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Cationic electrodeposition paint compositions

一种阳离子电沉积、组合物的技术,应用在电泳涂料、防腐涂料、环氧树脂涂料等方向,能够解决涂膜防腐蚀性降低、涂料稳定性降低等问题,达到涂料稳定性优异、膜厚保持性优异、电沉积涂布适性优异的效果

Active Publication Date: 2009-03-18
KANSAI PAINT CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] However, when a large amount of polyether polyol described in JP-A-2001-3005 or a specific polyether compound with a molecular weight of 1000 or less described in JP-A-2006-274234 is added to the electrodeposition paint, the anti- Corrosion reduction, electrodeposition coatings are subject to mechanical load for a long time, there are problems such as possible reduction in coating stability

Method used

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  • Cationic electrodeposition paint compositions
  • Cationic electrodeposition paint compositions
  • Cationic electrodeposition paint compositions

Examples

Experimental program
Comparison scheme
Effect test

manufacture example 1

[0121] Manufacturing Example 1: Manufacturing Example of Matrix Resin No.1

[0122] Put 185 parts of Denakor EX-821 (Note 1), 950 parts of jER828EL (Note 4), 456 parts of bisphenol A, and tetrabutyl bromide into a 2-liter beaker with a thermometer, a reflux cooler, and a stirrer. 0.8 part of ammonium chloride was reacted at 160° C. until the epoxy equivalent became 800.

[0123] Next, add 359 parts of methyl isobutyl ketone, then add 150 parts of diethanolamine and 127 parts of ketimide of methyl isobutyl ketone (purity 84%, methyl isobutyl ketone solution), reacted at 120° C. for 4 hours to obtain matrix resin No.1 solution of an amino group-containing modified epoxy resin with a solid content of 80%. The amine value of matrix resin No. 1 was 69 mgKOH / g, and the number average molecular weight was 2400.

manufacture example 2

[0124] Manufacturing example 2: Manufacturing example of matrix resin No. 2

[0125] Put 471 parts of denacol EX-931 (note 2), 950 parts of jER828EL (note 4), 456 parts of bisphenol A and tetrabutyl 0.8 part of ammonium bromide was reacted at 160° C. until the epoxy equivalent became 950.

[0126] Next, add 430 parts of methyl isobutyl ketone, then add 150 parts of diethanolamine and 127 parts of ketimides of methyl isobutyl ketone (purity 84%, methyl isobutyl ketone solution), reacted at 120° C. for 4 hours to obtain matrix resin No.2 solution of modified epoxy resin containing amino groups with a resin solid content of 80%. The amine value of matrix resin No. 2 was 60 mgKOH / g, and the number average molecular weight was 2500.

manufacture example 3

[0127] Manufacturing Example 3: Manufacturing Example of Matrix Resin No.3

[0128] Put 340 parts of Grisier BPP-350 (note 3), 950 parts of jER828EL (note 4), 456 parts of bisphenol A and tetrabutyl bromide into a 2-liter beaker with a thermometer, a reflux cooler, and a stirrer 0.8 part of ammonium chloride was reacted at 160° C. until the epoxy equivalent reached 900.

[0129] Next, add 400 parts of methyl isobutyl ketone, then add 150 parts of diethanolamine and 127 parts of ketimides of methyl isobutyl ketone (purity 84%, methyl isobutyl ketone solution), reacted at 120° C. for 4 hours to obtain a matrix resin No.3 solution of an amino group-containing modified epoxy resin with a solid content of 80%. Base resin No. 3 had an amine value of 64 mgKOH / g and a number average molecular weight of 2,500.

[0130] Table 1 shows the compounding contents and parameters of matrix resins No. 1 to No. 3 in Production Examples 1 to 3.

[0131]

[0132] (Note 1) Denakor EX-821: Nag...

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Abstract

This invention discloses cationic electrodeposition paint compositions which comprise specific amino group-containing modified epoxy resin, specific xylene-formaldehyde resin-modified, amino group-containing epoxy resin and blocked polyisocyanate curing agent at specific blend ratios, and which can form coating film of excellent film thickness retention, finished appearance and electrocoatabilityon galvanized alloy steel sheet and of good corrosion resistance, even when the amount of volatile organic compound in the cationic electrodeposition paint is reduced.

Description

technical field [0001] The present invention relates to water dispersibility containing amino group-containing modified epoxy resin (A), xylene-formaldehyde resin modified amino group-containing epoxy resin (B) and blocked polyisocyanate curing agent (C) as resin components Excellent cationic electrodeposition coatings, especially those related to excellent film thickness retention, workability, and electrodeposition coating suitability on alloyed hot-dip galvanized steel sheets even if the volatile organic compounds in cationic electrodeposition coatings are reduced and can be formed A cationic electrodeposition coating composition for a coating film having good corrosion resistance. Background technique [0002] Cationic electrodeposition paint compositions are widely used as primers for conductive metal products such as automobile bodies, which require these properties because they are excellent in coating workability and the corrosion resistance of the formed coating fil...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D5/44C09D5/08B32B33/00
CPCC08G59/184C08G18/8064C08G2150/90C09D5/4438C09D5/4473C08G18/643C09D163/00
Inventor 西口滋朗岛崎昭彦
Owner KANSAI PAINT CO LTD