Composite positive electrode material for lithium ion battery and battery using the same
A composite positive electrode material and lithium-ion battery technology, applied in battery electrodes, secondary batteries, active material electrodes, etc., can solve the problems of no pore capacity, difficulty in positive electrode active materials, insufficient high-speed discharge performance of positive electrodes, etc.
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Embodiment 1
[0214] In 100 parts by weight of ethanol, add the average particle size of 2μm (primary particle size of 25nm), DBP absorption of 155cm 3 0.4 parts by weight / 100 g of carbon black (manufactured by Tokai Carbon Co., Ltd., #5500) was ultrasonically dispersed using an ultrasonic disperser. The above-mentioned dispersed state is a forcibly dispersed state. 20 parts by weight of lithium manganate having a primary particle diameter of 0.8 μm was added to the dispersion, followed by ultrasonic dispersion. The obtained slurry was evaporated, dried and solidified to obtain a powder (composite particles I, surface coverage: 24%) in which fine particles of carbon black adhered to the surface of lithium manganate. Next, carbon black (manufactured by Denki Kagaku Kogyo Co., Ltd., HS-100, with a DBP absorption of 140 cm) was added to 100 parts by weight of ethanol with an average particle diameter of 1 μm and an aspect ratio of 3.8. 3 / 100g) 2.1 parts by weight, stirred with T.K.Homodispe...
Embodiment 2
[0216] In 100 parts by weight of ethanol, add the average particle size of 10μm (primary particle size of 34nm), DBP absorption of 495cm 30.4 parts by weight per 100 g of Ketjen Black was ultrasonically dispersed using an ultrasonic disperser. 20.4 parts by weight of the composite particle I prepared in Example 1 was added thereto and ultrasonically dispersed. The obtained slurry was evaporated, dried and solidified to obtain composite particles II. Next, carbon black (manufactured by Denki Kagaku Kogyo Co., Ltd., HS-100, with a DBP absorption of 140 cm) was added to 100 parts by weight of ethanol with an average particle diameter of 1 μm and an aspect ratio of 3.8. 3 / 100g) 1.9 parts by weight, stirred with T.K.Homodisper. Then, 20.8 parts by weight of composite particles II were added, mixed with a T.K. Homodisper, and the obtained slurry was evaporated to dry and solidify to obtain a composite positive electrode material 2 . Table 2 shows the physical properties of the c...
Embodiment 3
[0218] In 100 parts by weight of NMP, the average particle size is 10μm (primary particle size is 34nm), and the DBP absorption is 495cm 3 0.4 parts by weight per 100 g of Ketjen Black was ultrasonically dispersed using an ultrasonic disperser. Then add the average particle size of 2μm (primary particle size of 25nm), DBP absorption of 155cm 3 Ultrasonic dispersion was performed at 0.4 parts by weight / 100 g of carbon black (manufactured by Tokai Carbon Co., Ltd., #5500). While irradiating the carbon dispersion liquid with ultrasonic waves, 20 parts by weight of lithium manganate having a primary particle diameter of 0.8 µm was added, followed by ultrasonic dispersion to make it in a forcibly dispersed state. Then, the ultrasonic irradiation was stopped, and Ketjen black was self-agglomerated in NMP to obtain a slurry containing composite particles III. Carbon black (manufactured by Denki Kagaku Kogyo Co., Ltd., HS-100, with a DBP absorption of 140 cm) was added to the slurry...
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