Porous electrode base material and process for producing the same

A technology of electrode base material and manufacturing method, which is applied in the direction of battery electrodes, final product manufacturing, sustainable manufacturing/processing, etc., can solve the problems of insufficient fuel cell power generation, difficulty in controlling moisture, and low water retention, and achieves thickness and low cost , excellent bending strength, thin thickness effect

Active Publication Date: 2007-07-18
MITSUBISHI CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, such a material with few pores of 10 μm or less has low water retention, so it is difficult to control moisture, and it is considered that the power generation of the fuel cell cannot be sufficiently performed.

Method used

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  • Porous electrode base material and process for producing the same
  • Porous electrode base material and process for producing the same
  • Porous electrode base material and process for producing the same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0178] As short carbon fibers, polyacrylonitrile (PAN)-based carbon fibers with an average fiber diameter of 7 μm and an average fiber length of 3 mm and PAN-based carbon fibers with an average fiber diameter of 4 μm and an average fiber length of 3 mm were prepared at a ratio of 70:30 (mass ratio). carbon staple.

[0179] Vinylon fibers of 1.1 dtex and a cut length of 5 mm (Unicka Vinylon F manufactured by Unitica Co., Ltd.) were prepared as vinylon fibers.

[0180] Short fibers of polyvinyl alcohol (PVA) (Kuraray Co., Ltd. VBP105-1, cut length 3 mm) were prepared as the organic polymer compound.

[0181] In the slurry tank of the wet short-wire continuous papermaking device, the carbon short fibers are evenly dispersed in water, and the filaments are divided into single fibers. After being fully dispersed, 18 mass parts, 32 parts by mass to evenly disperse PVA short fibers and vinylon short fibers, and output them in a net shape.

[0182] Let the output net pass through th...

Embodiment 2

[0189] A porous electrode substrate having a smooth surface was obtained in the same manner as in Example 1 except that the ratio of short carbon fibers was changed to 50 / 50 (mass ratio). The evaluation results are shown in Tables 2 and 3.

Embodiment 3

[0191] Except that the vinylon fibers were changed to 0.6dtex and vinylon staple fibers with a cut length of 5mm (Unitica Vinylon F manufactured by Unitica Co., Ltd.), a porous material with a smooth surface was obtained in the same manner as in Example 1. Electrode substrate. The evaluation results are shown in Tables 2 and 3.

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Abstract

An electrode base material for solid polymer fuel cell that overcomes the problems of prior art and is most suitable for use in assembling of an inexpensive compact cell stack; and a process for producing the electrode base material. There is provided a porous electrode base material of <= 150 mum thickness, comprising carbon staple fibers of 3 to 9 mum diameter dispersed in random directions within a substantially two-dimensional plane, these carbon staple fibers bound to each other by an amorphous resin carbide, further these carbon staple fibers crosslinked to each other by a filamentous resin carbide. It is also intended to provide an electrode base material for solid polymer fuel cell that overcomes the problems of prior art, realizing low cost, smooth supply and discharge of gas and water for use in reaction and exertion of cell performance. Thus, further, there is provided a porous electrode base material, comprising carbon staple fibers of 3 to 9 mum diameter dispersed in random directions within a substantially two-dimensional plane, these carbon staple fibers bound to each other by an amorphous resin carbide, further these carbon staple fibers crosslinked to each other by a network resin carbide of <= 3 mum minimum fiber diameter.

Description

technical field [0001] The present invention relates to a porous electrode substrate and a manufacturing method thereof. Background technique [0002] The porous electrode substrate is a material located between the separator and the catalyst layer in the solid polymer fuel cell. The material is required not only to function as an electrical conductor between the separator and the catalyst layer, but also to distribute gases such as hydrogen and oxygen supplied from the separator to the catalyst layer, and to absorb water generated from the catalyst layer and function to discharge to the outside. Carbon materials are currently generally considered effective. [0003] Conventionally, in order to enhance the mechanical strength, methods such as finely bonding short carbon fibers and resin carbides have been used, but since the gas permeability decreases, the performance often decreases when it is installed in a fuel cell. On the other hand, if it is desired to maintain a la...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/96H01M4/88
CPCY02E60/521Y02E60/50Y02P70/50
Inventor 中村诚大桥英彦浜田光夫三原和茂隅冈和宏
Owner MITSUBISHI CHEM CORP
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