Templated catalyst composition and associated method
a catalyst and composition technology, applied in the field of catalyst composition, can solve the problems of poor nox reduction with concomitant carbon deposition, unsatisfactory reaction kinetics,
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[0043]Templated alumina is produced as follows, for example. Solution 1 is formed by combining ethylaetoacetate (26.5 g, 0.2 mol), TRITON X-114 (85g, ca. 0.15 mol) and 2-butanol (500 mL) in a 5-L, 3-neck flask equipped with an addition funnel, a condenser, and a mechanical stirrer. Solution 2 is composed of Al(O-secBu)3 (500 g, 2 mol) and 2-BuOH (2 L). Solution 3 is composed of water (75 mL, 4 mol) and 2-BuOH (850 mL).
[0044]Solution 2 is added to Solution 1 while stirring, and is held at ambient temperature for 30 min. Solution 3 is added to solutions 1 and 2 via an addition funnel over about 90 minutes. Mechanical stirring is continued at ambient temperature for 3 hours and then the contents are heated to about reflux for about 20 to about 24 hours.
[0045]The contents are cooled and filtered on a #50 paper filter and washed with ethanol. The obtained white solid is dried in vacuo, in a vacuum oven at 80 degrees Celsius. The solid is subjected to Soxhlet extrac...
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