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Cold briquetting and pelletisation

A pelletizing and pelletizing technology, applied in the direction of process efficiency improvement, sustainable waste treatment, solid waste management, etc., can solve the problems of increasing harmful impurities, polluting air, unsatisfactory performance of briquettes and pellets, etc.

Inactive Publication Date: 2006-01-11
COUNCIL OF SCI & IND RES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0019] Disadvantages of previous methods are that in the production of briquettes and pellets, the use of various binding materials, water vapor curing, heat hardening, sintering and thermal compaction under pressure are energy-intensive
Most organic and inorganic binders decompose at low temperatures (less than 600°C) and are easily soluble in water, so in terms of durability, water resistance, volume stability and thermal stability, these binders bleed After the briquettes and pellets have unsatisfactory properties
In addition, the application of binder materials containing sulfates, alkalis, chlorides, phosphates deteriorates the sinterability and reducibility of briquettes and pellets
These types of binders also add harmful impurities to the metallurgical process, producing hazardous and corrosive gas emissions, shortening furnace life and polluting the air

Method used

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  • Cold briquetting and pelletisation
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  • Cold briquetting and pelletisation

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0073] 3.600 kg of iron ore (grain size up to 6.3 mm), 0.4 kg of iron-rich mineral binder (10% by mineral basis) and 0.130 liters of water [water / binder ratio (W / B) 0.32] in a drum Mix in mixer for 5 minutes. Then 2 kg of the green mixture each time were used to produce cylindrical compacts with a diameter of 30 mm under a pressing load of 0.5 and 5 tons. To maintain the same briquette weight, 55 grams of green mix was used per briquette. Thus, 30 briquettes were produced under a load of 0.5 ton (compression ratio 0.70) and a load of 5 ton (compression ratio 0.60). The two briquette samples were water-cured in atmospheric air after 12 hours for up to 20 days for binder hydration and cold strength improvement. The cold bond strength of the briquette increases with time and binder hydration rate. Within 20 days, the adhesive reached almost 90% hydration strength, and reached equilibrium strength within 90 days. Briquettes made under 0.5 ton and 5.0 ton compressive loads achi...

Embodiment 2

[0075] Mix 1.680 kg iron ore (grain size up to 4 mm), 0.160 kg coke powder (grain size up to 0.5 mm), 0.160 kg iron-rich mineral binder (8% by weight), 70 ml water and 2 ml surfactant The agent was mixed in the pan for 5 minutes. The green mixture was briquetted under a compression load of 3 tons to produce cylindrical briquettes with a diameter of 30 mm at a compression ratio of 0.62. Use 50 grams of the mixture per briquette. Twenty briquettes were prepared from the above mixture and then cured in water for 28 days. After 1, 3, 7, 14, 21, and 28 days of water curing, the coke-containing composite iron ore briquettes reached an average cold crushing strength of 6.4, 13.0, 18.6, 23.5, 25.8, and 27.0 MPa, respectively.

Embodiment 3

[0077] 2.000 kg of BOF powder (particle size up to 1 mm), 0.800 kg of scale (particle size up to 3.0 mm), 0.800 kg of iron ore (particle size up to 2 mm), 0.400 kg of iron-rich mineral binder (by weight, 10%), 120 ml of water and 5 ml of surfactant were mixed in a drum mixer for 5 minutes. 2 kg of green mix was used at a time to produce cylindrical briquettes with a diameter of 30 mm under a compression load of 4 and 5 tons. The weight of green mix used per briquette was 45 grams. Therefore, 40 briquettes of each were prepared under 4 ton and 5 ton loads and then cured in water for 28 days. The briquettes made under the compression load of 4 tons and 5 tons were cured in water for 1, 3, 7, 14, 21 and 28 days to reach 5.5, 13.5, 18.5, 22.0, 24.4 and 26.2 MPa and 8.0, 16.3, Average cold crush strengths of 21.5, 25.0, 26.8 and 28.5 MPa.

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Abstract

The present invention provides a process for cold briquetting and pelletization of ferrous or non-ferrous or mineral fines using iron bearing hydraulic mineral binders for metallurgical applications, said process consisting the steps of: mixing 84-95% by Wt. of a metallurgical / mineral / carbonaceous / oil contaminated materials in the form of dust / fines / sludge with 4-10 % by Wt. of an iron bearing hydraulic mineral binder and optionally with 2-6 % by Wt. water and 0.05 to 0.20% by Wt. of a surface active agent to form a homogenized dry mix / slurry, pelletizing / compacting the dry mix / slurry to form an agglomerated mass, and curing the agglomerated mass for 3-20 days by exposing the agglomerated mass to atmospheric air for 10-14 hours followed by moisture treatment. The iron bearing binder is an ultrafine powdery material (like cement) having as chemical constituents 25 to 45% of Fe203, 40 to 60% of Ca0+Mg0 and 12 to 18% of Si02+A1203.

Description

technical field [0001] The present invention relates to a method for cold compacting and pelletizing iron-containing ore or non-iron-containing ore or mineral fines with iron-containing hydraulic mineral binder for metallurgical applications. Background technique [0002] Agglomeration products such as briquettes, pellets and blocks prepared from iron oxides and metallic iron fines derivatives, limestone, dolomite, peridotite, solid charcoal etc. with iron-containing hydraulic mineral binders are suitable as raw materials in blast furnaces It is used for extracting iron in rotary kilns and shaft kilns for reduction and oxidation roasting and sintering, and for roasting, roasting and sintering in air ducts, furnace chambers and movable grate type furnaces. [0003] Agglomeration methods of briquetting and pelletizing are well known for converting fine and powdered derivatives of ores, minerals, residues and solid waste into bulk sizes for various industrial applications. In ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B1/24C22B1/243C22B7/02C04B7/147C04B7/22C04B7/52C04B18/02C04B28/02
CPCC04B28/02C04B7/525C04B18/021C22B7/02C22B1/24C22B1/243C04B2111/0087C04B2111/00215Y02P10/20Y02P40/10Y02W30/91C04B18/141C04B24/122C04B40/0028C04B40/0071C04B40/02C04B18/14C04B18/12C04B14/28C04B2103/40C04B7/14C04B7/22
Inventor B·纳亚克V·K·米什拉
Owner COUNCIL OF SCI & IND RES