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Dielectric ceramic composition, multilayer ceramic capacitor, and method for manufacturing the same
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A technology of ceramic capacitors and dielectric layers, applied in the direction of multilayer capacitors, capacitors, fixed capacitors, etc., can solve problems such as inability to adapt to automotive electronic devices, high dielectric constant materials can not meet the X7R characteristics, etc., and achieve the effect of long failure life
Inactive Publication Date: 2005-09-21
TDK CORPARATION
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However, BaTiO 3 The high dielectric constant material of the series cannot meet the X7R characteristics of the EIA specification (-55~125°C, ΔC / C=±15% or within ±15%), and cannot be adapted to the automotive electronic devices used in the above harsh environments
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[0129] The present invention will be described in detail using the following examples and comparative examples. However, the present invention is not limited to the content described below.
[0130] (manufacturing of sample 1)
[0131] First, prepare the main component raw materials (BaTiO 3 ) and the first to seventh auxiliary component raw materials are used as starting materials for manufacturing dielectric materials. In addition, for the main component BaTiO 3 , and BaCO can also be weighed separately 3 and TiO 2 , use a ball mill to wet mix for about 16 hours, dry the mixture, and then use a ball mill to wet pulverize the fired product fired in the air at a temperature of 1100°C for about 16 hours, and the same result can be obtained by using the material obtained in this way . In addition, the main component BaTiO 3 It can be obtained by hydrothermal synthetic powder and oxalate method, and the same result can be obtained by using the substance obtained in this wa...
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Abstract
Provided are a dielectric porcelain composition, a laminated ceramic capacitor and the manafacturing method thereof. The dielectric porcelain composition comprises barium titanate as the principal component, a first subcomponent (at least one member of the oxides of Mg, Ca, Ba, and Sr), a second subcomponent (an oxide containing 1 mol of Si atoms in 1 mol), a third subcomponent (at least one member of the oxides of V, Mo, and W), a fourth subcomponent containing at least one kind of R1oxide (wherein R1is at least one member selected from among Sc, Er, Tm, Yb, and Lu), a fifth subcomponent containing at least one kind of R2oxide (wherein R2is at least one member selected from among Y, Dy, Ho, Tb, Gd, and Eu), a sixth subcomponent (at least one member selected from the oxides of Mn and Cr), and a seventh subcomponent (at least one member selected from calcium zirconate and a mixture of a Ca oxide and a Zr oxide). The ratio of the number of moles A of the second subcomponent of the composition 1, and the total number of moles B of the fourth subcomponent and the fifth subcomponent is no less than 0.7; the ratio of the number of moles C of the Si atoms in the second subcomponent of the composition 2, and the total number of moles D of the atoms except Si and oxygen in all the subcomponents.
Description
technical field [0001] The present invention relates to a dielectric ceramic composition, a multilayer ceramic capacitor and a manufacturing method thereof, and more specifically, to a dielectric ceramic composition and a multilayer ceramic having a long mean time to failure (MTTF: Mean Time To Failure) and satisfying X8R characteristics capacitors etc. technical background [0002] Electronic Components Multilayer ceramic capacitors are widely used as small, large-capacity, and highly reliable electronic components. In recent years, along with the miniaturization and high performance of equipment, the situation that multilayer ceramic capacitors are required to be further miniaturized, larger in capacity, lower in price, and higher in reliability has become increasingly severe. [0003] In multilayer ceramic capacitors, the paste for the internal electrode layer and the paste for the dielectric layer are usually laminated by the sheet method (シャト method) or the printing me...
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