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Martensite refractory stainless steel and manufacturing method thereof

A manufacturing method and stainless steel technology, applied in the field of martensitic heat-strength stainless steel and its manufacturing, can solve the problems of increasing cost, increasing production cost, and failing to improve steel performance and quality, so as to achieve extended service life, strong heat resistance, and improved The effect of cost performance

Active Publication Date: 2009-09-30
宝武特种冶金有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, there are certain problems in the composition design, quality level and production technology of heat-resistant materials for steam turbines, gas turbines and various engines (such as pressure-resistant and high-temperature resistant shells, discs, blades, shafts, fasteners, etc.) : 1) There are defects in the composition design of steel grades. For example, no or a small amount of strengthening element nitrogen is added to this kind of steel grades, resulting in insufficient heat resistance of the steel.
2) The production process is not standardized. For example, if the double vacuum smelting process is adopted, the overall chemical composition needs to be controlled, which increases the cost but does not improve the performance and quality of the steel, resulting in low economic competitiveness in the steel market
Steel grade 1Cr10Co6NiMoNbN and steel grade 1Cr10Co3W2MoVNbN are respectively added a large amount of precious metals Co and W elements. Although Co can improve the creep strength of steel, it increases the production cost.

Method used

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  • Martensite refractory stainless steel and manufacturing method thereof
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Examples

Experimental program
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Effect test

Embodiment 1

[0038] According to the chemical composition shown in Table 2, it is smelted in a vacuum induction furnace, and its technological process is as follows figure 1 As shown, electroslag remelting after pouring, control of CaF 2 :Al 2 o 3 : MgO ternary slag system ratio, smelting and electroslag remelting process parameters are shown in Table 3. The steel ingot is lower than 450°C into the heating furnace, heated at a rate of ≤50°C / h for 15 hours, homogenized at 1200-1250°C, then cooled to 1160°C, and forged after holding for 3 hours. The billet forging heating time is 2h, the heating temperature is 1120°C, the forging ratio is greater than 6, the final finished product fire is controlled at 1120±10°C, the rolling heating temperature is 1120°C, the heating time is 1h, and the final rolling temperature is greater than 800°C. The forgings were annealed at 720°C for 30 hours, then heated up to 1120°C at an unlimited rate for quenching, held for 2 hours, and then cooled to room te...

Embodiment 2

[0040] According to the chemical composition shown in Table 2, it is smelted in a vacuum induction furnace, and the process parameters of smelting and electroslag remelting are shown in Table 3. The steel ingot is lower than 450°C into the heating furnace, heated at a rate of ≤50°C / h for 16 hours, homogenized at 1200-1250°C, then cooled to 1180°C, and forged after holding for 3 hours. The billet forging heating time is 1.5h, the heating temperature is 1130°C, the forging ratio is greater than 6, the final finished product fire time is controlled at 1120±10°C, the rolling heating temperature is 1118°C, the heating time is 1.1h, and the final rolling temperature is greater than 800°C. Forging annealing, quenching and tempering heat treatment process parameters are shown in Table 4. All the other implementations are the same as in Example 1.

Embodiment 3

[0042] According to the chemical composition shown in Table 2, it is smelted in a vacuum induction furnace, and the process parameters of smelting and electroslag remelting are shown in Table 3. The steel ingot is lower than 450°C into the heating furnace, heated at a rate of ≤50°C / h for 14 hours, homogenized at 1200-1250°C, then cooled to 1190°C, and forged after holding for 3 hours. The billet forging heating time is 1.8h, the heating temperature is 1136°C, the forging ratio is greater than 6, the final finished product fire time is controlled at 1120±10°C, the rolling heating temperature is 1116°C, the heating time is 1.3h, and the final rolling temperature is greater than 800°C. Forging annealing, quenching and tempering heat treatment process parameters are shown in Table 4. All the other implementations are the same as in Example 1.

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Abstract

The invention provides a martensite refractory stainless steel and a manufacturing method thereof. The martensite refractory stainless steel comprises the following chemical compositions by weight percentage: 0.10 to 0.20 weight percent of C, less than or equal to 0.50 weight percent of Mn, less than or equal to 0.50 weight percent of Si, less than or equal to 0.030 weight percent of P, less than or equal to 0.015 weight percent of S, 10.00 to 13.00 weight percent of Cr, 1.50 to 2.50 weight percent of Ni, 0.60 to 1.00 weight percent of W, 1.30 to 1.70 weight percent of Mo, 0.15 to 0.30 weight percent of V, 0.20 to 0.40 weight percent of Nb, 0.02 to 0.12 weight percent of N, and the balance of Fe and inevitable impurities. A martensite stainless steel with strength and toughness matching, strong heat tolerance and corrosion resistance is manufactured by intensified vacuum smelting and forging technology. The martensite refractory stainless steel can work for a long time at high temperature of 650 DEG C, and can satisfy the using requirement of heat resistant critical components applied to steam turbines and combustion turbines.

Description

technical field [0001] The invention relates to heat-resistant stainless steel materials, in particular, the invention relates to a martensitic heat-strength stainless steel and a manufacturing method thereof. Background technique [0002] Heat-resistant steel refers to steel that has sufficient strength at high temperatures, certain oxidation and corrosion resistance, and long-term structural stability. The development of heat-resistant steel is the need for power machinery working at high temperatures, such as steam boilers and steam turbines in thermal power plants, jet engines in the aviation industry, and high-temperature working parts in industrial sectors such as aerospace, ships, petroleum and chemical industries. They are subjected to various loads at high temperatures, such as stretching, bending, torsion, fatigue and impact, etc. In addition, they are also in contact with high temperature, steam, air or gas, and high-temperature oxidation or gas corrosion occurs o...

Claims

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Application Information

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IPC IPC(8): C22C38/48C22C33/04C21D1/26
Inventor 姚长贵徐惠松王敏方静贤杨桦童英豪孟宪玲张杉廖洪军
Owner 宝武特种冶金有限公司
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