Flexible polymer dielectric material for electrical condenser and preparation thereof

A flexible polymer and dielectric material technology, applied in the direction of fixed capacitor dielectrics and components of fixed capacitors, can solve problems such as poor mechanical properties and poor combination of two-phase interfaces, and achieve good mechanical properties.

Inactive Publication Date: 2009-08-19
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This dielectric material can solve the problems of poor bonding and poor mechanical properties of the two-phase interface of the current ceramic / polymer composite material, and is a new type of flexible high-dielectric material.

Method used

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  • Flexible polymer dielectric material for electrical condenser and preparation thereof
  • Flexible polymer dielectric material for electrical condenser and preparation thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Example 1: Mix 20% PA11 and 80% PVDF powders according to the volume ratio in an internal mixer at 180-190°C and 15-20r / min; Molding at ~15MPa for 30 minutes, and then cooling under pressure, the PA11 / PVDF alloy material is prepared, and the dielectric constant of the alloy can reach 30.

Embodiment 2

[0020] Example 2: Mix 40% PA9 and 60% PVDF powder according to the volume ratio in an internal mixer at 180-200°C and a speed of 40-50r / min; Molding at 10-15MPa for 30 minutes, and then cooling under pressure, the PA9 / PVDF alloy material was prepared, and the dielectric constant of the alloy could reach 27.

Embodiment 3

[0021] Example 3: Mix 90% PA7 and 10% PVDF pellets according to the volume ratio in an internal mixer at 200-220°C and a rotating speed of 15-30r / min; , Molded under 20MPa for 20min, and then cooled under pressure, the PA7 / PVDF alloy material was prepared, and the dielectric constant of the alloy could reach 35.

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Abstract

The invention relates to a flexible polymer dielectric material used for a capacitor and the preparation thereof. The material is the blending material of fluorine-containing polymer and nylon, wherein, the fluorine-containing polymer is any one of polyvinylidene fluoride, vinylidene fluoride- trifluoroethylene copolymer and vinylidene fluoride-tetrafluoroethylene copolymer; the nylon is any one of PA7, PA9, PA11, PA7/ PA9, PA7/PA11, PA9/PA11 and PA7/ PA9/PA11. The volume ratio between the nylon and the fluorine-containing polymer is 10%-90%: 90%-10%. The preparation steps comprises: 1) under the condition that the temperature is 150-230 DEG C and the rotating speed is 15-50r/min, the nylon and the fluorine-containing polymer are mixed in mixing equipment according to the volume ratio of 10%-90%: 90%-10%, and then the mixture is cooled naturally; 2) the mixture obtained in the step 1) is pressed for shaping in a mould, the mould pressing temperature is 150-230 DEG C, the mould pressing pressure is 10-25MPa, and the pressing time is 15-30min; the pressed mixture is cooled when in pressure maintaining, so that the flexible polymer dielectric material is obtained. The flexible polymer dielectric material has good mechanical property and higher dielectric constant; the property needed by the material can be adjusted by regulating the mixture ratio between the nylon and the fluorine-containing polymer, so that the invention is especially suitable for preparing film dielectric material.

Description

technical field [0001] The invention relates to a flexible dielectric material for capacitors and a preparation method. In particular, it relates to a flexible polymer dielectric material for capacitors and a preparation method thereof. technical background [0002] Dielectric materials, as a kind of functional materials with unique functions and wide applications, play an irreplaceable role in industries such as electronics, motors and cables due to their good ability to store charges and uniform electric field. Especially in recent years, with the rapid development of electronic equipment, capacitors are also developing in the direction of high energy storage, miniaturization, environmental friendliness and flexible molding. Flexible dielectric materials with good flexibility, flexible processing, and good dielectric properties have become the focus of current research. [0003] At present, flexible dielectric materials are mainly ceramic and polymer composites. This ma...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L27/12H01G4/14B29C43/58B29B7/28
Inventor 熊传溪李蕊董丽杰朱庆明刘利萍
Owner WUHAN UNIV OF TECH
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