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Method for manufacturing high-strength galvannealed steel sheet

A technology of hot-dip galvanized steel sheet and high-strength alloy, which is applied in hot-dip galvanizing process, metal material coating process, coating, etc., and can solve problems such as long alloying treatment time, delayed zinc alloying reaction, complicated operation, etc. , to achieve the effect of good coating appearance and good coating adhesion

Active Publication Date: 2010-03-10
NIPPON STEEL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In addition, it is known that P in the steel hinders and delays the alloying reaction of zinc, requires a longer alloying treatment time than ordinary steel sheets, and becomes a factor hindering productivity.
In addition, in the case of producing both steel sheets with a high alloying rate (for example, Ti and Nb-added ultra-low carbon steel sheets) and P-added steel sheets on the same production line, it is necessary to optimally manage the Al in the hot-dip Zn plating bath, respectively. Concentration and alloying treatment conditions, etc., the operation becomes complicated

Method used

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  • Method for manufacturing high-strength galvannealed steel sheet
  • Method for manufacturing high-strength galvannealed steel sheet
  • Method for manufacturing high-strength galvannealed steel sheet

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] First, an example related to the method for producing the second half of the high-strength high-ductility alloyed hot-dip galvanizing will be described.

[0033] Table 1 shows the original plates used in the tests. The original plate 1 and the original plate 2 are steel plates that have been cold-rolled, annealed, and pickled. The original plate 3 is a pickled hot-rolled steel plate. In addition, Table 3 also shows the material values ​​measured after temper rolling each original plate.

[0034] After each original plate was degreased under the conditions in Table 2, the pickled steel plates were pickled under the conditions in Table 3. Pre-plating of Ni was performed by electroplating under the conditions in Table 4.

[0035] After pre-plating Ni, in 3% H 2 +N 2 Heated to 450°C at a heating rate of 30°C / sec in an atmosphere, immediately immersed in a hot-dip galvanizing bath (containing 0.15% Al) kept at 450°C, kept for 3 seconds, then wiped, and the unit surface ...

Embodiment 2

[0049] An example related to a method of galvanizing a P-added steel sheet will be described.

[0050] In the following examples, cold-rolled and annealed steel sheets having the compositions shown in Table 6 were used.

[0051] Table 6 Composition of the original test board

[0052]

Embodiment 9~11 and comparative example 4

[0054] Table 7 shows the combinations of the original plates used and the processing conditions. After the first pickling treatment, water washing and drying were carried out. In addition to Comparative Example 4, the second pickling treatment was carried out. After water washing, electroplating was carried out under the conditions shown in Table 4. The adhesion amount was 0.3 g / m 2 The pre-plated Ni. The conditions of the pickling treatment are shown in Table 8. Then, in a 3% hydrogen + 95% nitrogen atmosphere, heat at 40°C / s to 460°C, immediately dip in a hot-dip galvanizing bath containing Al at 455°C, and adjust the weight per unit surface area of ​​the coating by wiping. 60g / m 2 . The Al concentration of the hot-dip galvanizing bath is shown in Table 7. Immediately after wiping, heat up to the specified temperature shown in Table 7 at a heating rate of 50°C / s, and after soaking for a specified time, perform slow cooling at 10°C / s for 3 seconds, and then cool at 20°C / s...

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Abstract

A process for the production of galvannealed steel sheet which comprises subjecting an acid-pickled high-strength steel sheet, an acid-pickled hot-rolled steel sheet containing C: 0.02 to 0.2 % by mass and Mn: 0.15 to 2.5 % by mass, or an annealed acid-pickled cold-rolled steel sheet to additional acid pickling and preplating with Ni, heating the resulting sheet to 430 to 500 C in a non-oxidizingatmosphere, plating the sheet in a plating bath of molten zinc containing 0.05 to 0.2 % by mass of Al, and then subjecting the plated sheet to alloying treatment under heating. The process can give, at an enhanced alloying rate, a galvannealed steel sheet which has both high strength and ductility and a high degree of alloying and is excellent in both the surface appearance of deposit and the tight adhesion of deposit.

Description

technical field [0001] The present invention relates to a method for producing a high-strength alloyed hot-dip galvanized steel sheet. Specifically, it relates to a method using a pre-Ni plating method in which material deterioration due to hot-dip galvanizing and heat treatment in alloying treatment is extremely small, A method for manufacturing a high-strength alloyed hot-dip galvanized steel sheet that can obtain good coating performance. Background technique [0002] As part of measures to reduce the weight of automobiles, high-strength and high-ductility steel sheets are being used for body and exterior panels, running parts, etc. From the viewpoint of corrosion resistance, it is desirable to use alloyed hot-dip galvanized steel sheets for these steel sheets, but as a means of increasing strength, C and Mn added to steel have been known as alloying retarding elements of the galvanized layer, so that It is not easy to balance strength and alloying degree. In particular...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C2/02C23C2/06C23C2/28
Inventor 石塚清和西村一实菊池郁夫川崎薰土师纯二
Owner NIPPON STEEL CORP