Fuel cell separator
A technology for fuel cells and separators, which is used in fuel cells, fuel cell parts, solid electrolyte fuel cells, etc., and can solve the problems of high cost and materials that cannot be widely used.
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Embodiment 1
[0128] First, 88% by volume of a fluororesin (Sumitomo 3M Ltd., THV415G, specific gravity: 2) and 12% by volume of carbon black (Lion Corporation, Ketjen Black EC600JD, specific gravity: 1.5) as a conductive agent were mixed by a twin-screw extruder Mix together.
[0129]The mixture was extruded (at an extrusion temperature of 240° C.) into a conductive fluororesin sheet having a thickness of 50 μm. The volume resistance of the conductive fluororesin was 0.8 Ω·cm.
[0130] The metal substrate is a metal plate prepared by forming a nickel plating layer to 0.8 μm on a SUS304 plate (thickness: 0.3 mm). On both sides of the SUS 304 plate with the electroplated layer, a 0.3% solution of a silane coupling agent (GE Toshiba Silicones, TSL8331) in ethanol as a primer is coated by a #10 wire-wound bar coater, and then the substrate Dry at 100°C for 10 minutes. The conductive fluororesin sheet, the SUS304, and the conductive fluororesin sheet were placed in this order, and they were ...
Embodiment 2
[0136] Using the fluororesin sheet (first resin layer, thickness: 50 μm) prepared as described in Example 1 and two transfer sheets (transfer layer thickness of 10 μm), place the transfer sheet, fluororesin sheet, and transfer sheet in this order , so that the outermost layer is the transfer substrate (PET flake). at a temperature of 200°C and 3.5 x 10 6 Pa(36kgf / cm 2 ) under pressure conditions for 10 minutes, remove the two transfer substrates, thereby forming the second and third resin layers on both sides of the first resin layer. The flakes thus prepared had a total thickness of 170 μm.
[0137] Using the two conductive sheets prepared as described above, and the SUS304 plate (thickness: 0.3mm) having a surface nickel plating layer with a thickness of 0.8 μm as described in Example 1 as a metal plate, the conductive sheet, SUS304 plate and conductive sheets are placed in this order, at a temperature of 200°C and 3.5×10 6 Pa(36kgf / cm 2 ) under pressure conditions, the...
Embodiment 3
[0140] First, 85% by volume of polyolefin elastomer (Idemitsu Kosan Co., Ltd., T310E, specific gravity: 0.88) and 152% by volume of carbon black (Lion Corporation, Ketjen Black EC600JD, specific gravity : 1.5) mixed together.
[0141] The mixture was extruded (at an extrusion temperature of 260° C.) into a conductive polyolefin resin sheet having a thickness of 50 μm. The volume resistance of the conductive polyolefin resin was 0.5 Ω·cm.
[0142] Separately, as a preparation method for forming the second resin layer, to cyclohexane, styrene elastomer (Asahi Kasei Corporation, Tuftec H1041, specific gravity: 0.91) and fine carbon fiber (Showa Denko K.K. , Vapor-grown carbon fiber (VGCF), specific gravity: 2), to 10% by weight on a solid basis, to prepare a coating material.
[0143] The coating material was coated on a substrate film (polyethylene terephthalate, Mitsubishi Polyester Film Corporation, thickness: 25 μm) by a wire bar coater (Matsuo Sangyo Co. Ltd., #24) . The...
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