Formula of gas well water blocking damage treating agent

A technology for water lock damage and treatment agent, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of self-absorbed water that is not easy to flow back, the degree of water lock damage is reduced, and the radius of the capillary tube is reduced. Small water lock damage, good compatibility, reducing the effect of self-absorption

Inactive Publication Date: 2009-05-06
CNPC SICHUAN GASOLINEEUM GEOPHYSICAL PROSPECTING ENG TECH RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For low-permeability reservoirs, as the permeability decreases, although the amount of foreign fluid entering the reservoir decreases under the same pressure difference, the capillary radius decreases, the self-absorption increases, and this part of self-absorption water is less likely to flow back come out
If the low pressure of the reservoir is added, the degree of water lock damage will increase significantly, but when the permeability decreases to a certain level, the degree of water lock damage will decrease again when the external fluid cannot enter the formation by self-priming

Method used

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  • Formula of gas well water blocking damage treating agent
  • Formula of gas well water blocking damage treating agent
  • Formula of gas well water blocking damage treating agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Example 1: According to the weight percentage, add 65.5% distilled water to the reaction kettle, add 20% main agent benzyl tributylammonium bromide, stir for 20min; heat up to 40°C, then add 2.0% nonionic surfactant nonyl Phenol polyoxyethylene ether, add 0.5% SR18Y fluorocarbon surfactant produced by Shaanxi Senrui Technology Co., Ltd., and stir for 10 minutes; finally add 12.0% cationic surfactant dodecyldimethylbenzyl ammonium chloride, and stir for 20 minutes Get the gas well water lock treatment agent.

Embodiment 2

[0027] Example 2: Also according to the weight percentage, add 54% distilled water in the reactor, add 25% main agent benzyl tributylammonium bromide, stir for 25min; heat up to 40°C, then add 5.0% nonionic surfactant sucrose Fatty acid ester, add 1.0% SR18Y fluorocarbon surfactant produced by Shaanxi Senrui Technology Co., Ltd., and stir for 25 minutes; finally add 15.0% cationic surfactant cetyltrimethylammonium bromide, and stir for 20 minutes to obtain gas well water lock treatment agent.

Embodiment 3

[0028] Example 3: According to the percentage by weight, add 60% distilled water to the reaction kettle, add 22% main agent benzyl tributylammonium chloride, stir for 20min; heat up to 40°C, add 3.0% nonionic surfactant nonylphenol Polyoxyethylene ether, add 0.8% SR18Y fluorocarbon surfactant produced by Shaanxi Senrui Technology Co., Ltd., and stir for 10 minutes; add 14.2% cationic surfactant dodecyldimethylbenzyl ammonium chloride, and stir for 15 minutes to obtain a gas well Water lock treatment agent.

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Abstract

The invention belongs to a fracturing fluid additive, and in particular relates to a formulation of a gas-well water-lock damage treating agent. The formulation is characterized in that the treating agent is formed by matching the following components in weight percentage: 20.0 to 25.0 percent of benzyltributylammonium bromide or benzyltributylammonium chloride as a main agent, 2.0 to 5.0 percent of polyoxyethylene nonyl phenyl ether or sucrose fatty acid ester as nonionic surfactant, 0.5 to 1.0 percent of SR18Y fluorocarbon surfactant produced by Shaanxi Senrui Science and Technology Co., Ltd, 12.0 to 15.0 percent of dodecyl benzyl dimethyl ammonium chloride or hexadecyl trimethyl ammonium bromide as cationic surfactant, and the balance being distilled water. The gas-well water-lock damage treating agent prepared according to the formulation has the advantages of reducing gas-well water-lock damage, lowering starting pressure, improving the gas phase permeability of rock cores and protecting reservoirs.

Description

technical field [0001] The invention belongs to fracturing fluid additive formulations, in particular to a gas well water lock damage treatment agent formula for reducing gas well water lock damage, lowering start-up pressure, improving rock core gas phase permeability and protecting reservoirs. Background technique [0002] Water lock damage seriously affects the development effect of gas reservoirs, and has become one of the main damages of low-permeability tight gas reservoirs. payback period, etc. [0003] The degree of water lock damage is related to the size and distribution of reservoir pore throats, reservoir permeability, pressure and time of interaction between external fluid and rock, original water saturation, formation pressure, contact angle and fluid viscosity and other factors. For low-permeability reservoirs, as the permeability decreases, although the amount of foreign fluid entering the reservoir decreases under the same pressure difference, the capillary...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/62
Inventor 李养池赵倩云李勇陈迎花周然李楷
Owner CNPC SICHUAN GASOLINEEUM GEOPHYSICAL PROSPECTING ENG TECH RES INST
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