Optical recording material and optical recording medium
A technology for optical recording media and optical recording materials, applied in the direction of optical recording media, recording carrier materials, optical recording/reproduction, etc., capable of solving problems such as insufficient solubility
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Embodiment 1
[0126] A polycarbonate resin substrate having a diameter of 120 mm and a thickness of 0.6 mm having pregrooves (180 nm in depth, 0.30 μm in width, and 0.74 μm in pitch) on one side was prepared. Separately, salt-forming dye 1 represented by the following general formula (3) was added to 2,2,3,3-tetrafluoropropanol to prepare a recording layer coating solution having a content of 1.0% by weight.
[0127]
[0128] The obtained coating solution was applied to the surface of the polycarbonate resin substrate on which the pregroove was formed, and dried to form a recording layer (thickness: 100 nm).
[0129] Then, an Ag reflective layer (85 nm thick) was formed by sputtering on the recording layer, and a transparent protective layer (5 μm thick) made of ultraviolet curable acrylic resin was formed on the Ag reflective layer to obtain a laminated structure. Two pieces of this laminated structure are produced, with the protective layer as the inner side, and they are pasted with a...
Embodiment 2
[0131] An optical recording disc was produced in the same manner as in Example 1 except that the salt-forming dye 2 represented by the following general formula (74) was used instead of the salt-forming dye 1 in Example 1.
[0132]
Embodiment 3~13、 comparative example 1~3
[0134] In Examples 3 to 13 and Comparative Examples 1 to 3, optical recording disks were produced in the same manner as in Example 1 except that dye compositions 3 to 13 shown in Table 1 were used instead of salt dye 1, respectively. In Table 1, numbers in parentheses represent symbols of the above-mentioned and following chemical structural formulas.
[0135] Salt
Cyanoin dye
Composition (weight%)
Composition (weight%)
Example 3
(73)
40
(61)
60
Example 4
(73)
50
(61)
50
Example 5
(74)
40
(65)
60
Example 6
(74)
40
(66)
60
Example 7
(74)
40
(67)
60
Example 8
(74)
40
(68)
60
Example 9
(73)
30
(61)
70
Example 10
(73)
60
(61)
40
...
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