Light degradation antibiotic polylactic acid material and preparation method thereof
A polylactic acid and photodegradation technology, which is applied in the field of composite materials to achieve the effects of enhancing interaction, achieving uniform and stable dispersion, and improving glass transition temperature and mechanical properties
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[0031] 2. Preparation of photodegradable antibacterial polylactic acid composite material
[0032] Organically treated lactide and TiO with different contents 2 (Organized TiO 2 The mass fractions of 1.0wt%, 3.0wt%, 5.0wt%, 10wt%) were put into 5 straight sealed tubes respectively, added with the tetrahydrofuran solution of stannous octoate and the magnets, stirred, and evacuated under the protection of nitrogen atmosphere. Seal the tube, place the sealed tube in an oil bath at 150°C for pre-polymerization for 2 hours, and then polymerize at 150°C for 24 hours to prepare PLA substrate and nano-TiO 2 / PLA composite material, marked as TiO 2 -x / PLA(x is TiO 2 Quality score). After the prepared sample is formed into a film by hot pressing or a solution, it is stored in a desiccator for later use.
Example Embodiment
[0033] Example 1:
[0034] 1.TiO 2 Organic treatment
[0035] Add 6g anatase nano TiO 2 Mix with 300 mL methyl ethyl ketone, ultrasonically disperse for 10 min, mix with 300 mL methyl ethyl ketone solution containing 2.4 g KH570 silane coupling agent (γ-methylacetoxypropyltrimethoxysilane), and reflux at 80° C. for 3 hours. Cooled to room temperature, centrifuged, and dried at 100°C to obtain organically treated TiO 2, Keep it in a desiccator for later use. The result of acetone treatment is similar to the material performance obtained by methyl ethyl ketone.
[0036] 2. Preparation of photodegradable antibacterial polylactic acid composite material
[0037] The purified lactide and the organically treated TiO with a mass fraction of 1.0wt% 2 Put it into a straight sealed tube, add the tetrahydrofuran solution of stannous octoate and stir with a magnet, vacuum seal the tube under the protection of nitrogen atmosphere, place the sealed tube in a 150℃ oil bath for pre-polymerization...
Example Embodiment
[0038] Example 2: Perform nano-TiO according to the method described in Example 1 2 The difference is that the dispersant is triethylamine, and the reagent used for the organic modification is titanate coupling agent (NDZ105, isopropyl trioleic acid acyloxy titanate). Other treatment methods And the reaction conditions are the same.
[0039] Purification of lactide and preparation of photodegradable antibacterial polylactic acid composite material were carried out according to the method described in Example 1. The difference is that the catalyst is stannous chloride and the nano TiO is used. 2 The mass fraction of L-lactide is 3.0wt%, and other treatment methods and reaction conditions are the same. The resulting composite material is labeled TiO 2 -3 / PLA.
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