Pigment disperse combination, coloring photosensitive combination, color filter, liquid crystal display element and solid camera shooting element
A pigment dispersion and composition technology, applied in the field of liquid crystal display elements and solid-state imaging elements, can solve the problems of inability to meet the contrast requirements, and achieve the effects of excellent contrast, suppression of turbidity, and suppression of agglomeration
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[0438] Hereinafter, although an Example demonstrates this invention more concretely, this invention is not limited to the following Example unless the summary is exceeded. In addition, "parts" means "parts by mass" unless otherwise specified.
[0439]
Synthetic example 1
[0440] [Synthesis Example 1: Synthesis of Specific Polymer (P-1)]
[0441] 171.2 g of ε-caprolactone, 8.6 g of methacrylic acid, and 0.2 g of 2,6-di-tert-butyl-4-methylphenol were introduced into a 500 mL three-necked flask, and stirred and dissolved while blowing nitrogen. 0.1 g of monobutyltin oxide was further added thereto, followed by heating to 100°C. Eight hours later, after confirming the disappearance of the raw material from the mixed liquid by gas chromatography, the mixture was cooled to room temperature, and 100 mL of N-methyl-2-pyrrolidone was added to dissolve the mixed liquid. 18.0 g of DBU was added thereto, and after stirring at room temperature for 30 minutes, 12.1 g of allyl bromide was further added.
[0442] Then, the mixed liquid was heated to 60° C., and after 6 hours, it was confirmed by gas chromatography that the raw materials had disappeared from the mixed liquid, and then cooled to room temperature. Then, the reaction mixture was poured into 1 L ...
Synthetic example 2
[0446] [Synthesis Example 2: Synthesis of Specific Polymer (P-2)]
[0447]228.2 g of ε-caprolactone, 8.6 g of methacrylic acid, and 0.2 g of 2,6-di-tert-butyl-4-methylphenol were introduced into a 500 mL three-necked flask, and stirred and dissolved while blowing nitrogen. 0.1 g of monobutyltin oxide was further added thereto, followed by heating to 100°C. Eight hours later, after confirming the disappearance of the raw materials from the mixed solution by gas chromatography, the mixture was cooled to room temperature, and 100 mL of N-methyl-2-pyrrolidone was added to dissolve it. 18.0 g of DBU was added thereto, and after stirring at room temperature for 30 minutes, 13.1 g of epibromohydrin was further added.
[0448] Then, the mixed liquid was heated to 50° C., and after 6 hours, it was confirmed by gas chromatography that the raw materials had disappeared from the mixed liquid, and then cooled to room temperature. The reaction mixture was poured into 1 L of water to preci...
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