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Non-transparent microvoided axially stretched film, production process therefor and process for obtaining a transparent pattern therewith

An antioxidant, polyester technology, applied in the direction of replication/marking method, temperature recording method, printing, etc., can solve the problems of sufficient dimensional stability, insufficient opacity, insufficient whiteness of opaque microporous axially stretched film, etc.

Active Publication Date: 2012-12-26
AGFA GEVAERT AG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0014] Prior art opaque microvoided axially stretched films suffer from insufficient opacity and lack of dimensional stability, or sufficient dimensional stability and insufficient opacity
Additionally, opaque microvoided axially stretched films do not have sufficient whiteness for certain applications

Method used

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  • Non-transparent microvoided axially stretched film, production process therefor and process for obtaining a transparent pattern therewith
  • Non-transparent microvoided axially stretched film, production process therefor and process for obtaining a transparent pattern therewith
  • Non-transparent microvoided axially stretched film, production process therefor and process for obtaining a transparent pattern therewith

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no. 5 approach

[0056] According to the fifth embodiment of the opaque microporous axially stretched self-supporting film of the present invention, the weight ratio of linear polyester to uncrosslinked SAN-polymer is 2.3:1 to 13:1, 2.5:1 to 10 The range of :1 is preferred, and the range of 2.7:1 to 9.0:1 is particularly preferred.

[0057] According to the sixth embodiment of the opaque microporous axially stretched self-supporting film of the present invention, the weight ratio of linear polyester to uncrosslinked SAN-polymer is 2.85:1 to 7.0:1, 3.0:1 to 5.5 The range of :1 is preferred, and the range of 3.2:1 to 4.9:1 is particularly preferred.

[0058] According to the seventh embodiment of the opaque microporous axially stretched self-supporting film of the present invention, the opaque microporous axially stretched self-supporting film is provided with alphanumeric characters, embossed patterns, optional embossed holograms and At least one of continuous halftone or digital image.

[0059] Acc...

no. 4 approach

[0075] According to the fourth embodiment of the method for manufacturing an opaque microporous axially stretched film of the present invention, the method includes a further step, step (iv), wherein the temperature> 2.5N / mm 2 Apply another stretching process to the film at an angle of substantially 90° to the first stretching process under the stretching tension of ≥4.0N / mm 2 The tensile tension of is preferred.

[0076] According to the fifth embodiment of the method for manufacturing an opaque microporous axially stretched film of the present invention, the method includes a further step, step (iv), wherein the stretching tension of >2.5 is substantially equal to the first stretching process. Another stretching process is applied to the film at a 90° angle to at least twice the initial length, and step iv) is performed at a temperature that is at most 30°C higher than the glass transition temperature of the linear polyester matrix, which is higher than the linear poly A tempera...

no. 7 approach

[0078] According to the seventh embodiment of the method for manufacturing an opaque microporous axially stretched film of the present invention, the method further includes a heat fixing step as the fifth step.

[0079] According to the eighth embodiment of the method for manufacturing an opaque microporous axially stretched film of the present invention, the stretch ratio of the longitudinal stretch is about 2 to about 6, preferably about 2.5 to about 5, and particularly preferably 3 to 4 . The higher the stretch ratio, the higher the opacity.

[0080] According to the ninth embodiment of the method for manufacturing an opaque microporous axially stretched film of the present invention, the transverse stretch ratio is about 2 to about 6, and the range of 2.5 to about 5 is preferred, and the range of about 3 to about 4 Especially preferred. The higher the stretch ratio, the higher the opacity. In addition, the higher the stretching rate in % / min, the higher the opacity.

[0081]...

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Abstract

The present invention discloses a film consisting essentially of a continuous phase linear polyester matrix having dispersed therein a non-crosslinked random SAN-polymer and dispersed or dissolved therein at least one ingredient from the group of ingredients consisting of inorganic opacifying pigments, whitening agents, colorants, UV-absorbers, light stabilizers, antioxidants and flame retardants, wherein the film is white, microvoided, non-transparent and axially stretched; the linear polyester matrix has monomer units consisting essentially of at least one aromatic dicarboxylic acid, at least one aliphatic diol and optionally at least one aliphatic dicarboxylic acid; the weight ratio of the linear polyester to the non-crosslinked SAN-polymer is in the range of 2.0:1 to 19.0:1; and one of said at least one aromatic dicarboxyate monomer units is isophthalate and said isophthalate is present in said polyester matrix in a concentration of 15 mole % or less of all the dicarboxylate monomer units in said linear polyester matrix; the use of the non-transparent microvoided axially stretched film as a synthetic paper; an image recording element comprising the non-transparent microvoided axially stretched film; a process for the preparing of the non-transparent microvoided axially stretched film; and a process for obtaining a transparent pattern therewith.

Description

Invention field [0001] The present invention relates to an opaque microporous axially stretched film and a manufacturing method thereof. Background of the invention [0002] US 3,755,499 discloses a synthetic sheet for writing purposes, which is basically selected from polyethylene terephthalate, polyethylene isophthalate and ethylene terephthalate and ethylene isophthalate The linear polyester of the ester copolymer and the high polymer having a glass transition point higher than the linear polyester are composed, and the mixing ratio of the high polymer is 7 to 35% by weight of the polymer mixture. The material is selected from polymethyl methacrylate, copolymers of acrylonitrile and styrene, copolymers of acrylonitrile, butadiene and styrene, because it is uniformly dispersed in the linear polyester to form its irregular surface The core of the high polymer, the synthetic sheet has a very fine and rough surface. The simultaneous and sequential stretching of these mixed polym...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G03C1/795B41M5/41B41M5/50C08J5/18C08L67/02
CPCG03C1/7954C08L67/02B41M5/41B41M5/508C08L25/00C08L35/00
Inventor D·昆滕斯L·利恩德斯
Owner AGFA GEVAERT AG