Extinction anion electrophoresis film forming method and coating implement
A technology of ion electrophoresis and film coating, which is applied in the direction of electrophoretic coating, electrolytic coating, electrophoretic plating, etc., and can solve problems such as difficulty and changing the degree of extinction
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manufacture example 1
[0098] Add 280 g of isopropanol to the reaction vessel, add dropwise 40 g of styrene, 96 g of methyl methacrylate, 40 g of n-butyl acrylate, 120 g of ethyl acrylate, and 2- A mixture of 48g of hydroxyethyl ester, 28g of propylene ester and 8g of azodimethylvaleronitrile, then add 4g of azodimethylvaleronitrile, and keep it at 80°C for 1 hour for reaction to obtain ethylene copolymer resin No.1 .
[0099] This ethylene-based copolymer resin No. 1 had a weight average molecular weight of about 25,000, an acid value of 55 mgKOH / g, and a hydroxyl value of 58 mgKOH / g.
manufacture example 2
[0100] Production Example 2 Production Example of Emulsion No.1
[0101] After mixing 0.4 equivalent of triethylamine with respect to the carboxyl group of 70 parts (solid content) of ethylene-based copolymer resin No. 1 obtained in Production Example 1, mix and disperse, and then mix and disperse 30 parts of Nikalac MX430 (Note 1), Deionized water was slowly added dropwise while stirring, and triethylamine was added to adjust the pH to 7.5 to obtain emulsion No. 1 with a solid content of 10%.
[0102] The difference in solubility parameters between the ethylene-based copolymer resin No.1 and Nikalac MX430 was 0.7.
manufacture example 3
[0103] Production Example 3 Production Example of Emulsion No. 2
[0104] Add 0.4 equivalent of triethylamine to the carboxyl group of 70 parts (solid content) of ethylene copolymer resin No. 1 obtained in Production Example 1, mix and disperse, and then mix and disperse 20 parts of Nikalac MX430 (Note 1), DURANATE 24A-90CX (Note 2) 12.5 parts (solid content 10 parts), then slowly add deionized water dropwise while stirring, and then add triethylamine to make the pH 7.5 to prepare emulsion No. 2 with a solid content of 10%.
[0105] The difference in solubility parameters between ethylene copolymer resin No.1 and Nikalac MX430 / DURANATE 24A-90 CX is 0.6.
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