High internal phase emulsion comprising photoinitiator

Abstract

The present invention relates to a High Internal Phase Emulsion (HIPE) and HIPE foams produced therefrom comprising two or more layers and having a photoinitiator.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application claims the benefit of U.S. Provisional Application No. 61 / 290,947 filed on 30 Dec. 2009, the substance of which is incorporated herein by reference.FIELD OF THE INVENTION[0002]This application relates to a High Internal Phase Emulsion (HIPE) comprising photoinitiator.BACKGROUND OF THE INVENTION[0003]An emulsion is a dispersion of one liquid in another liquid and generally is in the form of a water-in-oil mixture having an aqueous or water phase dispersed within a substantially immiscible continuous oil phase. Water-in-oil (or oil in water) emulsions having a high ratio of dispersed aqueous phase to continuous oil phase are known in the art as High Internal Phase Emulsions, also referred to as “HIPE” or HIPEs. At relatively high dispersed aqueous phase to continuous oil phase ratios the continuous oil phase becomes essentially a thin film separating and coating the droplet-like structures of the internal, dispersed aqueous...

AI Technical Summary

Benefits of technology

[0003]An emulsion is a dispersion of one liquid in another liquid and generally is in the form of a water-in-oil mixture having an aqueous or water phase dispersed within a substantially immiscible continuous oil phase. Water-in-oil (or oil in water) emulsions having a high ratio of dispersed aqueous phase to continuous oil phase are known in the art as High Internal Phase Emulsions, also referred to as “HIPE” or HIPEs. At relatively high dispersed aqueous phase to continuous oil phase ratios the continuous oil phase becomes essentially a thin film separating and coating the droplet-like structures of the internal, dispersed aqueous phase. The continuous oil phase of a water-in-oil HIPE generally comprises one or more polymerizable monomers. These monomers can be polymerized, forming a cellular structure, for example a foam, having a cell size distribution defined by the size distribution of the dispersed, aqueous phase droplets.

Problems solved by technology

However there are several significant drawbacks to using heat alone for curing HIPEs.

A HIPE usually has a large surface area and the unequal application of heat to such a large surface can cause defects in the resulting HIPE foam, such as dimpling, shrinkage, and edge curls.

Further, whatever form the heat application takes such application is usually quite expensive in energy and monetary costs, as the heat being applied to a HIPE usually has a temperature ranging from around 50° C. to 150° C. An additional drawback to the use of heat alone to polymerize HIPEs is that an enclosed area, such as an oven, is required to keep the heat from escaping into the environment and reducing the amount of heat applied to the HIPE.

This need for an oven further increases the cost of producing HIPE foams and takes up a large amount of physical space on the HIPE foam production line.

However, these methods have had problems, such as a reliance on the use of polyelectrolytes in the HIPE which can lead to undesirable properties in the resulting HIPE foam, as polyectrolytes are trapped in the polymer backbone, whether through entanglements; polymerized in, via chain transfer reactions; or simply absorbed onto the surface of the HIPE foam struts.

The polyelectrolytes thus incorporated into the HIPE foam change the physical properties of the foam, typically decreasing the strength and increasing friability of the resulting HIPE foam.

Further, these methods have not been usable on thicker HIPEs and preferentially polymerize the monomers on the surface of the HIPE exposed to the source of the UV light, leaving the bulk of the HIPE unpolymerized.

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