Thin Film Diffusion Barrier
a thin film and diffusion barrier technology, applied in the direction of synthetic resin layered products, tyre parts, using optical means, etc., can solve the problems of increased thickness and rigidity of packaging, damage to trod contained within packaging, and undesired weight increase of packaging
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[0050]Materials. Natural sodium montmorillonite (MMT)(CLOISITE® NA+, which is a registered trademark of Southern Clay Products, Inc.) clay was used as received. Individual MMT platelets had a negative surface charge in deionized water, reported density of 2.86 g / cm3, thickness of 1 nm, and a nominal aspect ratio (l / d)≧200. Branched polyethylenimine (PEI) (Mw=25,000 g / mol and Mn=10,000 g / mol), polyethylene oxide (PEO) (Mw=4,000,000 g / mol) and polyacrylic acid (PAA) (35 wt.% in water, Mw=100,000 g / mol) were purchased from Sigma-Aldrich (Milwaukee, Wis.) and used as received. 500 μm thick, single-side-polished, silicon wafers were purchased from University Water (South Boston, Mass.) and used as reflective substrates for film growth characterization via ellipsometry.
[0051]Film Preparation. All film deposition mixtures were prepared using 18.2 MΩ deionized water, from a DIRECT-Q® Ultrapure Water System, and rolled for one day (24 h) to achieve homogeneity. DIRECT-Q® is a registered trad...
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