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Multilayer Copper-based Zeolite Fiber Medical Material, Protective Equipment and Manufacturing Method

a technology of copper-based zeolite fiber and medical materials, applied in the field of multi-layer copper-based zeolite fiber medical materials, protective equipment and manufacturing methods, to achieve the effects of effective protective measures, low cytotoxicity, and sufficient antibacterial and antiviral performan

Pending Publication Date: 2022-03-31
ZHEJIANG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention is a new type of medical material that can kill bacteria and viruses using copper ions embedded in a copper-based zeolite fiber layer. This material has high antibacterial and viral performance while also being low cytotoxic, meaning it is safe for use in medical masks. The technology used to prepare this material overcomes traditional concerns and defects in the field, making it efficient in killing viruses and safe for practical use. This new material is expected to reshape the industry standard for medical masks and have high theoretical and practical value.

Problems solved by technology

Based on the existing problems in the prior art, through many unremitting experimental studies, the inventors unexpectedly found that the medical material as provided can use the copper ions locked on the surface of the copper-based zeolite fiber layer to interact with biological macromolecules such as bacterial or virus proteins / amino acids and thus kill bacteria or viruses after the bacteria or virus attaches the mask.

Method used

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  • Multilayer Copper-based Zeolite Fiber Medical Material, Protective Equipment and Manufacturing Method
  • Multilayer Copper-based Zeolite Fiber Medical Material, Protective Equipment and Manufacturing Method

Examples

Experimental program
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Effect test

example 1

[0090]The manufacturing method of the mask 1 of the present disclosure includes the following steps:

[0091]The mask includes the outermost layer, the first intermediate layer, the second intermediate layer and the innermost layer; the outermost layer and the second intermediate layer are composed of copper-based zeolite fiber layers; the first intermediate layer is a hydrophobic fiber layer; the innermost layer is a hydrophilic fiber layer.

[0092]Among them, the first intermediate layer is composed of low-density and hydrophobic or water-resistant fibers. Typically, a low-density point-bonded non-woven fabric layer made of polyethylene terephthalate fiber and polyethylene subjected to pressure point bonding processing can be used. The pore size of the first intermediate layer is set at 40-60 μm.

[0093]The innermost layer is a layer of water-absorbing non-woven fabric.

[0094]Among them, the manufacturing methods of the copper-based zeolite fiber layer of the outermost layer and the secon...

example 2

[0121]The manufacturing method of the mask 2 of the present disclosure includes the following steps:

[0122]The mask includes the outermost layer, the first intermediate layer, the second intermediate layer and the innermost layer; the outermost layer and the second intermediate layer are composed of copper-based zeolite fiber layers; the first intermediate layer is a hydrophobic fiber layer; the innermost layer is a hydrophilic fiber layer.

[0123]Among them, the manufacturing methods of the copper-based zeolite fiber layer of the outermost layer and the second intermediate layer are as follows:

[0124](1) Preparing the zeolite precursor solution according to the following molar ratio of 8Na2O:Al2O3:9SiO2:180H2O. 60 cotton fiber were twisted and spun into fiber threads. The zeolite precursor solution and the fiber threads were mixed uniformly and heat treated at 110° C. for 36 h to obtain Y-type zeolite fiber threads. After soaking in a 5M copper sulfate solution for 3 times, each time f...

example 3

[0131]The manufacturing method of the mask 3 of the present disclosure includes the following steps:

[0132]The mask includes the outermost layer, the first intermediate layer, the second intermediate layer and the innermost layer; the outermost layer and the second intermediate layer are composed of copper-based zeolite fiber layers; the first intermediate layer is a hydrophobic fiber layer; the innermost layer is a hydrophilic fiber layer.

[0133]Among them, the manufacturing methods of the copper-based zeolite fiber layer of the outermost layer and the second intermediate layer are as follows:

[0134](1) Preparing the zeolite precursor solution according to the following molar ratio of 8Na2O:Al2O3:9SiO2:180H2O. 60 cotton fiber were twisted and spun into fiber threads. The zeolite precursor solution and the fiber threads were mixed uniformly and heat treated at 110° C. for 36 h to obtain Y-type zeolite fiber threads. After soaking in a 5 M copper sulfate solution for 3 times, each time ...

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Abstract

The present disclosure is to provide a medical material, medical protective equipment with both low cytotoxicity and high-efficiency antibacterial, antiviral properties and its manufacturing method. The multi-layer copper-based zeolite fiber medical material of the present disclosure includes a four-layer structure, including the outermost layer, the first intermediate layer, the second intermediate layer, and the innermost layer in sequence; the outermost layer and the second intermediate layer are copper-based zeolite fiber layer, the first intermediate layer is a hydrophobic fiber layer, and the innermost layer is a hydrophilic fiber layer; the pore size of the copper-based zeolite fiber layer of the outermost layer is greater than the pore size of the hydrophobic fiber layer of the first intermediate layer; the copper-based zeolite fiber layer contains copper-based zeolite and fiber threads, the fiber threads are formed by twisting fibers; the copper-based zeolite is independently dispersed on the fiber surface.

Description

CROSS REFERENCE OF RELATED APPLICATIONS[0001]This application claims priority to Chinese Patent Application No. 202010839473.6, filed on Aug. 19, 2020, entitled “Multilayer Copper-based Zeolite Fiber Medical Material, Medical Protective Equipment and Manufacturing Method,” in the China National Intellectual Property Administration (CNIPA), the entire contents of which are hereby incorporated by reference in their entireties.TECHNICAL FIELD[0002]This disclosure relates to the field of sanitary appliances used for epidemic prevention, in particular to a medical material with sufficiently low cytotoxicity, high antibacterial and effective antiviral performance. Specially, it can be used to prepare biosafety medical materials and medical protective equipment for killing SARS-CoV-2.BACKGROUND[0003]The emergence of new and sudden infectious diseases has caused great harm to human health, social politics, and economy. Coronavirus is a large family of viruses that can cause infectious disea...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): A01N59/20B01D39/20A41D13/11A41D31/10A01N25/34
CPCA01N59/20B01D39/2041A41D13/1192A41D31/10A01N25/34B01D2239/10B01D2239/0421B01D2239/0428B01D2239/0622B01D2239/0618B01D2239/1241B01D2239/0442B32B5/022B32B5/024B32B5/26B32B37/06A41D31/02A41D31/305A41D19/015A41D19/0006A43B23/0235A61F11/06B32B2307/7145B32B2307/728B32B2307/73B32B2260/021B32B2260/04B32B2437/00B32B2437/02B32B2437/04B32B2262/062B32B2262/0284B32B2262/0253A41D2500/30A41D2500/50A61L31/128A61L2300/102A61L2300/404A61L2400/12Y02A50/30B32B2262/10B32B5/265A62B18/02D06M11/79A41D13/05B01D39/2031D06M2101/04D10B2509/00
Inventor FAN, JIEXIAO, LIPINGYU, LISHALI, DANSHI, YIFENGYAO, HANGPING
Owner ZHEJIANG UNIV