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Diffusion prevention method for inorganic fused salt on magnesium alloy surface

A technology of magnesium alloy and mixed molten salt, applied in the direction of metal material coating process, etc., can solve the problems of deformation and structural change of magnesium and magnesium alloy parts, loss of protective function, and high preparation temperature, so as to reduce production cost and protect performance. The effect of improving and reducing energy consumption

Inactive Publication Date: 2007-10-24
SHANGHAI JIAO TONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the preparation temperature of this method is high, and it is easy to cause deformation and structure change of magnesium and magnesium alloy parts with low melting point, thin diffusion layer, and coating defects lead to loss of protection function

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The material is extruded AZ91D magnesium alloy, and the specific operation steps are:

[0026] 1) Carry out mechanical decontamination (such as sandblasting, sandpaper polishing) on ​​the surface of the magnesium alloy to remove surface pollutants, then degrease with acetone, rinse with alcohol, and then dry in the air;

[0027] 2) Choose anhydrous AlCl 3 Prepare 500g AlCl with anhydrous NaCl in a molar ratio of 2:3 3 -NaCl inorganic mixed molten salt, packed in a dry ceramic crucible;

[0028] 3) Put the pretreated magnesium alloy into a ceramic crucible filled with inorganic mixed molten salt, and ensure that the magnesium alloy does not touch the crucible wall, then quickly bury the sample with the same mixed salt, and cover the crucible lid;

[0029] 4) Put the ceramic crucible with magnesium alloy into the furnace to heat the molten salt to diffuse. The heating temperature is generally controlled at 230°C, and the holding time is 5 hours; , to make the inorganic...

Embodiment 2

[0033] The material is extruded AZ91D magnesium alloy, and the specific operation steps are:

[0034] 1) Carry out mechanical decontamination (such as sandblasting, sandpaper polishing) on ​​the surface of the magnesium alloy to remove surface pollutants, then degrease with acetone, rinse with alcohol, and then dry in the air;

[0035]2) Select anhydrous AlCl3 and anhydrous NaCl in a molar ratio of 4:1 to prepare 500 g of AlCl3-NaCl inorganic mixed molten salt, and put it into a dry ceramic crucible;

[0036] 3) Put the pretreated magnesium alloy into a ceramic crucible filled with inorganic mixed molten salt, and ensure that the magnesium alloy does not touch the crucible wall, then quickly bury the sample with the same mixed salt, and cover the crucible lid;

[0037] 4) Place the ceramic crucible with magnesium alloy into the furnace to heat the molten salt to diffuse. The heating temperature is generally controlled at 320°C, and the holding time is 8 hours; , to make the i...

Embodiment 3

[0041] The material is pure magnesium, and the specific operation steps are:

[0042] 1) Carry out mechanical decontamination (such as sandblasting, sandpaper polishing) on ​​the surface of the magnesium alloy to remove surface pollutants, then degrease with acetone, rinse with alcohol, and then dry in the air;

[0043] 2) Choose anhydrous AlCl 3 Prepare 500g AlCl with anhydrous NaCl in a molar ratio of 1:1 3 -NaCl inorganic mixed molten salt, packed in a dry ceramic crucible;

[0044] 3) Put the pretreated magnesium alloy into a ceramic crucible filled with inorganic mixed molten salt, and ensure that the magnesium alloy does not touch the crucible wall, then quickly bury the sample with the same mixed salt, and cover the crucible lid;

[0045] 4) Place the ceramic crucible with magnesium alloy into the furnace to heat the molten salt to diffuse. The heating temperature is generally controlled at 300°C and the holding time is 6 hours; , to make the inorganic molten salt sy...

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PUM

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Abstract

The invention discloses a dispersing protective method of inorganic fused salt on the magnesium alloy surface in the antiseptic technical domain of metal surface, which comprises the following steps: cleaning the surface of magnesium alloy; placing the alloy into inorganic fusing salt; selecting AlCl3-NaCl or AlCl3-NaCl-KCl as the inorganic fusing salt system; proceeding induction heating for the inorganic fusing salt system; forming metal compound on the surface of magnesium alloy; connecting magneium-aluminium metal compound and magnesium alloy base without generating surface cracking or stripping easily.

Description

technical field [0001] The invention relates to a method in the technical field of metal surface anticorrosion, in particular to a method for protecting magnesium alloy surface from inorganic molten salt diffusion. Background technique [0002] Although magnesium alloy has many excellent properties, it is easy to be corroded due to its active chemical properties. The basic carbonate film formed by its natural passivation in the air is thin and brittle, and its corrosion resistance is very poor, which limits magnesium and its corrosion resistance. Further applications of the alloy. Therefore, magnesium alloys must be used as structural materials with reliable surface protection measures. At present, the surface protection methods of magnesium alloys mainly include chemical conversion coating, anodic oxidation film layer, surface metal coating (electroless plating, electroplating, etc.), diffusion coating, laser surface modification, vapor deposition layer, organic coating, e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C22/70C23C22/77C23C22/78
Inventor 胡文彬何美凤刘磊仵亚婷
Owner SHANGHAI JIAO TONG UNIV