Ray-sensing resin composition for forming protective film and method for forming protective film
A technology of resin composition and protective film, which is applied to photosensitive materials used in optomechanical equipment, input/output process of data processing, instruments, etc., which can solve the problems of easy scars, long film forming time, and reliability of touch panels Lowering and other issues
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[0115] Hereinafter, synthesis examples and examples are disclosed, and the present invention is more specifically described, but the present invention is not limited to the following examples.
[0116] Manufacture of (co)polymers
Synthetic example 1
[0118] In a flask equipped with a condenser tube and a stirrer, 5 parts by mass of 2,2'-azobis(2,4-dimethylvaleronitrile) and 200 parts by mass of diethylene glycol methyl ethyl ether were charged first. Then, 40 parts by mass of glycidyl methacrylate, 18 parts by mass of styrene, 20 parts by mass of methacrylic acid, and 22 parts by mass of N-cyclohexylmaleimide were charged, and then replaced by nitrogen, and then slowly stirred . The temperature of the solution was raised to 70° C., and the temperature was maintained for five hours to obtain a polymer solution containing the copolymer (A-1). The solid content concentration of the obtained polymer solution was 33.1% by mass. The number average molecular weight of the obtained polymer was 7,000 (the number average molecular weight is a polystyrene-equivalent molecular weight measured using GPC (gel permeation chromatography) HLC-8020 (manufactured by TOSOH Co., Ltd.)). In addition, the molecular weight distribution (Mw / Mn) ...
Synthetic example 2
[0120] In a flask equipped with a condenser tube and a stirrer, 5 parts by mass of 2,2'-azobisisobutyronitrile and 200 parts by mass of diethylene glycol methyl ethyl ether were charged first. Next, 40 parts by mass of glycidyl methacrylate, tricyclic methacrylate [5.2.1.0 2,6 ] 35 parts by mass of decan-8-yl ester, 20 parts by mass of methacrylic acid, and 5 parts by mass of 1,3-butadiene were further replaced by nitrogen, and then slowly stirred. The temperature of the solution was raised to 80° C., and the temperature was maintained for five hours to obtain a polymer solution containing the copolymer (A-2). The solid content concentration of the obtained polymer solution was 33.3% by mass. The number average molecular weight of the obtained polymer was 6,500. In addition, the molecular weight distribution (Mw / Mn) was 2.
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