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Method for processing chemical fibre titanium white from normal TiO2 by drying surface treatment

A surface treatment, chemical fiber titanium dioxide technology, applied in the direction of inorganic pigment treatment, chemical instruments and methods, fibrous fillers, etc., can solve the problems of limiting the application range of chemical fiber titanium dioxide, high operating costs, and unavoidable waste water

Inactive Publication Date: 2009-06-10
上海华力索菲科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the chemical fiber titanium dioxide disclosed in the above-mentioned patent belongs to a class of chemical fiber titanium dioxide that is surface-treated with inorganic compounds. They are mainly used as matting agents for polyamide fibers (nylon), and generally have a water dispersibility of 95.5%), the application range of this chemical fiber titanium dioxide is limited
[0005] "Paint Industry" 1994 No. 4 P22-24 and 1995 No. 6 P11-13 reported the small test work of chemical fiber titanium dioxide and CN1271746 disclosed a surface treatment technology and production method of chemical fiber titanium dioxide, but they They all belong to wet surface treatment technology, using conventional wet processing techniques such as beating, grinding, dispersing, surface treatment, etc., there are high operating costs, many process parameters required to be controlled (making it difficult to guarantee product quality) and in the production process It is difficult to avoid shortcomings such as waste water discharge, so there is no industrial production report so far
According to our investigation, for a long time, all the processing plants in my country that use chemical fiber titanium dioxide raw materials to produce chemical fiber products rely almost entirely on imports of chemical fiber titanium dioxide raw materials, and are suitable for chemical fiber used in the processing of polyester, acrylic, polypropylene and other chemical fiber products. The production method of titanium dioxide has not been reported by foreign public materials so far. It can be seen that the above-mentioned chemical fiber titanium dioxide is still in the production of commercial secrets in the world.

Method used

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  • Method for processing chemical fibre titanium white from normal TiO2 by drying surface treatment
  • Method for processing chemical fibre titanium white from normal TiO2 by drying surface treatment

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] (1) Pretreatment of raw materials:

[0062] Take 1000 kg of ordinary titanium dioxide with a particle size of 325 mesh (equivalent to a particle size of 43 μm), and carry out ultrafine crushing and classification in a jet mill with a classification device powered by 0.6-1.0 MPa compressed air. Remove particles with a particle size > 3 ~ 5 μm (can be used for other purposes); ultrafine titanium dioxide with a particle size up to the standard (ie particle size ≤ 2 μm) is used as raw material for the next step of processing; particles with a particle size > 2 μm and < 3 μm are automatically returned It enters the airflow crushing system for circular crushing until it reaches the standard.

[0063] Through pretreatment, at least 900 kg of qualified ultrafine titanium dioxide (particle size ≤ 2 μm) raw materials can be obtained for the next step of dry surface treatment.

[0064] (2) Dry surface treatment of ultrafine titanium dioxide at room temperature

[0065] Weigh 100...

Embodiment 2

[0071] Except that the surfactant used is "Sorbitol 0.3kg+Spen20 (spen20) 0.1kg", all the other raw materials and operating process are the same as in Example 1. Finally, about 22.1kg of the first-grade chemical fiber titanium dioxide product with a particle size of <1μm was obtained, and about 78.2kg of the second-grade chemical fiber titanium dioxide product with a particle size of ≥1μm to a radius of ≤2μm was obtained.

[0072] Tested according to conventional methods, the water dispersibility is 95.5% and 95.1% respectively; the heat stability is >55min; the product quality is better than the existing chemical fiber titanium dioxide.

Embodiment 3

[0074] Except that the tensio-active agent used is " tartaric acid 0.25kg+ lauryl alcohol 0.20kg ", all the other raw materials and operation process are all the same as embodiment 1. Finally, 22.1 kg of the first-grade chemical fiber titanium dioxide product with a particle size of <1 μm, and 78.2 kg of the second-grade chemical fiber titanium dioxide product with a particle size of ≥1 μm to ≤2 μm were obtained.

[0075] According to conventional test methods, the water dispersibility of the above products is measured to be 95.7% and 95.3% respectively; the thermal stability is greater than 46 minutes; the quality of the products is better than the existing chemical fiber titanium dioxide.

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Abstract

The invention opened a dry surface treatment to make the chemical fiber titanium white using the TiO2 as the material. First to get the superfine titanium-white powder, next to disperse the powder and the surface active agent to gas-solid or gas-fog using the compression air loading system, last leading into the cyclone, so we can get the two phase titanium white powder. After separating the gas / solid and aging treatment, we get two product which diameter<1um and >=1um or <=2um respectively.

Description

technical field [0001] The invention belongs to the production field of chemical fiber titanium dioxide, in particular to a TiO 2 It is a method of processing raw materials into chemical fiber titanium dioxide through surface treatment. Background technique [0002] Titanium dioxide is an inorganic compound with the molecular formula TiO 2 . Titanium dioxide after surface treatment has good hiding power, refractive index and strong dispersibility in hydrophilic medium, so it is often used in the production of synthetic fibers and artificial fibers such as polyester, wet-process acrylic fibers and viscose fibers. It is widely used as a matting agent, and this surface-treated titanium dioxide is also called chemical fiber titanium dioxide. [0003] Many patent documents disclose chemical fiber titanium dioxide with different properties and preparation methods thereof, such as: 1. U.S. Patent US 350588A and German Patent DE 1060378A disclose a kind of phosphate or vinegar wi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09C1/36C09C3/00D01F1/02
Inventor 葛晓陵季建平王洪斌蔡相涌金海明王象勤钱洪
Owner 上海华力索菲科技有限公司
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