poisoning, etc., which will lead to a decrease in denitrifi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/96B01D53/90B01D53/86B01D53/56
CPCB01D53/96B01D53/90B01D53/8631B01D53/8628B01D2258/0283
Inventor 吴国勋王丽朋孔凡海张发捷卞子君何川李乐田李昂王乐乐杨晓宁马云龙姚燕雷嗣远王凯鲍强卿梦磊
Owner SUZHOU XIRE ENERGY SAVING ENVIRONMENTAL PROTECTION TECH CO LTD
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