Single-component cationoid water-soluble epoxy-polyurethane anticorrosion primer system drying at 150 DEG C
A cationic, water-based epoxy technology, used in polyurea/polyurethane coatings, anti-corrosion coatings, epoxy resin coatings, etc., can solve problems such as serious water resistance and achieve excellent construction performance, good overall performance, and good elasticity. Effect
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[0024] The preparation method of above-mentioned aqueous cationic epoxy resin is characterized in that it comprises the following steps:
[0025] (1) Preparation of modified epoxy resin: Put 20-35 parts of epoxy resin, 10-30 parts of alcohol ethers and ketone solvents into the reaction kettle, stir and dissolve at 50°C-80°C for 1 hour, then add 0.5% fatty amine -2 parts were reacted at 80°C-90°C for 2-3 hours; after the reaction was completed, 10-25 parts of ketimine resin was added dropwise at 75°C-90°C into the reactor and kept warm for 1.5-2.5 hours to obtain modified epoxy resin;
[0026] (2) Preparation of curing agent: Put 5-20 parts of aromatic polyisocyanate into the reaction pot, add or drop 3-30 parts of alcohol ether monohydroxyl compound or heterocyclic hydroxyl-containing compound in batches at 20-50°C, 0-80 parts of polyether or polycarbonate diol (if the polycarbonate diol or polyether needs to be dissolved in a solvent in advance); then keep warm at 40-60°C fo...
Embodiment 1
[0029] Put 76 parts of TDI into the reaction pot, start stirring and add 46 parts of tetrahydrofurfuryl alcohol in batches below 50°C, keep warm at 50°C for half an hour, then raise the temperature to 80°C and keep warm for 2 hours to obtain a semi-closed polyurethane curing agent.
Embodiment 2
[0031] Put 33.4 parts of acetylacetone, 55.3 parts of TDI, 1 part of dimethylethanolamine, and 80 parts of solvent butanone into the reaction pot, heat and stir, heat at 70°C for 30 minutes, then raise the temperature to 85°C and react for 4 hours to obtain the closed type Polyurethane curing agent.
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