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Image display panel having antistatic film with transparent and electroconductive properties and process for processing same

a technology of transparent and electroconductive properties and image display panels, which is applied in the manufacture of coatings, cathode ray tubes/electron beam tubes, etc., can solve the problems of affecting the anti-static function of the front protection glasses of television receivers or other display devices, accumulating, and fouling the panel surface, etc., to achieve the effect of superior anti-static function

Inactive Publication Date: 2001-05-22
HITACHI LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

An object of the invention is to provide image display panels superior in antistatic function.
Another object of the invention is to provide a process for producing image display panels superior in antistatic function.
A further object of the invention is to provide image display panels superior in both antistatic and reflection inhibiting functions.

Problems solved by technology

As regards the inhibition of electrification, the wide use of explosion-proof cathode ray tubes in recent years has brought about the uselessness of the front protecting glasses of television receivers or of other display devices and, in consequence, the front parts of cathode ray tubes have become bare.
This has caused matters such that a person upon directly touching the front part (panel) of a cathode ray tube, is strongly shocked by high voltage electrostatic charge present on the panel surface.
Moreover, the electrified panel surface absorbs atmospheric dirt or dust, which accumulates and fouls the panel surface.
This raises the problem of images formed on the panel being hard to see.
In addition, the outer surfaces of the panels (image display panels) of Braun tubes are glassy and hence are liable to strongly reflect external light, making it difficult to read images formed on the panels.
In addition, the film fixing temperature cannot be raised over 80.degree. C. because some silanol groups (--Si--OH) must be left in the film constitution (at higher temperatures all the silanol groups convert to form the Si--O--SiO siloxane structure).
Vapor deposition methods are not fitted for mass production, since they generally require large-scale apparatus for vacuum deposition, sputtering, CVD (chemical vapor deposition), or the like and need treatment in vacuo.
Moreover, these methods involve significant problems in fabrication cost as well as in increase in throughput.
The above-mentioned method of forming transparent conductive films in the form of strips requires more operation steps, requiring high production costs.
The formation of extra fine conductor wires in the form of strips has many problems in production cost and in product performance.
Hence it is difficult to form uniform unevenness throughout the glass surface.
This raises the problem of such panels displaying images of low degrees of resolution.
Therefore the intended antistatic effect cannot be obtained.
According to the method of adhering telepanels provided with AR coats by vapor deposition, excellent reflection inhibiting efficiency can be achieved, but the antistatic effect cannot be obtained since the AR coats consist of an insulator, and in addition the fabrication cost is high.

Method used

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  • Image display panel having antistatic film with transparent and electroconductive properties and process for processing same
  • Image display panel having antistatic film with transparent and electroconductive properties and process for processing same
  • Image display panel having antistatic film with transparent and electroconductive properties and process for processing same

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first embodiment

The first embodiment is a process for producing image display panels such as cathode ray tube, which comprises coating the front surface of an image display panel with an alcoholic solution containing an alkoxysilane and at least one of SnO.sub.2, In.sub.2 O.sub.3, and Sb.sub.2 O.sub.3, burning the resulting coat preliminarily to convert it into a transparent conductive film, then spray-coating this film with an alcoholic solution of alkoxysilane, and burning the whole to form a conductive coat having fine SiO.sub.2 projections at its surface.

second embodiment

The second embodiment is a process for producing image display panels such as cathode ray tubes, which comprises the steps of: forming a transparent conductive film on the front surface of an image display panel; dispersing fine SiO.sub.2 particles of 100-10,000 .ANG. in diameter in an alcoholic solution of alkoxysilane Si(OR.sub.1).sub.4, wherein R.sub.1 is alkyl, and applying this dispersion on the transparent conductive film formed on the front surface of the panel; and heating the resulting coat to decompose the Si(OR.sub.1).sub.4 contained therein and form a thin SiO.sub.2 film, thereby coating and fixing the fine SiO.sub.2 particles with the thin SiO.sub.2 film.

In the first place, the step of forming the transparent conductive film is described in detail. Since this film is formed on an image display panel such as the panel of a cathode ray tube, it is desirable to form this film under such conditions, particularly temperature conditions (up to about 500.degree. C.), as to giv...

third embodiment

The third embodiment is a process for producing image display panels, which comprises the steps of; dispersing fine SiO.sub.2 particles of 100-10,000 .ANG. in diameter and particles of at least one additive selected from hygroscopic metal salts and conductive metal oxides in an alcoholic solution of alkoxysilane Si(OR.sub.1).sub.4 ; applying this dispersion on the front surface of an image display panel and heating the coating surface to decompose the Si(OR.sub.1).sub.4, thereby forming a thin SiO.sub.2 film to cover and fix the fine SiO.sub.2 particles with the thin SiO.sub.2 film, thus forming a film having non-glare function as well on the front surface of the panel.

The amounts of materials and the manner of using materials, in this embodiment, are almost the same as in the second embodiment. Therefore the description of the amounts and of the manner are omitted. In this embodiment, however, there is no step of forming such a transparent conductive film as is formed in the second...

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Abstract

There are disclosed an image display panel having an antistatic film comprising a SiO2 coat of transparent and electroconductive properties on the front surface of said panel; the coat containing fine particles of at least one compound selected from electroconductive metal oxides and hygroscopic metal salts; and a process for producing the same.

Description

BACKGROUND OF THE INVENTION1. Field of the InventionThe present invention relates to image display panels and a process for producing the same, and more particularly, to image display panels, especially screen panels of cathode ray tubes, the front surfaces of which are improved in antistatic properties and if necessary, coated with films best suited for minimizing the reflection of external light, and to a process for producing such panels.2. Description of Related ArtTransparent base plates made of glass or the like are used for image display panels, as represented by those of cathode ray tubes and liquid crystal display devices. It is desired to inhibit these image display panels from electrification, i.e. being charged with electricity, and from the reflection of external light.As regards the inhibition of electrification, the wide use of explosion-proof cathode ray tubes in recent years has brought about the uselessness of the front protecting glasses of television receivers or...

Claims

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Application Information

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IPC IPC(8): H01J29/28H01J29/18H01J29/86
CPCC03C17/007C03C2217/211C03C2217/213C03C2217/215C03C2217/452C03C2217/465C03C2217/476C03C2217/478C03C2217/48C03C2217/732C03C2217/734C03C2217/77C03C2218/113C03C2218/116C03C2218/154H01J29/28H01J29/868H01J2229/8913H01J29/86
Inventor KAWAMURA, HIROMITSUKAWAMURA, TAKAOKOBARA, KATSUMIENDO, YOSHISHIGE
Owner HITACHI LTD