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Polymerization reactor and method for producing water absorbent resin

Inactive Publication Date: 2015-03-19
SUMITOMO SEIKA CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The invention is a polymerization reactor that can speed up the process of transferring heat during the polymerization process while still being reliable over a long period of time. The invention also provides a method for efficiently producing a water absorbent resin using this reactor.

Problems solved by technology

Such a large thickness leads to a decrease in the efficiency of heat transfer through the wall of the container body and hence leads to an increase in the heat transfer time, hindering the improvement of productivity.
However, it is difficult to check the condition inside the container body during the use of the polymerization reactor.
Thus, in view of possible breakage or the like of the wall due to deterioration with time, reducing the wall thickness of the passage for a cooling / heating medium provided on the inner side of the container body and bonding the wall by welding causes poor reliability for long use.
However, stainless steel is inferior to carbon steel in heat transfer ability.

Method used

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  • Polymerization reactor and method for producing water absorbent resin
  • Polymerization reactor and method for producing water absorbent resin
  • Polymerization reactor and method for producing water absorbent resin

Examples

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examples

[0058]Advantages of the present invention are demonstrated below by way of Inventive Example and Comparative Example.

Inventive Example

[0059]A water absorbent resin was produced by reversed phase suspension polymerization by using a polymerization reactor X having the structure schematically shown in FIGS. 1 and 2, and the time taken for each step is measured. Specifically, to produce a water absorbent resin in this example, a water-soluble ethylenically unsaturated monomer was subjected to three-stage polymerization by reversed phase suspension polymerization in a petroleum-based hydrocarbon dispersion medium (organic solvent) in the presence of a dispersion stabilizer by using a radical polymerization initiator.

[0060]The container body 1 of the polymerization reactor X used in this Example had a volume of 60 m3. The agitating element 13 was a paddle agitator. The side wall 11 and the bottom wall 12 of the container body 1 were made of three-layer clad steel plate having a thickness...

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Abstract

A polymerization reactor of the present invention includes a container body 1 and a jacket 2 covering the outer surface of the container body 1 and defining a passage for passing a cooling / heating medium between itself and the outer surface of the container body. The container body 1 is made of a clad metal plate including a support metal layer 11a having an inner surface at an inner side of the container body and an outer surface at an outer side of the container body, and an inner corrosion-resistant metal skin layer 11b bonded to the inner surface of the support metal layer and being smaller in thickness than the support metal layer.

Description

FIELD OF THE INVENTION[0001]The present invention relates to a polymerization reactor for performing polymerization reaction. In particular, the present invention relates to a polymerization reactor configured to allow heat transfer through a wall of a container body due to the flow of a cooling / heating medium. The invention also relates to a method for producing a water absorbent resin by using such a polymerization reactor.BACKGROUND ART[0002]FIG. 4 shows a typical polymerization reactor used for producing a polymer such as a water absorbent resin. The illustrated polymerization reactor has a container body 91 for containing e.g. a reaction solution, and an outer shell (jacket 92) that covers the outer surface of the container body 91. A cooling / heating medium (cooling medium or heating medium) is caused to flow through the inside of the jacket 92 as required, so that the content (e.g. reaction solution or reaction mixture) is cooled or heated due to heat transfer through the wall...

Claims

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Application Information

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IPC IPC(8): B01J19/02C08F220/06
CPCB01J19/02B01J2219/0236C08F220/06B01J19/18B01J2219/00094C08F2/01C08F2/38C08F20/00
Inventor MAEDA, NOBUHIROHARA, NAOAKITAKATORI, JUNICHI
Owner SUMITOMO SEIKA CHEM CO LTD
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