Sulfopolyester binders

a technology of sulfopolyester and binders, which is applied in the field of sulfopolyester binders, can solve the problems of limiting the application of specific end uses, many of the binder compositions utilized above lack the ability to be modified in order to fit a wide array of end use products, and the fixed water permeability cannot be significantly modified

Inactive Publication Date: 2012-07-19
EASTMAN CHEM CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0008]In one embodiment of the present invention, there is provided a nonwoven article comprising a plurality of thermoplastic polycondensate fibers and a sulfopolyester binder. The thermoplastic polycondensate fibers make up at least 10 weight percent of the total fiber content of the nonwoven article, whereas the sulfopolyester binder makes up at least 1 weight percent and not more than 40 weight percent of the nonwoven article. The nonwoven article further comprises a plurality of synthetic microfibers having a length of less than 25 millimeters and a minimum transverse dimension of less than 5 microns, wherein the synthetic microfibers make up at least 1 weight percent of the nonwoven article.
[0009]In another embodiment of the present invention, there is provided a wet-laid process to produce a bound nonwoven article. The first step of the process

Problems solved by technology

Unfortunately, many of the methods or compositions mentioned above lack versatility in their methods or properties, thus limiting their application to specific end uses.
In addition, many of the binder compositions utilized above lack the ability to be modified in order to fit a wide array of end use pr

Method used

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Examples

Experimental program
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example 1

[0177]A sulfopolyester polymer was prepared with the following diacid and diol composition: diacid composition (71 mole percent terephthalic acid, 20 mole percent isophthalic acid, and 9 mole percent 5-(sodiosulfo) isophthalic acid) and diol composition (60 mole percent ethylene glycol and 40 mole percent diethylene glycol). The sulfopolyester was prepared by high temperature polyesterification under a vacuum. The esterification conditions were controlled to produce a sulfopolyester having an inherent viscosity of about 0.31. The melt viscosity of this sulfopolyester was measured to be in the range of about 3,000 to 4,000 poise at 240° C. and 1 rad / sec shear rate.

example 2

[0178]The sulfopolyester polymer of Example 1 was spun into bicomponent segmented pie fibers and formed into a nonwoven web according to the procedure described in Example 9 of U.S. 2008 / 0311815, herein incorporated by reference. During the process, the primary extruder (A) fed Eastman F61HC PET polyester melt to form the larger segment slices into the segmented pie structure. The extrusion zones were set to melt the PET entering the spinnerette die at a temperature of 285° C. The secondary extruder (B) processed the sulfopolyester polymer of Example 1, which was fed at a melt temperature of 255° C. into the spinnerette die. The melt throughput rate per hole was 0.6 gm / min. The volume ratio of PET to sulfopolyester in the bicomponent extrudates was set at 70 / 30, which represents the weight ratio of about 70 / 30. The cross-section of the bicomponent extrudates had wedge shaped domains of PET with sulfopolyester polymer separating these domains.

[0179]The bicomponent extrudates were mel...

example 3

[0184]The nonwoven webs of Example 2 having basis weights of both 140 gsm and 110 gsm were hydroentangled using a hydroentangling apparatus manufactured by Fleissner, GmbH, Egelsbach, Germany. The machine had five total hydroentangling stations wherein three sets of jets contacted the top side of the nonwoven web and two sets of jets contacted the opposite side of the nonwoven web. The water jets comprised a series of fine orifices about 100 microns in diameter machined in two-feet wide jet strips. The water pressure to the jets was set at 60 bar (Jet Strip #1), 190 bar (Jet Strips #2 and 3), and 230 bar (Jet Strips #4 and 5). During the hydroentanglement process, the temperature of the water to the jets was found to be in the range of about 40 to 45° C. The nonwoven fabric exiting the hydroentangling unit was strongly tied together. The continuous fibers were knotted together to produce a hydroentangled nonwoven fabric with high resistance to tearing when stretched in both directio...

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Abstract

A versatile binder comprising at least one or more sulfopolyesters is provided. These sulfopolyester binders can enhance the dry tensile strength, wet tensile strength, tear force, and burst strength of the nonwoven articles in which they are incorporated. Additionally, the water permeability of these binders can be modified as desired by blending different types of sulfopolyesters to produce the binder. Therefore, the binder can be used in a wide array of nonwoven end products and can be modified accordingly based on the desired properties sought in the nonwoven products.

Description

RELATED APPLICATIONS[0001]This application claims priority from U.S. Provisional Application Ser. No. 61 / 405,312, filed on Oct. 21, 2010, the disclosure of which is incorporated herein by reference.BACKGROUND[0002]1. Field of the Invention[0003]The present invention relates to sulfopolyester binders for use in nonwoven articles.[0004]2. Description of the Related Art[0005]Nonwoven articles are found throughout the consumer marketplace. Nonwoven articles, which are generally made up of microfibers and / or nanofibers, are generally produced using a wet-laid or dry-laid process. Various methods or compositions are generally utilized in order to hold the fibers within a nonwoven article together. For example, it is known that nonwoven articles can be held together by (1) mechanical fiber cohesion and interlocking in a web or mat; (2) various techniques of fusing of fibers, including the use of binder fibers; (3) use of a binding resin; (4) use of powder adhesive binders; and / or (5) combi...

Claims

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Application Information

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IPC IPC(8): B32B5/02H01M2/16D04H13/00
CPCD21H13/00D21H13/24D21H21/18D04H1/4391D01F11/06D04H1/587D04H1/435D01F8/14D01D5/36C08G63/6886D04H1/74Y10T442/2008Y10T442/608
Inventor GUPTA, RAKESH KUMARMITCHELL, MELVIN GLENNKLOSIEWICZ, DANIEL WILLIAMCLARK, MARK DWIGHTANDERSON, CHRIS DELBERTMITCHELL, MARVIN LYNNMITCHELL, PAULA HINESWOLFE, AMBER LAYNE
Owner EASTMAN CHEM CO
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