Method for recovering gallium from brown aluminum oxide dust collecting material
A technology of corundum and brown corundum, applied in the field of recovering gallium from brown corundum dust collection material, can solve the problems of waste, waste of resources, shelving of resources, etc., and achieve the effects of pollution-free purity, increase leaching rate, and reduce discharge.
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[0031] The specific embodiment of the inventive method is as follows:
[0032] (1) Mix 5Kg of brown corundum dust collection powder with gallium content of 0.18% and 500g of potassium pyrosulfate evenly. Then carry out roasting treatment, the roasting temperature is 400℃, and the roasting time is 2h;
[0033] (2) leaching the calcined product in step (1) with 10L aqueous solution, the leaching temperature is 70°C, and the leaching time is 60min, after filtering and separating impurities, the obtained gallium sulfate solution is added with 5L, 30% sodium hydroxide;
[0034] (3) Heating and concentrating the solution to 3000ml, the content of gallium in the solution is 2.52g / L, the solution is kept at a constant temperature of 45°C, electrolyzed by direct current, the electrolysis voltage is 10V, the electrolysis current density is 400mA / L, and the electrolysis time is 4.5h, to obtain 4N metal gallium.
[0035] After measurement, in the above embodiment, 7.69 g of metal galliu...
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