Bi-component bisphenol A type epoxy resin structured fluid sealant and preparation thereof

An epoxy resin, two-component technology, applied in the direction of epoxy resin glue, chemical instruments and methods, adhesives, etc., can solve the problems of high brittleness, low peel strength, and large intermolecular force of epoxy polymers

Inactive Publication Date: 2009-01-14
SYST EQUIP CO LTD OF THE 28TH RES INST LI YANG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because this adhesive contains hydroxyl active groups and epoxy groups, there is a strong hydrogen bond between them, resulting in greater intermolecular force, greater brittleness, poor flexibility, and poor peel strength of the cured epoxy polymer. low level problem
Due to the complex application environment of the box body, especially the military van, higher requirements are placed on the quality of the box body, and this simple epoxy resin glue is far from meeting the assembly requirements of the box body

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The formula and weight ratio of two-component bisphenol A epoxy resin structural sealant:

[0028] Component A: 85 parts of bisphenol A type epoxy resin, 15 parts of toughening agent Qishi QS-BE tough epoxy resin, 85 parts of silicon micropowder with 99% silica content as filler, plasticizer phthalic acid 20 parts of butyl ester;

[0029] Component B: 50 parts of curing agent 934 modified amine, 50 parts of silicon micropowder with 99% silica content as filler, and 10 parts of iron oxide powder.

[0030] The preparation method comprises the following steps:

[0031] a. Pour the above-mentioned component A raw materials into a mixing bucket, put them into an electric mixer, and stir for 30 minutes to obtain a uniform off-white fluid, pour it out, and seal it for storage to obtain component A;

[0032] b. Pour the above-mentioned component B raw materials into a mixing bucket, put them into an electric mixer, and stir for 30 minutes to obtain a uniform red fluid, pour i...

Embodiment 2

[0035] The formula and weight ratio of two-component bisphenol A epoxy resin structural sealant:

[0036] Component A: 75 parts of bisphenol A type epoxy resin, 8 parts of toughening agent KISS QS-BE tough epoxy resin, 95 parts of silicon micropowder with a silica content of 98.5% as a filler, and phthalic acid as a plasticizer 25 parts of butyl ester;

[0037] Component B: 60 parts of curing agent 934 modified amine, 45 parts of silicon micropowder with 98.5% silica content as filler, and 15 parts of iron oxide powder.

[0038] The preparation method comprises the following steps:

[0039] a. Pour the above-mentioned component A raw materials into a mixing bucket, put them into an electric mixer, and stir for 20 minutes to obtain a uniform off-white fluid, pour it out, and seal it for storage to obtain component A;

[0040] b. Pour the above-mentioned component B raw materials into a mixing bucket, put them into an electric mixer, and stir for 25 minutes to obtain a uniform...

Embodiment 3

[0043] The formula and weight ratio of two-component bisphenol A epoxy resin structural sealant:

[0044] Component A: 95 parts of bisphenol A type epoxy resin, 22 parts of toughening agent KISS QS-BE tough epoxy resin, 75 parts of silicon micropowder with 99.5% silica content as filler, plasticizer phthalic acid 15 parts of butyl ester;

[0045] Component B: 40 parts of curing agent 934 modified amine, 45 parts of silicon micropowder with 99.5% silica content as filler, and 5 parts of iron oxide powder.

[0046] The preparation method comprises the following steps:

[0047] a. Pour the above-mentioned component A raw materials into a mixing bucket, put them into an electric mixer, and stir for 40 minutes to obtain a uniform off-white fluid, pour it out, and seal it for storage to obtain component A;

[0048] b. Pour the above-mentioned component B raw materials into a mixing bucket, put them into an electric mixer, and stir for 35 minutes to obtain a uniform red fluid, pour...

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PUM

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Abstract

The invention discloses sealant of a dual-component and bisphenol A type epoxy resin structure and the preparation method, which comprises a first component and a second component, wherein, the first component comprises 75 parts to 95 parts of bisphenol A type epoxy resin, 8 parts to 22 parts of toughening agent, 75 parts to 95 parts of filling agent and 15 parts to 25 parts of plasticizing agent, the second component comprises 40 parts to 60 parts of curing agent, 45 parts to 55 parts of filling agent and 5 parts to 15 parts of ferric oxide powder. The preparation method comprises the followings: the preparation of the first component: the materials in the first component are poured into an agitating barrel according to the weight parts proportion, evenly stirring the materials, until grayish white fluid is obtained, namely the first component; the preparation of the second component: the materials in the second component are poured into the agitating barrel according to the weight part proportion, evenly stirring the materials, until grayish red fluid is obtained, namely the second component; the first component and the second component are mixed and evenly stirred according to the weight part of 2.8 to 3.2:1, and the sealant of the dual-component and bisphenol A type epoxy resin structure is obtained. The sealant has the advantages that the pliability is good, the stripping strength is strong, and the physical mechanical performance and the process performance are well improved.

Description

technical field [0001] The invention relates to a structural sealant and a preparation method thereof, in particular to a two-component structural sealant used for van body assembly, foam bonding in aluminum frames, and the like and a preparation method thereof. Background technique [0002] At present, simple epoxy resin adhesives are generally used for sealants used for van body assembly and foam bonding in aluminum frames. Because this adhesive contains hydroxyl active groups and epoxy groups, there is a strong hydrogen bond between them, resulting in greater intermolecular force, greater brittleness, poor flexibility, and poor peel strength of the cured epoxy polymer. Inferior question. Due to the complex application environment of the box body, especially the military van, higher requirements are placed on the quality of the box body, and this simple epoxy resin glue is far from meeting the assembly requirements of the box body. Contents of the invention [0003] Th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J163/02C09K3/10
Inventor 许自力石小富周玲
Owner SYST EQUIP CO LTD OF THE 28TH RES INST LI YANG
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