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Composite positive electrode material for lithium ion battery and battery using the same

A composite positive electrode material and lithium-ion battery technology, applied in battery electrodes, secondary batteries, active material electrodes, etc., can solve the problems of no pore capacity, difficulty in positive electrode active materials, insufficient high-speed discharge performance of positive electrodes, etc.

Active Publication Date: 2012-09-05
ENVISION AESC JAPAN LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0016] In addition, as disclosed in Patent Document 4, although it is intended to form a conductive path between positive electrode active materials covered with spherical graphite by fibrous carbon, due to the aspect ratio of fibrous carbon (Example of Patent Document 4 In general, the aspect ratio of 75) is generally large, so it is difficult to properly arrange between positive electrode active materials (especially in dry mixing), and it will become a positive electrode active material without appropriate pore capacity, The high-speed discharge performance of the obtained positive electrode was insufficient

Method used

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  • Composite positive electrode material for lithium ion battery and battery using the same
  • Composite positive electrode material for lithium ion battery and battery using the same
  • Composite positive electrode material for lithium ion battery and battery using the same

Examples

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Effect test

Embodiment 1

[0214] In 100 parts by weight of ethanol, add the average particle size of 2μm (primary particle size of 25nm), DBP absorption of 155cm 3 0.4 parts by weight / 100 g of carbon black (manufactured by Tokai Carbon Co., Ltd., #5500) was ultrasonically dispersed using an ultrasonic disperser. The above-mentioned dispersed state is a forcibly dispersed state. 20 parts by weight of lithium manganate having a primary particle diameter of 0.8 μm was added to the dispersion, followed by ultrasonic dispersion. The obtained slurry was evaporated, dried and solidified to obtain a powder (composite particles I, surface coverage: 24%) in which fine particles of carbon black adhered to the surface of lithium manganate. Next, carbon black (manufactured by Denki Kagaku Kogyo Co., Ltd., HS-100, with a DBP absorption of 140 cm) was added to 100 parts by weight of ethanol with an average particle diameter of 1 μm and an aspect ratio of 3.8. 3 / 100g) 2.1 parts by weight, stirred with T.K.Homodispe...

Embodiment 2

[0216] In 100 parts by weight of ethanol, add the average particle size of 10μm (primary particle size of 34nm), DBP absorption of 495cm 30.4 parts by weight per 100 g of Ketjen Black was ultrasonically dispersed using an ultrasonic disperser. 20.4 parts by weight of the composite particle I prepared in Example 1 was added thereto and ultrasonically dispersed. The obtained slurry was evaporated, dried and solidified to obtain composite particles II. Next, carbon black (manufactured by Denki Kagaku Kogyo Co., Ltd., HS-100, with a DBP absorption of 140 cm) was added to 100 parts by weight of ethanol with an average particle diameter of 1 μm and an aspect ratio of 3.8. 3 / 100g) 1.9 parts by weight, stirred with T.K.Homodisper. Then, 20.8 parts by weight of composite particles II were added, mixed with a T.K. Homodisper, and the obtained slurry was evaporated to dry and solidify to obtain a composite positive electrode material 2 . Table 2 shows the physical properties of the c...

Embodiment 3

[0218] In 100 parts by weight of NMP, the average particle size is 10μm (primary particle size is 34nm), and the DBP absorption is 495cm 3 0.4 parts by weight per 100 g of Ketjen Black was ultrasonically dispersed using an ultrasonic disperser. Then add the average particle size of 2μm (primary particle size of 25nm), DBP absorption of 155cm 3 Ultrasonic dispersion was performed at 0.4 parts by weight / 100 g of carbon black (manufactured by Tokai Carbon Co., Ltd., #5500). While irradiating the carbon dispersion liquid with ultrasonic waves, 20 parts by weight of lithium manganate having a primary particle diameter of 0.8 µm was added, followed by ultrasonic dispersion to make it in a forcibly dispersed state. Then, the ultrasonic irradiation was stopped, and Ketjen black was self-agglomerated in NMP to obtain a slurry containing composite particles III. Carbon black (manufactured by Denki Kagaku Kogyo Co., Ltd., HS-100, with a DBP absorption of 140 cm) was added to the slurry...

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Abstract

Disclosed is a composite positive electrode material for lithium ion batteries, which especially enables to achieve excellent high-rate discharge characteristics in a battery. Also disclosed are a slurry, positive electrode and battery using such a composite positive electrode material. Specifically disclosed is a composite positive electrode material for lithium ion batteries, which contains a positive electrode active material (a), a conductive substance (b) having a primary particle diameter of 10-100 nm and / or a fibrous conductive substance (c) having a fiber diameter of from 1 nm to 1 [mu]m, and a conductive substance (d) having an aspect ratio of 2-50. This composite positive electrode material for lithium ion batteries is obtained by mixing the conductive substance (d) with a composition containing the positive electrode active material (a), the conductive substance (b) and / or the conductive substance (c), which composition is obtained by dispersing the positive electrode active material (a), the conductive substance (b) and / or the conductive substance (c) in a solvent to a state where they are forcibly dispersed, and then agglutinating them.

Description

technical field [0001] The present invention relates to a composite positive electrode material for a lithium ion battery containing a positive electrode active material and a conductive material, and a slurry, a positive electrode, and a battery using the material. Background technique [0002] In recent years, electric vehicles, hybrid vehicles, fuel cell vehicles, etc. have attracted attention against the background of rising prices of petroleum resources and the upsurge of the global environmental protection movement, and some of them have been put into practical use. In these drive systems, secondary batteries are indispensable as an auxiliary power source and the like, and high output secondary batteries capable of responding to sudden start and sudden acceleration of automobiles are desired. In addition, from the viewpoint of weight load on the vehicle and increase in fuel consumption, secondary batteries with high energy density are desired. From such a background, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/36H01M4/58H01M4/131H01M4/1391H01M4/50H01M4/505H01M10/0525H01M10/36
CPCY02E60/122H01M4/625Y02T10/7011H01M10/0525H01M4/661H01M2004/021H01M4/1391H01M4/131H01M4/621H01M4/505Y02E60/10H01M4/02H01M4/36H01M4/62H01M10/36Y02T10/70
Inventor 隐岐一雄福本泰久赤木隆一西村谦一金子健人三浦环斋藤崇实川合干夫
Owner ENVISION AESC JAPAN LTD
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