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Gasoline engine with an exhaust system for combusting particulate matter

a technology of exhaust system and gasoline engine, which is applied in the direction of electric supply techniques, physical/chemical process catalysts, separation processes, etc., can solve the problems of pm, health problems, and more hazardous, and achieve the effect of minimal impact on the overall efficiency of the vehicle and low power consumption

Inactive Publication Date: 2011-09-29
JOHNSON MATTHEY PLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0039]An advantage of the present invention incorporating an electrostatic trap, such as the cylinder-wire embodiments, is that they have a relatively low power consumption e.g. about 10 W, therefore there is minimal impact on the overall efficiency of the vehicle.
[0040]According to a further aspect, the invention provides a method of combusting PM from a gasoline engine in CO2 and / or H2O from the exhaust gas at temperatures in excess of 500° C., which method comprising trapping the PM and contacting the trapped PM with a catalyst comprising a supported alkali metal. The temperatures in excess of 500° C. can be e.g. 550° C., 600° C., 650° C. or 700° C.EXAMPLES
[0041]In order that the invention may be more fully understood, the following Examples are provided by way of illustration only:

Problems solved by technology

It is very well known that gas-borne particulates can cause health problems if inhaled.
However, it is not generally appreciated that many modern gasoline engines emit large numbers of very small (<0.1 μm generally 10-100 nm) particulate matter (PM), which because of its small size is not observed by the naked eye.
Nonetheless, the size of this PM is such that it can be inhaled into the deepest recesses of the lungs and may even be more hazardous than the PM from diesel engines.
Indeed, as reported in the Proceedings from the 2″ International Conference on Health Effects of Vehicle Emissions, Ed. K. Donaldson, (2000), PM poses a significant threat to health in the UK.
In seeking to combust gasoline PM, one problem is that the amount of oxidant available in the exhaust gas for combusting the PM downstream of a three-way catalyst (TWC) is generally very low at approximately 0.03% v / v (300 ppm).

Method used

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  • Gasoline engine with an exhaust system for combusting particulate matter
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Examples

Experimental program
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Effect test

example 1

Catalyst Preparation

[0042]A 10 wt % K / Al2O3, 10 wt % K / CeO2 and 10 wt % K / ZrO2 (as the elemental alkali metal based on the total weight of the catalyst) was prepared by wet impregnation. In each case the impregnation medium was an aqueous solution of KNO3. A mixture of the correct amounts of the support and impregnation solution was heated to evaporate the water and the material was calcined at 500° C. for 2 hours. Three alumina supports were used: alpha-, theta- and gamma-. We understand that the alkali metal is present as K2O in each catalyst, although some residual KNO3 may be present post-calcination.

example 2

Catalyst Ageing

[0043]Pelletised catalysts of Example 1 were aged in a simulated stoichiometric gasoline exhaust gas mixture of nitrogen, water, carbon monoxide, hydrogen, oxygen, sulphur dioxide at 850° C. for 2 hours and 16 hours.

example 3

Preparation of Catalyst / Particulate Matter Samples

[0044]Fresh catalyst of Example 1 and aged catalyst from Example 2 were each mixed with about 30-40% w / w carbonaceous PM (BP2000—high surface area graphite, a simulant for gasoline exhaust PM) lightly in a mortar and pestle to ensure thorough mixing. Light mixing was employed in order to simulate real conditions in an exhaust system in which the gasoline PM would loosely contact a trap device including a catalyst. Thus heavy grinding, which would promote too tight a contact between the PM and the trap, was avoided.

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Abstract

A gasoline engine having an exhaust system comprises means for trapping particulate matter (PM) from the exhaust gas and a catalyst for catalysing the oxidation of the PM by carbon dioxide and / or water in the exhaust gas, which catalyst comprising a supported alkali metal. The invention further includes a method of combusting PM from a gasoline engine in CO2 and / or H2O from the exhaust gas at temperatures in excess of 500° C., which method comprising trapping the PM and contacting it with a catalyst comprising a supported alkali metal.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application is a continuation of U.S. patent application Ser. No. 10 / 485,592, filed Sep. 7, 2004, which is the U.S. National Phase of PCT International Application No. PCT / GB02 / 03500, filed Jul. 30, 2002, and claims priority of British Patent Application No. 0118748.3, filed Aug. 1, 2001, and British Patent Application No. 0119107.1, filed Aug. 6, 2001, the disclosures of all of which are incorporated herein by reference in their entirety for all purposes.FIELD OF THE INVENTION[0002]The present invention relates to an exhaust system for treating exhaust gases from a gasoline engine, and in particular it relates to an exhaust system for trapping and combusting fine particulate matter in the exhaust gas.BACKGROUND OF THE INVENTION[0003]It is very well known that gas-borne particulates can cause health problems if inhaled. It is also well known that diesel engines emit particulates, especially upon start-up and under heavy load, and thi...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): F01N3/035F01N13/16F01N3/02B01D39/12B01D39/14B01D39/20B01D46/42B01D53/94B01J21/04B01J21/06B01J23/04B01J23/10B01J37/02B03C3/40B03C3/41B03C3/49B03C3/66B03C3/74F01N3/10F01N3/24
CPCB01D53/944B01J21/04B01J21/06B01J21/066Y02T10/22B01J23/10B01J37/0201F01N3/035F01N2560/028B01J23/04B01D53/323B01D53/864B01D2255/202B01D2255/2025B01D2255/2027B01D2255/50B01D2255/9155B01D2258/014B01D2255/2022Y02T10/12B01D2255/2065B01D2255/20715B01D2255/2092B01D2255/40B01D2255/915F01N3/101
Inventor MCNAMARA, JOHN MARTINROWE, JULIA MARGARETPOULSTON, STEPHENRAJARAM, RAJ RAOCRANE, ROBERT IANARCOUMANIS, CONSTANTINERUBINO, LAURETTA
Owner JOHNSON MATTHEY PLC
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