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Process for making highly dispersible polymeric reinforcing fibers

a polymer and fiber technology, applied in the field of making highly dispersible polymeric reinforcing fibers, can solve the problems of unsatisfactory fiber "balling, unsatisfactory fiber dosage, and high flexibility (such as in wet human hair)

Inactive Publication Date: 2003-05-01
WR GRACE & CO CONN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0020] Exemplary individual fiber bodies of the invention are also substantially free of internal and external stress fractures, such as might be created by clinker grinding or mechanical flattening. The general intent of the present inventors is to maintain integrity of the individual fiber bodies, not only in terms of structural fiber integrity, but also integrity and uniformity of total surface area and bendability characteristic from one batch to the next.
[0021] A generally quadrilateral cross-sectional profile provides a higher surface area to volume ratio (S.sub.a / V) compared to round or oval monofilaments comprising similar material and having a diameter of comparable dimension. The present inventors believe that a quadrilateral cross-sectional shape provides a better flexibility-to-volume ratio in comparison with round or elliptical cross-sectional shapes, and, more significantly, this improved flexibility characteristic translates into better "bendability" control. The individual fiber bodies of the invention will tend to bend predominantly in a bow shape with comparatively less minimal twisting and fiber-to-fiber entanglement, thereby facilitating dispersal. In contrast, for a given material modulus and cross-sectional area, the prior art fibers having circular or elliptical cross section with major axis / minor axis ratios of less than 3 will have greater resistance to bending, thereby having a greater tendency for fiber balling when compared to fibers of generally quadrilateral (e.g., rectangular) cross-section.

Problems solved by technology

They also sought to avoid extreme rigidity, which is often associated with strength, because this too can lead to undesirable fiber "balling."
Flexibility that is too high (such as in wet human hair) can be just as troublesome as stiffness (such as in the "pick-up-sticks" game played by children) because self-entanglement can arise in either case.
A high degree of fiber balling or entanglement means that substantially uniform dispersion has not been attained in the matrix material; and this, in turn, means that the fiber dosage will be inadequate and the material properties of the fiber reinforced material will be subject to significant variation.
As mentioned above, an increase in elastic modulus usually means a decrease in bendability, which has a negative impact on dispersion properties of the plurality of fibers.
Fibers added at these low dosage rates do not have a significant effect on the hardened properties of concrete.

Method used

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  • Process for making highly dispersible polymeric reinforcing fibers
  • Process for making highly dispersible polymeric reinforcing fibers
  • Process for making highly dispersible polymeric reinforcing fibers

Examples

Experimental program
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Effect test

example 1

Prior Art

[0070] Prior art fibers having an elliptical shaped cross section were tested in terms of bendability and dispersibility in a concrete mix. These elliptical fibers were 50 mm long, 1.14 mm wide, 0.44 mm. thick, and had a Young's modulus of elasticity of 4 Giga Pascal. The "bendability" formula discussed above may be employed, wherein bendability "B" was computed as B=1 / (3.multidot.E.multidot.I), and the moment of inertia (I) for ellipses is calculated by the formula, I.sub.elipse=Pi / 64.multidot.a.multidot.b.sup.3, where "a" is half the width of the elliptical fiber (major axis of the ellipse, i.e., widest dimension through the center) and "b" is half the thickness of the elliptical fiber (minor axis of the ellipse, i.e. thinnest dimension through the center point of the ellipse). The bending deflection "B" was computed to be 17.5 mN.sup.-1*m.sup.-2. This fiber is considered a "stiff" fiber. 30 minutes were required for introducing 100 pounds of these elliptical fibers into ...

example 2

[0071] In contrast to the prior art elliptical fibers of Example 1, fibers having a generally quadrilateral cross-section were used. These quadrilateral fibers had the following average dimensions: 50 mm long, 1.35 mm wide, and 0.2 mm thickness, with a Young's modulus of elasticity of 9 Giga Pascal. The bendability "B" of these fibers was computed in accordance with the formula, B=1 / (3.multidot.E.multidot.I), wherein the moment of inertia "I" for rectangular cross-section was computed in accordance with the formula, I.sub.rectangle=1 / 12.multidot.w.multidot.t.s-up.3, wherein "w" is the average width and "t" is the average thickness of the rectangle. Using the equation, the bendability "B" was computed as 41.2 mN.sup.-1*m.sup.-2. This fiber is considered flexible. When 100 pounds of these fibers were introduced into 8 cubic yards of concrete, located in a ready-mix truck drum and rotated at the same rate as in Example 1, a homogeneous fiber distribution was achieved in just 5 minutes....

example 3

[0072] The mechanical properties of the fibers themselves have a huge impact on the behavior of the fibers in concrete, if there is sufficient bond between the fiber and the brittle concrete matrix. If the fibers have not bonded well to the matrix (e.g. fiber pull-out is the major fiber failure mechanism observed when the fiber reinforced concrete is broken apart), then the fiber properties will have minimal impact on the behavior of the composite material. As mentioned earlier, due to the fiber geometry and dimensional ranges inventively selected by the present inventors, sufficient bond adhesion between the matrix material (when hardened) and the fibers can be achieved to obtain, ideally, half fiber failure (breakage) and half fiber pull-out. Therefore, fiber properties such as elastic modulus of elasticity, tensile strength, and minimum load carrying capacity were selected so as to maintain as closely as possible the ideal 50:50 balance between fiber pull-out failure and fiber fa...

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Abstract

Synthetic polymer reinforcing fibers provide dispersability and strength in matrix materials such as concrete, masonry, shotcrete, and asphalt. The individual fiber bodies, substantially free of stress fractures and substantially non-fibrillatable, have generally quadrilateral cross-sectional profiles along their elongated lengths.

Description

[0001] The invention relates to fibers for reinforcing matrix materials, and more particularly to a plurality of synthetic polymer fibers having excellent dispersibility and reinforcibility properties in hydratable cementitious compositions. Individual fiber bodies are elongated and highly bendable, with generally quadrilateral cross-sectional profiles, thereby minimizing fiber balling and maximizing fiber bond.[0002] Although fibers of the present invention are suitable for reinforcing various matrix materials, such as adhesives, asphalts, composites, plastics, rubbers, etc., and structures made from these, the fibers that will be described herein are especially suited for reinforcing hydratable cementitious compositions, such as ready-mix concrete, precast concrete, masonry concrete (mortar), shotcrete, bituminous concrete, gypsum compositions, gypsum- and / or Portland cement-based fireproofing compositions, and others.[0003] A major purpose of the fibers of the present invention i...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C04B16/06C08J5/04D01D5/253E04C5/07
CPCC04B16/06C08J5/04D01D5/253E04C5/073Y10T428/2922Y10T428/2978Y10T428/2913Y10T428/2967Y10T428/2973Y10T428/2929Y10T428/2904Y10T428/2964Y10T428/24994Y10T428/249932D01F6/00
Inventor RIEDER, KLAUS ALEXANDERBERKE, NEAL S.MACKLIN, MICHAEL B.RANGANATHAN, ANANDAKUMAR
Owner WR GRACE & CO CONN
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