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Process for co-producing jet fuel and LPG from renewable sources

a technology of jet fuel and renewable sources, which is applied in the direction of fuels, gaseous fuels, hydrocarbon oil treatment products, etc., can solve the problems of additive products that are characterized as not always acceptable for commercial use, methods that are limited, and additive products that are characterized as poor at low temperatures, so as to improve cold flow properties

Inactive Publication Date: 2011-03-24
REG SYNTHETIC FUELS LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0012]The resultant jet fuel product has improved cold flow properties. In particular, the jet fuel product has a viscosity of less than 5 centistokes at about −20° C., a boiling range of about 150° C. to about 300° C. and a freezing point of less than about −47° C.

Problems solved by technology

Such methods, however, have limitations, including producing fuels that are not always acceptable for commercial use.
This method results in an additive product that is characterized as performing poorly at low temperatures.
This process also produces a product having a high cetane value but poor low temperature properties, such as a high cloud point at around 25° C. As such, both mentioned resultant products are useful as diesel fuel additives but not usable as diesel or jet fuel replacements.
This process still suffers from a cloud point at a temperature that is comparatively too high.

Method used

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  • Process for co-producing jet fuel and LPG from renewable sources
  • Process for co-producing jet fuel and LPG from renewable sources
  • Process for co-producing jet fuel and LPG from renewable sources

Examples

Experimental program
Comparison scheme
Effect test

example 1

Process of Making a Jet Fuel from Renewable Sources

[0031]The present example demonstrates how a jet fuel was made from a renewable feedstock. A 100 cc isothermal tubular reactor was filled with 80 cc of Criterion 424 Ni—Mo catalyst and +70-100 mesh glass beads. The catalyst was sulfided with dimethyl disulfide at two hold temperatures: 6 hours at 400° F. and 12 hrs at 650° F. Hydrogen sulfide break-through was confirmed before the temperature was raised from 400° F. to 650° F. at 50° F. / hr. After sulfiding, the reactor was cooled to 400° F.

[0032]Next a triglyceride / fatty acid feed was introduced to the isothermal reactor. The reactor was slowly heated to 650° F. to achieve full conversion of the triglyceride / fatty acid feed to n-paraffins. The reactor temperature was further increased to 700° F. to maintain good catalyst activity at 80 cc / hr feed rate (1 LHSV).

[0033]The total liquid hydrocarbon (TLH) from the hydrotreater was then hydroisomerized to jet fuel using the conditions sum...

example 2

[0034]The hydrotreated effluent was analyzed using a gas chromatogram. In particular, the total liquid hydrocarbon (TLH) from the hydrotreater reaction of Example 1 was analyzed to confirm triglyceride conversion, and quantify cracking to light ends.

[0035]The gas chromatogram utilized the following materials:

[0036]Materials:

[0037]Analytical Balance, capability to 0.1 mg

[0038]Carbon Disulfide, High Purity

[0039]Custom Alkane Standard—Restek Cat #54521

[0040]Pasteur Pipette with bulb

[0041]HP 5860 Gas Chromatograph—FID

[0042]GC Column, Restek—Rtx—1 MS, Cat #11624

[0043]Helium Gas—Alpha Gas

[0044]Hydrogen Gas—Alpha Gas

[0045]Zero Air Gas—Alpha Gas

[0046]Sharpie

[0047]GC Vials and Caps

[0048]The gas chromatogram was operated under the following conditions:

[0049]Runtime 82 minutes

[0050]Injection Volume 1-pL

[0051]Inlet Temperature 320° C.

[0052]Detector Temperature 350°

[0053]Oven:[0054]Initial Temperature 35° C.[0055]Rate (° C. / min) 5.00[0056]Equilibrate Time 0.20 min[0057]Final Temperature 320° C.[...

example 3

Jet Fuel from Renewable Sources

[0059]The resultant jet fuel and the isoparaffinic product from Example 1 was analyzed and compared to similar products. The feedstock jet fuel was found to have a cloud point of −53° C.

[0060]The composition of the isoparaffinic product was analyzed via Gas Chromatograph and is summarized in Table 3. A key property to observe is iso / normal ratio. The procedure employed to determine iso / normal ratio is shown below. As indicated by Table 3 data, the hydroisomerizer product may be fractionated to the desired jet fuel boiling range. Such separation was performed using standard lab distillation apparatus. The comparable properties of Fischer-Tropsch IPK jet fuel distillate are summarized in Table 5. As observed from Table 4, the renewable jet fuel of this invention met or exceeded all key specifications of commercial jet fuel.

TABLE 3Carbon Number Distribution and Iso / NormalRatio of Hydroisomerizer ProductIso / NormalNormalIsomerNormalRatio byMass %GroupMWMass...

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Abstract

The present invention generally relates to a method for producing an isoparaffinic product useful as jet fuel from a renewable feedstock. The method may also include co-producing a jet fuel and a liquefied petroleum gas (LPG) fraction from a renewable feedstock. The method includes hydrotreating the renewable feedstock to produce a hydrotreating unit heavy fraction that includes n-paraffins and hydroisomerizing the hydrotreating unit heavy fraction to produce a hydroizomerizing unit heavy fraction that includes isoparaffins. The method also includes recycling the hydroisomerizing unit heavy fraction through the hydroisomerization unit to produce an isoparaffinic product that may be fractionated into a jet fuel and an LPG fraction. The present invention also relates to a jet fuel produced from a renewable feedstock having improved cold flow properties.

Description

STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT[0001]Not applicable.CROSS-REFERENCE TO RELATED APPLICATIONS[0002]The present application is a continuation of U.S. application Ser. No. 12 / 062,970, filed Apr. 4, 2008, which claims benefit under 35 U.S.C. 119(e) of U.S. Provisional Application Ser. No. 60 / 910,573, filed Apr. 6, 2007, both of which are hereby expressly incorporated herein by reference in their entirety.FIELD OF THE INVENTION[0003]The present invention generally relates to a method for producing from a renewable feedstock an isoparaffinic product useful in producing jet fuel and / or jet fuel blendstock (hereinafter referred to as “jet fuel”) or an LPG product. The present invention also relates to the resultant jet fuel, whereby the jet fuel has improved cold flow properties.BACKGROUND OF THE INVENTION[0004]Due to concerns with limited resources of petroleum-based fuels, the demand for using renewable feedstock, such as vegetable oils and animal fats, to p...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C07C1/00C10L1/16
CPCC10G2400/08C10G2400/28C10L1/04C10L3/12C10G3/46C10G2400/02C10G2300/1014C10G2300/1018C10G2300/301C10G2300/302C10G3/50Y02P30/20
Inventor ABHARI, RAMINTOMLINSON, LYNNHAVLIK, PETERJANNASCH, NATHAN
Owner REG SYNTHETIC FUELS LLC
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