Titanium oxide-containing material and process for preparing the same
A manufacturing method and technology of titanium oxide, applied in the direction of titanium dioxide, chemical instruments and methods, titanium oxide/hydroxide, etc., can solve the problems of titanium oxide falling off, affecting material properties, and titanium oxide deterioration.
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Embodiment 1
[0042] Titanium oxide was introduced into synthetic fibers (type: polyester fibers) and synthetic fibers containing titanium oxide were produced in the following procedure.
[0043] First, titanium tetrafluoride is dissolved in water at a ratio of 2.0% owf. The above-mentioned synthetic fibers were immersed in the aqueous solution, and treated at normal temperature for 30 minutes. Then, a mixture of boric acid: citric acid: D, L-malic acid = 0.5: 1: 1 was added to the above aqueous solution at a ratio of 0.5% owf, and treated at 50°C for 30 minutes . At this point the pH of the solution was 3. Then, washing with water was carried out to obtain the desired titanium oxide-containing synthetic fiber.
[0044] The synthetic fibers containing titanium oxide thus obtained were investigated for their antibacterial properties, deodorizing properties, antifouling properties, and shedding of titanium oxide by the following methods.
[0045] (antibacterial)
[0046] The investigatio...
Embodiment 2
[0066] In addition to using stainless steel (20cm 2 ) to replace the polyester fiber, the remaining titanium oxide was introduced into the surface of the stainless steel according to the same method as in the above-mentioned Example 1. Then, the stain resistance and deodorization properties of the stainless steel were investigated in the same manner as above. The results are shown in Table 5 and Table 6 below. In Table 6 below, the treated stainless steel represents the titanium oxide-containing stainless steel of Example 2, and the untreated stainless steel represents stainless steel that has not been treated with titanium oxide.
[0067] table 5
[0068] (deodorization)
[0069] early stage
[0070] Table 6
[0071] (fouling resistance)
[0072] initial coloring
[0073] From the results of Table 5 and Table 6 above, it can be seen that the titanium oxide-treated stainless steel has excellent antifouling and deodorizing properties. It was also c...
Embodiment 3
[0075] Using titanium oxide and gold, polyester fibers were treated as shown below. First, titanium ions were generated in the solution using titanium fluoride in the same manner as above. In addition, chloroauric acid (0.001 by weight relative to the above-mentioned titanium oxide) was added to this solution to simultaneously generate titanium ions and gold ions from this solution. Then, a mixture of boric acid, citric acid, and D,L-malic acid (weight mixing ratio: 0.5:1:1) was added to the above solution in the same manner as in Example 1. As a result, generated titanium oxide ions and gold ions are deposited on the surface of the polyester according to the same principle as electroless plating (electroless plating), and are strongly bonded to the polyester.
[0076] Then, the antibacterial, deodorizing, and antifouling properties of the titanium oxide and gold-treated polyester fibers thus obtained were investigated in the above-mentioned manner. The results are shown in ...
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