Full-biological degradation nonwoven cloth material
A technology of biodegradable materials and degradable materials, applied in the field of fully biodegradable non-woven materials, can solve problems such as cold flow and poor dimensional stability
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Embodiment 1
[0012] With 22kg carbon dioxide-propylene oxide copolymer (number average molecular weight 87,000, 88wt%), 0.5kg maleic anhydride (2wt%) and 2.5kg carbon dioxide-epoxycyclohexane copolymer (number average molecular weight 5400, molecular weight distribution: 1.2, 10wt%) after blending in an internal mixer, the resulting blend does not flow cold at 70°C. The raw material is granulated by a twin-screw extruder, and melted and extruded at 160-170°C after drying. The length-to-diameter ratio of the screw is 25:1. , web forming, reinforcement, curling and other processes to prepare degradable non-woven fabric products, which can maintain dimensional stability at 70 °C.
Embodiment 2
[0014] 18kg carbon dioxide-propylene oxide copolymer (number average molecular weight 148,000, 72wt%), 0.5kg maleic anhydride (2wt%) and 6.5kg carbon dioxide-epoxycyclohexane copolymer (number average molecular weight 7600, molecular weight distribution: 1.2 , 26wt%) After blending in an internal mixer, the obtained blend did not flow cold at 70°C. The blend is granulated by a twin-screw extruder, and melted and extruded at 170-180°C after drying, wherein the length-to-diameter ratio of the screw is 25:1. Degradable non-woven fabric products are prepared through processes such as filament separation, web forming, reinforcement, and crimping. The non-woven fabric maintains dimensional stability at 75°C.
Embodiment 3
[0016] With 15kg carbon dioxide-ethylene oxide copolymer (number average molecular weight 114,000, 60wt%), 0.5kg maleic anhydride (2wt%) and 9.5kg carbon dioxide-epoxy cyclohexane copolymer (number average molecular weight 5400, molecular weight distribution: 1.3, 38wt%) after blending in an internal mixer, the resulting blend did not flow cold at 80°C. The blend is granulated by a twin-screw extruder, and melt-extruded at 160-170°C after drying, wherein the length-to-diameter ratio of the screw is 30:1. Degradable non-woven fabric products are prepared through processes such as filament separation, web forming, reinforcement, and crimping. The non-woven fabric maintains dimensional stability at 80°C.
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